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Preparation method of expanded perlite sulfur-loading modified patina adsorbent

An expanded perlite and adsorbent technology, which is applied in the field of preparation of green rust adsorbents, can solve the problems of reducing the adsorption performance of green rust heavy metals, unable to remove heavy metals efficiently at the same time, unfavorable for popularization and application, etc., so as to reduce the influence and expand the interlayer distance. , Improve the effect of adsorption

Active Publication Date: 2020-02-07
CHANGSHU INSTITUTE OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The pH sensitivity of green rust will reduce the adsorption performance of green rust itself to heavy metals, which is not conducive to its popularization and application in different pH polluted water environments
At present, green rust still has the problem that the adsorption capacity is small, and it cannot efficiently remove multiple heavy metals in water at the same time.

Method used

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  • Preparation method of expanded perlite sulfur-loading modified patina adsorbent
  • Preparation method of expanded perlite sulfur-loading modified patina adsorbent
  • Preparation method of expanded perlite sulfur-loading modified patina adsorbent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Effect of molar ratio of sodium dimercaptopropane sulfonate to iron sulfate on adsorption performance of expanded perlite sulfur-loaded green rust adsorbent

[0019] Preparation of expanded perlite sulfur-loaded green rust adsorbent: such as figure 1 As shown, according to the molar ratio of sodium dimercaptopropanesulfonate to iron sulfate 1.5:10, 2:10, 2.5:10, 3:10, 4.5:10, 6:10, 6.5:10, 7:10, 7.5:10 Weigh sodium dimercaptopropanesulfonate and ferric sulfate respectively, mix, stir evenly, obtain sulfur-iron mixture; take expanded perlite and sulfur-iron mixture according to the mass ratio of expanded perlite and sulfur-iron mixture 3:6, mix , stir evenly, and then mechanically grind at 120rpm for 6h to obtain activated expanded perlite mixed sulfur ferrite; weigh sodium hydroxide, dissolve it in water, and prepare 4mol / L sodium hydroxide solution; according to the solid-liquid ratio of 1:2 (mg :mL) the activated expanded perlite mixed sulfur ferric agent is added in...

Embodiment 2

[0027] Effect of mass ratio of expanded perlite and sulfur-iron mixture on the adsorption performance of the prepared expanded perlite sulfur-loaded green rust adsorbent

[0028] Preparation of expanded perlite sulfur-loaded green rust adsorbent: Weigh sodium dimercaptopropanesulfonate and iron sulfate according to the molar ratio of sodium dimercaptopropanesulfonate and iron sulfate 6:10, mix and stir evenly to obtain sulfur-iron mixture ; Take by weighing respectively according to the mass ratio of expanded perlite and sulfur-iron mixture 1.5:6, 2:6, 2.5:6, 3:6, 4.5:6, 6:6, 6.5:6, 7:6, 7.5:6 Expanded perlite and sulfur-iron mixture, mixed, stirred evenly, and then mechanically ground at 240rpm for 9 hours to obtain activated expanded perlite mixed with sulfur-iron; weigh sodium hydroxide, dissolve it in water, and prepare 7mol / L sodium hydroxide solution ; According to the solid-liquid ratio of 1:2.5 (mg:mL), the activated expanded perlite mixed sulfur iron agent was added t...

Embodiment 3

[0035] Effect of sodium hydroxide concentration on the adsorption performance of the prepared expanded perlite sulfur-loaded green rust adsorbent

[0036] Preparation of expanded perlite sulfur-loaded green rust adsorbent: Weigh sodium dimercaptopropanesulfonate and iron sulfate according to the molar ratio of sodium dimercaptopropanesulfonate and iron sulfate 6:10, mix and stir evenly to obtain sulfur-iron mixture Take expanded perlite and sulfur-iron mixture according to the mass ratio of expanded perlite and sulfur-iron mixture 6:6, mix, stir, and then mechanically grind 12h with 360rpm rotating speed to obtain activated expanded perlite mixed sulfur-iron agent; weigh Take sodium hydroxide, dissolve it in water, and prepare 2mol / L, 3mol / L, 3.5mol / L, 4mol / L, 7mol / L, 10mol / L, 10.5mol / L, 11mol / L, 12mol / L hydroxide respectively Sodium solution; according to the solid-liquid ratio of 1:3 (mg:mL), the activated expanded perlite mixed sulfur iron agent was added to the sodium hydr...

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Abstract

The invention discloses a preparation method of an expanded perlite sulfur-loading modified patina adsorbent. The preparation method comprises the following preparation steps: mixing sodium dimercaptopropanesulfonate and iron sulfate evenly so as to obtain a sulfur-iron mixture, then mixing the obtained sulfur-iron mixture with expanded perlite evenly, performing mechanical grinding so as to obtain an activated expanded perlite sulfur-iron-doped agent, then adding the activated expanded perlite sulfur-iron-doped agent to a sodium hydroxide solution, performing sealing and stirring so as to obtain expanded perlite sulfur-loading modified patina absorbent slurry, performing solid-liquid separation on the slurry, and finally performing drying, grinding and sieving so as to obtain the expandedperlite sulfur-loading modified patina adsorbent. Simultaneous and efficient removal of multiple heavy metal ions in sewage can be achieved through the patina adsorbent within a wide pH range of 2-12, and the removal rate of all the heavy metal ions is greater than 97%.

Description

technical field [0001] The invention relates to a preparation method of a green rust adsorbent for treating heavy metal wastewater, in particular to a preparation method of an expanded perlite sulfur-loaded modified green rust adsorbent. Background technique [0002] The abundance of iron in the earth is second only to aluminum, ranking fourth among all elements. Iron is usually in the form of ferrite. At present, there are 16 kinds of ferrites with different crystal structures on the earth, which can be divided into three categories according to the chemical composition and the chemical valence state of iron: the first category is ferrites containing only ferric iron, such as ferrihydrite, goethite ore, hematite, lepidotite, etc.; the second type is ferrite containing only divalent iron, such as ferrous oxide and ferrous hydroxide; the third type is iron containing both divalent iron and ferric iron Oxygen, such as magnetite and patina. [0003] Patina is usually dark bl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/22B01J20/30C02F1/28C02F1/62
CPCB01J20/06B01J20/106B01J20/22C02F1/288C02F1/62
Inventor 黄涛宋东平刘万辉张树文周璐璐徐娇娇
Owner CHANGSHU INSTITUTE OF TECHNOLOGY
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