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Method for preparing wear-resistant plastic particles by using waste polystyrene

A technology of waste polystyrene and plastic particles, applied in the field of polymers, can solve the problems of poor wear resistance, poor mechanical properties of wear resistance, and insignificant performance enhancement effect of polymer blends, etc., to achieve improved wear resistance , solve the effect of poor wear resistance and enhance the interaction force

Inactive Publication Date: 2020-02-07
ANHUI GUANHONG PLASTIC IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, polystyrene has poor mechanical properties such as wear resistance and strength, which limits its application in many fields, and the wear resistance of polystyrene obtained after waste recycling is even worse. Therefore, in order to realize waste polystyrene The recycling of waste polystyrene needs to be processed to improve its wear resistance and strength, so as to truly realize the recycling and reuse of waste polystyrene
[0004] For example, Chinese patent CN2017104055384 discloses a high-toughness and high-wear-resistant polystyrene plastic and its preparation method. By adding high-strength coupling agent modified carbon black as a wear-resistant agent, the wear-resistant performance of the material is improved; another example Chinese patent CN2017112266334 discloses a polystyrene-ABS resin wear-resistant composite material and its preparation method. Nano-ceramic particles are used as wear-resistant agents, and nano-ceramic particles are treated with a coupling agent to increase the bond between nano-ceramic particles and ABS resin. Compatibility, so that the wear resistance of the composite material is improved; the technical solutions adopted by the above two patents are to improve the wear resistance between the wear agent and the polymer resin by using a coupling agent to treat the wear agent. Compatibility, so that a good blending system can be formed between the two, so as to improve the wear resistance of the material, but a single improvement of the compatibility of the blending system cannot solve the problem of wear-resistant agents and blending systems in the blending system. The defect that the interaction between polymer resins is poor, so the enhancement effect on the properties of polymer blends is not significant

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A method for preparing wear-resistant plastic particles by using waste polystyrene, the specific preparation method is as follows:

[0017] 1) Clean the recovered waste polystyrene and put it into the pressure reactor. According to the mass ratio of 1:1, add an appropriate amount of liquid paraffin, seal the reactor, and use nitrogen to purify for 15 minutes to discharge the air in the reactor, so that the reaction system Under a nitrogen environment, turn on the stirring device, heat up to 200°C at a speed of 150r / min, heat-treat for 25min, then cool down to 110°C, add cobalt powder with 1% polystyrene weight after exhaust gas, and cool naturally to room temperature. After solid-liquid separation, the solid phase product is used for standby to obtain pretreated polystyrene;

[0018] 2) Add a certain amount of chitosan to the acetic acid solution with a concentration of 1%, put it in a water bath and fully dissolve it to obtain a chitosan solution with a content of 10%,...

Embodiment 2

[0023] A method for preparing wear-resistant plastic particles by using waste polystyrene, the specific preparation method is as follows:

[0024] 1) Clean the recovered waste polystyrene and put it into the pressure reactor. According to the mass ratio of 1:1.2, add an appropriate amount of liquid paraffin, seal the reactor, and use nitrogen to purify for 20 minutes to discharge the air in the reactor, so that the reaction system Under a nitrogen environment, turn on the stirring device, heat up to 210°C at a speed of 180r / min, heat-treat for 20min, then cool down to 120°C, add cobalt powder with 1.3% polystyrene weight after exhaust gas, and cool to room temperature naturally. After solid-liquid separation, the solid phase product is used for later use to obtain pretreated polystyrene

[0025] 2) Add a certain amount of chitosan to the acetic acid solution with a concentration of 2%, put it in a water bath and fully dissolve it to obtain a chitosan solution with a content of...

Embodiment 3

[0030] A method for preparing wear-resistant plastic particles by using waste polystyrene, the specific preparation method is as follows:

[0031] 1) Clean the recovered waste polystyrene and put it into the pressure reactor. According to the mass ratio of 1:1.5, add an appropriate amount of liquid paraffin, seal the reactor, and use nitrogen to purify for 25 minutes to discharge the air in the reactor, so that the reaction system Under a nitrogen environment, turn on the stirring device, heat up to 220°C at a speed of 200r / min, heat treatment for 15min, then cool down to 130°C, add cobalt powder with 1.5% polystyrene weight after exhaust gas, and cool naturally to room temperature. After solid-liquid separation, the solid phase product is used for later use to obtain pretreated polystyrene

[0032] 2) Add a certain amount of chitosan to the acetic acid solution with a concentration of 3%, put it in a water bath and fully dissolve it to obtain a chitosan solution with a conten...

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Abstract

The invention discloses a method for preparing wear-resistant plastic particles by using waste polystyrene. The method specifically includes the following steps that (1) the waste polystyrene and liquid paraffin are put into a reactor for heat treatment under the nitrogen environment, then cobalt powder is added for natural cooling, and pretreated polystyrene is obtained; (2) tetraethyl orthosilicate is added into a chitosan solution, hydrochloric acid is added and then placed in a water bath, glutaraldehyde is added, and chitosan / silica particles are obtained by reaction; (3) the pretreated polystyrene is added into cyclohexanone after being cut into granules and dried, and polyvinyl pyrrolidone is added, stirred and dissolved, and then dried particles are added to obtain a coating solution; and (4) after the coating solution is treated, a film is scraped on a substrate, removed after phase transfer, and melted and extruded with a plasticizer and a lubricant through a twin-screw extruder. According to the method, by increasing the bond strength between the polystyrene and silicon dioxide, significant improvement of the wear resistance of the polystyrene is realized, and the methodis suitable for large-scale and industrial production.

Description

technical field [0001] The invention belongs to the technical field of macromolecules, and in particular relates to a method for preparing wear-resistant plastic particles by using waste polystyrene. Background technique [0002] Plastic is an important product in polymer synthetic materials. While the plastic industry meets people's life and social development, social and environmental problems caused by "white pollution" caused by the sharp increase in plastic waste are also becoming more and more serious. "White pollution" has begun to cause headaches for people. Lunch boxes that do not rot or decompose cannot be effectively recycled, and domestic plastic waste cannot be disposed of. The sharp increase of plastic waste and the resulting social and environmental problems are in front of people. [0003] Recycled plastics are an effective way to solve the pollution caused by plastics, but recycled plastics have disadvantages such as low strength, no toughness, and poor wea...

Claims

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Application Information

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IPC IPC(8): C08L25/06C08L91/06C08L5/08C08L39/06C08K5/07B29C48/92B29B9/06
CPCB29B9/06B29C48/92B29C2948/9259B29C2948/92704C08L25/06C08L2205/035C08L2207/20C08L2312/00C08L91/06C08L5/08C08L39/06C08K5/07
Inventor 申乾成申辉黄振
Owner ANHUI GUANHONG PLASTIC IND