Analog HfOx/HfOy homojunction memristor and regulation and control method thereof
A technology of homojunction and memristor, which is applied in the field of analog HfOx/HfOy homojunction memristor and its regulation, can solve the problems of small analog resistive switching window, working speed, insufficient cycle characteristics of devices, etc., and achieve electric field The effect of large voltage division, high resistance and low resistance
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Embodiment 1
[0061] Embodiment 1: A kind of large window simulation type HfO x Preparation method of homojunction memristor
[0062] The HfO provided by embodiment 1 x Memristor, Pt / HfO with small square structure y / HfO x / Ti memristor, whose structure is as figure 1 , Figure 7 shown; wherein, the bottom electrode is Ti with a thickness of 100nm, and the functional layer is HfO with a thickness of 10nm x and 4nm HfO y , x=1.72, y=1.93; the upper electrode is Pt with a thickness of 100nm.
[0063] The following specifically sets forth the embodiment HfO x The preparation method of memristor; Concrete steps are as follows:
[0064] (1) The first step: prepare the lower electrode:
[0065] Sputtering: In long SiO 2 The lower electrode Ti with a thickness of 100nm was prepared on the Si substrate of the insulating layer by magnetron sputtering; the sputtering process conditions were: background vacuum 5*10 -5 Pa, the working pressure is 0.5Pa, the DC sputtering power is 100W, and ...
Embodiment 2
[0075] Embodiment 2: A kind of large window simulation type HfO x Regulation and testing method of homojunction memristor
[0076] The following is a method for regulating and testing the memristor prepared in Example 1, which specifically includes the following steps:
[0077] (1) The memristor units in the first row and the first column of the small square array structure memristor are pre-formed conductive channels; the scanning voltage used for forward I / V voltage scanning is 5V, and the current limit is 300μA.
[0078] (2) Perform 20 bidirectional I / V voltage scans on the memristor unit until stable RESET, SET voltage values and their corresponding high and low resistance states appear in the memristor unit;
[0079] (3) Perform a DC gradient test on the memristor unit, using continuous unidirectional SET / RESET voltage to scan; the initial low resistance is 2.6kΩ, the SET voltage amplitude is 1.2V, and the limiting current is from 240μA to 1mA, with a step size is 5µ...
Embodiment 3
[0097] Embodiment 3: A kind of large window simulation type HfO x Preparation method of homojunction memristor
[0098] The HfO provided by embodiment 3 x Memristor, Pt / HfO with small square structure y / HfO x / Ti memristor, whose structure is as figure 1 shown; wherein, the bottom electrode is Ti with a thickness of 100nm, and the functional layer is HfO with a thickness of 10nm x and 4nm HfO y , x=1.6, y=1.93; the upper electrode is Pt with a thickness of 100nm. The preparation process is the same as in Example 1.
[0099] Among them, the difference from Example 1 is that in the sputtering process, the first 10nm HfO x Oxygen storage layer, regrown 4nm HfO y Migration barrier layer; the process conditions of sputtering are: the background vacuum is 5*10 -3 Pa, working pressure are 0.67Pa, DC sputtering power is 100W, sputtering time is 306s, 120s respectively, Ar and O 2 The volume ratio is 38:9, 31:16;
[0100] When x=1.6, the corresponding HfO x There are more ...
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