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Ultrafilter membrane and preparation method thereof

A technology of ultrafiltration membrane and membrane casting liquid, which is applied in the field of ultrafiltration membrane, can solve the problems that need to be improved, and achieve the effect of good performance

Active Publication Date: 2020-03-27
CHINA LUCKY FILM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the current ultrafiltration membranes and preparation methods still need to be improved.

Method used

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  • Ultrafilter membrane and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] (1) Dissolving polyethersulfone and polyethylene glycol with a molecular weight of 300 in N,N-dimethylacetamide to obtain a casting solution. Based on the total mass of the casting solution, the content of polyethersulfone is 20%, and the content of polyethylene glycol is 3%.

[0047] (2) Drop titanium tetrachloride into the casting solution while stirring, stir evenly, and then statically defoam for 24 hours to obtain the modified casting solution. Based on the total mass of the modified casting solution, the content of titanium tetrachloride is 2%.

[0048] (3) Stick the non-woven fabric on the hollow glass with tape, pour the modified casting solution on the non-woven fabric, scrape the modified casting solution evenly with a light stick, put it into the coagulation bath after standing for a period of time The mesophase is transformed into a membrane, and after 10 minutes, the membrane is taken out and soaked in pure water for 24 hours to obtain an ultrafiltration m...

Embodiment 2

[0050] (1) Dissolving polysulfone and K30 in N,N-dimethylacetamide to obtain a casting solution. Based on the total mass of the casting solution, the content of polysulfone is 18%, and the content of K30 is 5%.

[0051] (2) Drop titanium tetrachloride into the casting solution while stirring, stir evenly, and then statically defoam for 24 hours to obtain the modified casting solution. Based on the total mass of the modified casting solution, the content of titanium tetrachloride is 2%.

[0052] (3) Stick the non-woven fabric on the hollow glass with tape, pour the modified casting solution on the non-woven fabric, scrape the modified casting solution evenly with a light stick, put it into the coagulation bath after standing for a period of time The mesophase is transformed into a membrane, and after 10 minutes, the membrane is taken out and soaked in pure water for 24 hours to obtain an ultrafiltration membrane. The coagulation bath is pure water.

Embodiment 3

[0054] (1) Dissolving polyvinylidene fluoride and K30 in N,N-dimethylacetamide to obtain a casting solution. Based on the total mass of the casting solution, the content of polyvinylidene fluoride is 10%, and the content of K30 is 1%.

[0055] (2) Drop titanium tetrachloride into the casting solution while stirring, stir evenly, and then statically defoam for 24 hours to obtain the modified casting solution. Based on the total mass of the modified casting solution, the content of titanium tetrachloride is 4%.

[0056] (3) Stick the non-woven fabric on the hollow glass with tape, pour the modified casting solution on the non-woven fabric, scrape the modified casting solution evenly with a light stick, put it into the coagulation bath after standing for a period of time The mesophase is transformed into a membrane, and after 10 minutes, the membrane is taken out and soaked in pure water for 24 hours to obtain an ultrafiltration membrane. The coagulation bath is pure water.

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Abstract

The invention discloses an ultrafilter membrane and a preparation method thereof. The preparation method comprises following steps: (1) dissolving a high molecular polymer and a pore forming agent inan organic solvent to obtain a casting solution; (2) adding a titanium containing hydrophilic modifier into the casting solution, and stirring and de-foaming to obtain a modified casting solution, wherein the titanium containing hydrophilic modifier accounts for 1 to 5% of the total weight of the modified casting solution; and (3) painting the modified casting solution on nonwoven cloth, and soaking the processed nonwoven cloth in a coagulating bath to obtain the ultrafilter membrane. The preparation method has at least one of following advantages: (1) the prepared ultrafilter membrane has a strong hydrophilic property, a high antibacterial performance, a good anti-contamination property, high thermal stability, an excellent corrosion resistant performance, high photocatalytic activity, and a high flux; (2) solved is the problem that in a conventional ultrafilter membrane that takes titanium dioxide as an additive, titanium dioxide is lost due to the erosion of water flow; and (3) theoperation is simple, the energy consumption is low, and the preparation method is suitable for industrial production.

Description

technical field [0001] The invention relates to the field of ultrafiltration membranes, in particular to an ultrafiltration membrane and a preparation method. Background technique [0002] Polysulfone polymer materials are more commonly used membrane materials at present. Polysulfone ultrafiltration membranes play an important role in food, chemical industry, machinery, environmental protection, biomedicine, aerospace, petrochemical, automobile, machinery manufacturing, electronic information and other fields. effect. Among them, polyethersulfone (PES) has high impact strength, high heat distortion temperature and excellent formability, and is widely used in separation membranes, and can be used to manufacture microfiltration, ultrafiltration, nanofiltration, gas separation and hemodialysis membranes. However, polyethersulfone itself has strong hydrophobicity, which easily causes the deposition of organic matter and colloids on the surface of the membrane and the adsorption...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/68B01D71/34B01D71/02B01D69/12B01D67/00B01D61/14
CPCB01D71/68B01D71/34B01D71/02B01D69/12B01D67/0079B01D61/145B01D2325/48B01D2325/30
Inventor 丁宇孟祥钦柳艳敏郭宇孙蒙蒙赵朔
Owner CHINA LUCKY FILM CORP