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High-performance industrial composite glycerin and preparation method thereof

A compound glycerin, high-performance technology, applied in the field of glycerol, can solve the problems of poor combination effect, poor anti-yellowing resistance of glycerin, limited application field of glycerin, etc., and achieves the effect of good anti-yellowing effect and improved performance effect.

Inactive Publication Date: 2020-04-07
安徽诚宁油脂科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Existing glycerol has poor anti-yellowing performance at high temperatures, which limits the application field of glycerin. The existing Chinese patent document announcement number: CN1106833317B discloses a kind of high-temperature anti-yellowing glycerin. Its preparation method is as follows: a, take an appropriate amount of purity: 95%-98% glycerin; b, adding appropriate amount of sodium hypochlorite and additives to the above-mentioned glycerin, and stirring evenly under heating conditions to make high-temperature anti-yellowing glycerin; the weight percentage of the above-mentioned raw materials in the whole high-temperature anti-yellowing glycerin is : Glycerin: 90%-99%; Sodium hypochlorite: 1%-1.5%; Additives: remaining
The additive includes any one of the following raw materials or combinations: nano-titanium dioxide, hexamethylphosphoric acid triamide, bis(stearyl) alcohol thiodipropionate, water, and anti-yellowing glycerol is given in this document, However, the raw material is composed of a simple combination of antioxidants, high melting point solvents, and nano-titanium dioxide. The raw materials are relatively conventional, and the combination effect is poor, and further improvement is still needed.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A kind of high-performance industrial compound glycerin of the present embodiment comprises the raw material of following weight portion:

[0029] 55 parts of glycerin, 10 parts of alloy additive solution, 3 parts of Si powder, 5 parts of reinforcing agent, 2 parts of rutile nano-titanium dioxide.

[0030] The preparation method of the alloy additive solution of this embodiment is to add nickel powder into the stirrer, then add titanium carbide powder with 5% of the total amount of nickel powder, then stir at a speed of 1000r / min for 20min at a high speed, and then add Magnesium borate powder with 2% of the total amount of nickel powder, mechanically stirred for 10 minutes, and finally added methyl phenyl silicone oil twice as much as the total amount of nickel powder, then continued to stir for 50 minutes at a low speed of 200r / min. Dispersion treatment, after the treatment is completed, the alloy additive solution is obtained.

[0031] The specific steps of the heat ...

Embodiment 2

[0042] A kind of high-performance industrial compound glycerin of the present embodiment comprises the raw material of following weight portion:

[0043] 65 parts of glycerin, 20 parts of alloy additive solution, 7 parts of Si powder, 15 parts of reinforcing agent, 6 parts of rutile nano-titanium dioxide.

[0044] The preparation method of the alloy additive solution of this embodiment is to add nickel powder into the stirrer, then add titanium carbide powder with 15% of the total amount of nickel powder, then stir at a high speed of 2000r / min for 30min, and then add Magnesium borate powder with 5% of the total amount of nickel powder, mechanically stirred for 20 minutes, and finally added methyl phenyl silicone oil 3 times the total amount of nickel powder, then continued to stir at a low speed of 300r / min for 60 minutes, after the stirring was completed, then heat evenly Dispersion treatment, after the treatment is completed, the alloy additive solution is obtained.

[0045] ...

Embodiment 3

[0056] A kind of high-performance industrial compound glycerin of the present embodiment comprises the raw material of following weight portion:

[0057] 60 parts of glycerin, 15 parts of alloy additive solution, 5 parts of Si powder, 10 parts of reinforcing agent, 4 parts of rutile nano-titanium dioxide.

[0058] The preparation method of the alloy additive solution of this embodiment is to add nickel powder into the stirrer, then add titanium carbide powder with 10% of the total amount of nickel powder, and then carry out high-speed stirring at a speed of 1500r / min for 25min, and then add Magnesium borate powder with 3.5% of the total amount of nickel powder, mechanically stirred for 15 minutes, and finally added methyl phenyl silicone oil with 2.5 times the total amount of nickel powder, and then continued to stir for 55 minutes at a low speed of 250r / min. Dispersion treatment, after the treatment is completed, the alloy additive solution is obtained.

[0059] The specific...

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PUM

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Abstract

The invention discloses a high-performance industrial composite glycerin. The high-performance industrial composite glycerin comprises the following raw materials by weight: 55-65 parts of glycerin, 10-20 parts of an alloy assistant liquid, 3-7 parts of Si powder, 5-15 parts of a reinforcing agent and 2-6 parts of rutile type nano-titanium dioxide. According to the invention, the alloy assistant liquid is added into glycerin to improve the adaptability of glycerin at a high temperature and adapt to the temperature change so as to reach a yellowing-resistant effect, the alloy assistant liquid adopts methyl phenyl silicone oil as a matrix liquid, methyl phenyl silicone oil itself has weather resistance, heat resistance, chemical resistance and other excellent properties, and by adding nickelpowder, titanium carbide powder and magnesium borate powder, on the one hand, methyl phenyl silicone oil can serve as bridging liquid to make nickel powder, titanium carbide powder and magnesium borate powder better integrate into glycerin, the nickel powder can play a repairing role, so that glycerin can adapt to the temperature timely at the high temperature, the yellowing resistance effect isimproved, and the titanium carbide powder and magnesium borate powder can improve the temperature resistant effect of glycerin.

Description

technical field [0001] The invention relates to the technical field of glycerin, in particular to a high-performance industrial compound glycerin and a preparation method thereof. Background technique [0002] Glycerol is a colorless, sweet, clear, viscous liquid. Odorless. Has a warm sweet taste. Commonly known as glycerin, it absorbs moisture from the air, as well as hydrogen sulfide, hydrogen cyanide, and sulfur dioxide. Insoluble in benzene, chloroform, carbon tetrachloride, carbon disulfide, petroleum ether and oils. The relative density is 1.26362. The melting point is 17.8°C. The boiling point is 290.0°C. The refractive index is 1.4746. The industrial production methods of glycerin can be divided into two categories: the method of using natural oil as raw material, the obtained glycerin is commonly known as natural glycerin; the synthesis method of propylene as raw material, the obtained glycerin is commonly known as synthetic glycerin. [0003] Existing glyce...

Claims

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Application Information

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IPC IPC(8): C08L83/04C08K13/02C08K5/053C08K3/08C08K3/22C08K3/02C08K3/14C08K3/38C08K5/13
CPCC08K3/02C08K3/08C08K3/14C08K3/22C08K3/38C08K5/053C08K5/13C08K13/02C08K2003/023C08K2003/0862C08K2003/2241C08K2003/387C08K2201/011C08L2201/08C08L83/04
Inventor 倪震曾炜伍海辉
Owner 安徽诚宁油脂科技有限公司
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