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Sulfuric acid manufacturing method

A manufacturing method and technology of sulfuric acid, applied in chemical instruments and methods, sustainable manufacturing/processing, sulfur compounds, etc., can solve the problems of long process flow, inability to achieve automatic control, and inability to produce reagent sulfuric acid, etc., and achieve short process flow, Realize the effect of automatic control and a small number of equipment

Pending Publication Date: 2020-04-28
惠州市百利宏晟安化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This process is long, cannot realize automatic control, and cannot produce reagent sulfuric acid and oleum, so it has not been applied industrially

Method used

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  • Sulfuric acid manufacturing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Such as Figures 1 to 3 As shown, a kind of manufacture method of sulfuric acid is provided, comprises the following steps:

[0031] Step 1. Furnace gas generation: After entering the air filter, the air is pressurized by the main fan, then enters the drying tower to remove part of the water, and then mixes with the acid gas containing hydrogen sulfide at a pressure of 0.06MPa and passes through the 0.8MPa high-pressure pump and sulfur gun mechanical mist The liquefied liquid sulfur is sent to the incinerator for mixed combustion to generate SO 2 The temperature of mixed furnace gas and water gas is 1100 ℃, SO in the mixed furnace gas 2 Concentration is 8%, NO x The content is 600mg / Nm 3 ;

[0032] Among them, the content of hydrogen sulfide in acid gas containing hydrogen sulfide is 80%, the content of S in liquid sulfur is 99.5%, and the addition amount of liquid sulfur and acid gas containing hydrogen sulfide is 1:1.5 based on the mass ratio of sulfur content;

...

Embodiment 2

[0040] Such as Figures 1 to 3 As shown, a kind of manufacture method of sulfuric acid is provided, comprises the following steps:

[0041] Step 1. Furnace gas generation: After entering the air filter, the air is pressurized by the main fan, then enters the drying tower to remove part of the water, and then mixes with the acid gas containing hydrogen sulfide at a pressure of 0.06MPa and passes through the 0.8MPa high-pressure pump and sulfur gun mechanical mist The liquefied liquid sulfur is sent to the incinerator for mixed combustion to generate SO 2 The temperature of mixed furnace gas and water gas is 1000 ℃, SO in the mixed furnace gas 2 Concentration is 6%, NO x The content is 500mg / Nm 3 ;

[0042] Among them, the hydrogen sulfide content in the acid gas containing hydrogen sulfide is 75%, the S content in the liquid sulfur is 99.3%, and the addition amount of liquid sulfur and acid gas containing hydrogen sulfide is 1:2 based on the mass ratio of the respective sul...

Embodiment 3

[0050] Such as Figures 1 to 3 As shown, a kind of manufacture method of sulfuric acid is provided, comprises the following steps:

[0051] Step 1. Furnace gas generation: After entering the air filter, the air is pressurized by the main fan, then enters the drying tower to remove part of the water, and then mixes with the acid gas containing hydrogen sulfide at a pressure of 0.06MPa and passes through the 0.8MPa high-pressure pump and sulfur gun mechanical mist The liquefied liquid sulfur is sent to the incinerator for mixed combustion to generate SO 2 The temperature of mixed furnace gas and water gas is 1200 ℃, SO in the mixed furnace gas 2 Concentration is 10%, NO x The content is 600mg / Nm 3 ;

[0052] Among them, the content of hydrogen sulfide in acid gas containing hydrogen sulfide is 85%, the content of S in liquid sulfur is 99.7%, and the addition amount of liquid sulfur and acid gas containing hydrogen sulfide is 1:1 based on the mass ratio of sulfur content;

...

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Abstract

The invention relates to the technical field of inorganic chemical manufacturing, and particularly relates to a sulfuric acid manufacturing method. The method comprises the steps of furnace gas generation, impurity removal and conversion, absorption and acid formation, sulfuric acid circulation and cooling, waste heat recovery and tail gas emission. The method combines the advantages of 'dry method ', 'wet method' and 'semi-dry method' acid manufacturing processes, and can prepare various sulfuric acid products such as fuming sulfuric acid and reagent sulfuric acid, and no low-concentration dilute acid byproduct is generated; the sulfuric acid manufacturing method is short in technological process, low in tail gas concentration, low in production energy consumption, high in waste heat recovery efficiency, small in equipment number, low in investment cost, large in device size and easy to achieve, and automatic control can be achieved.

Description

technical field [0001] The invention relates to the technical field of inorganic chemical manufacturing, in particular to a method for manufacturing sulfuric acid. Background technique [0002] At present, the quality standard of domestic industrial sulfuric acid is in accordance with GB / T534-2014 "Industrial Sulfuric Acid", and all production adopts the contact process of sulfuric acid production. The industrial production equipment of contact process acid production depends on the difference between the raw material and the moisture content of the furnace gas. There are mainly "dry process", "Wet" and "semi-dry" three manufacturing processes. [0003] The "dry" acid production process technology is mature and reliable, and is currently the mainstream sulfuric acid manufacturing process technology. Its raw materials include sulfur, pyrite, smelting flue gas, acid gas containing hydrogen sulfide, waste sulfuric acid, etc. The "dry" acid production process is generally to in...

Claims

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Application Information

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IPC IPC(8): C01B17/76C01B17/775C01B17/78C01B17/79C01B17/80
CPCC01B17/76C01B17/775C01B17/80C01B17/78C01B17/79Y02P20/129Y02P20/10
Inventor 何文旭
Owner 惠州市百利宏晟安化工有限公司