Waterborne graphene conductive anticorrosion coating and preparation method thereof
A water-based graphene, conductive anti-corrosion technology, applied in the direction of conductive coatings, anti-corrosion coatings, epoxy resin coatings, etc., can solve the problems of general anti-corrosion performance, environmental pollution, high resistivity of coatings, etc., and achieve excellent conductive anti-corrosion effect
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[0075] The preparation method of described graphene aqueous dispersion comprises the following steps:
[0076] Mix graphene, carboxymethyl cellulose and water, and shear and disperse for 1h-2h to obtain a mixture;
[0077] The mixture was sonicated for 3h-4h.
[0078] In the present invention, graphene, carboxymethyl cellulose and water are mixed, sheared and dispersed, and ultrasonically treated to obtain a well-dispersed and stable graphene aqueous solution, and then the graphene aqueous dispersion, zinc oxide, and water-based ring The oxygen curing agent is mixed to obtain component B. At this time, the addition amount of graphene and zinc oxide is small, and both can be stably dispersed in component B. At the same time, the conductive network is formed by graphene and zinc oxide, and it still has an excellent conductive anti-corrosion effect when the two are added in a small amount.
[0079] In the graphene aqueous dispersion, the mass fraction of graphene will also affe...
Embodiment 1
[0120] The present embodiment provides a kind of waterborne graphene conductive anticorrosion coating and preparation method thereof, and the steps are as follows:
[0121] (1) Preparation of graphene aqueous dispersion
[0122] Pour graphene flakes (800 mesh) into a beaker, add deionized water and carboxymethyl cellulose, and disperse at high speed for 1.5 hours to obtain a mixture.
[0123] The mixture was subjected to high-power ultrasonication for 3.5 hours to obtain a uniform graphene aqueous dispersion, wherein the mass fraction of graphene in the graphene aqueous dispersion was 5%.
[0124] (2) Preparation of Component A
[0125] Mix 50g of water-based epoxy resin, 10g of organic bentonite, 10g of silica powder, 10g of barium sulfate, 20g of water, 1g of dispersant PE100, 1g of leveling agent BYK346 and 1g of defoamer BYK-028, and stir at a speed of 1500rpm for 2h to obtain Component A.
[0126] (3) Preparation of component B
[0127] Mix 10 g of the above graphene ...
Embodiment 2
[0130] This embodiment provides a water-based graphene conductive anti-corrosion coating and a preparation method thereof, the steps of which are basically the same as in Example 1, the only difference being that the raw material content and preparation method of A component and B component are different from those of Example 1, specifically Proceed as follows:
[0131] (1) Preparation of graphene aqueous dispersion
[0132] Pour graphene flakes (800 mesh) into a beaker, add deionized water and carboxymethyl cellulose, and disperse at high speed for 1.5 hours to obtain a mixture.
[0133] The mixture was subjected to high-power ultrasonication for 3.5 hours to obtain a uniform graphene aqueous dispersion, wherein the mass fraction of graphene in the graphene aqueous dispersion was 5%.
[0134](2) Preparation of Component A
[0135] Mix 60g of water-based epoxy resin, 10g of organic bentonite, 20g of silica powder, 20g of barium sulfate, 15g of water, 1g of dispersant PE100, ...
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Abstract
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