Check patentability & draft patents in minutes with Patsnap Eureka AI!

Waterborne graphene conductive anticorrosion coating and preparation method thereof

A water-based graphene, conductive anti-corrosion technology, applied in the direction of conductive coatings, anti-corrosion coatings, epoxy resin coatings, etc., can solve the problems of general anti-corrosion performance, environmental pollution, high resistivity of coatings, etc., and achieve excellent conductive anti-corrosion effect

Active Publication Date: 2020-08-11
泽铱(佛山)工业技术有限公司 +1
View PDF3 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, graphene and metal oxides are difficult to wet and disperse in aqueous solution, and graphene is easy to agglomerate in the coating, thus affecting the performance of the coating
Patent 201610813904.5 reports a conductive coating with graphene oxide and tin oxide nanoparticles as fillers, but the coating has poor stability and general anti-corrosion performance; patent 201611154411.1 reports a conductive anti-corrosion coating with metal and non-metal conductor material particles as conductive fillers, However, the resistivity of the coating is still high; patent 201811076130.8 reports an anti-corrosion coating using hydroxyacrylic resin and epoxy resin as film-forming substances, modified graphene and carbon nanotubes as conductive fillers, but the coating contains a large amount of organic solvents, easy to cause environmental pollution

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Waterborne graphene conductive anticorrosion coating and preparation method thereof
  • Waterborne graphene conductive anticorrosion coating and preparation method thereof
  • Waterborne graphene conductive anticorrosion coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0075] The preparation method of described graphene aqueous dispersion comprises the following steps:

[0076] Mix graphene, carboxymethyl cellulose and water, and shear and disperse for 1h-2h to obtain a mixture;

[0077] The mixture was sonicated for 3h-4h.

[0078] In the present invention, graphene, carboxymethyl cellulose and water are mixed, sheared and dispersed, and ultrasonically treated to obtain a well-dispersed and stable graphene aqueous solution, and then the graphene aqueous dispersion, zinc oxide, and water-based ring The oxygen curing agent is mixed to obtain component B. At this time, the addition amount of graphene and zinc oxide is small, and both can be stably dispersed in component B. At the same time, the conductive network is formed by graphene and zinc oxide, and it still has an excellent conductive anti-corrosion effect when the two are added in a small amount.

[0079] In the graphene aqueous dispersion, the mass fraction of graphene will also affe...

Embodiment 1

[0120] The present embodiment provides a kind of waterborne graphene conductive anticorrosion coating and preparation method thereof, and the steps are as follows:

[0121] (1) Preparation of graphene aqueous dispersion

[0122] Pour graphene flakes (800 mesh) into a beaker, add deionized water and carboxymethyl cellulose, and disperse at high speed for 1.5 hours to obtain a mixture.

[0123] The mixture was subjected to high-power ultrasonication for 3.5 hours to obtain a uniform graphene aqueous dispersion, wherein the mass fraction of graphene in the graphene aqueous dispersion was 5%.

[0124] (2) Preparation of Component A

[0125] Mix 50g of water-based epoxy resin, 10g of organic bentonite, 10g of silica powder, 10g of barium sulfate, 20g of water, 1g of dispersant PE100, 1g of leveling agent BYK346 and 1g of defoamer BYK-028, and stir at a speed of 1500rpm for 2h to obtain Component A.

[0126] (3) Preparation of component B

[0127] Mix 10 g of the above graphene ...

Embodiment 2

[0130] This embodiment provides a water-based graphene conductive anti-corrosion coating and a preparation method thereof, the steps of which are basically the same as in Example 1, the only difference being that the raw material content and preparation method of A component and B component are different from those of Example 1, specifically Proceed as follows:

[0131] (1) Preparation of graphene aqueous dispersion

[0132] Pour graphene flakes (800 mesh) into a beaker, add deionized water and carboxymethyl cellulose, and disperse at high speed for 1.5 hours to obtain a mixture.

[0133] The mixture was subjected to high-power ultrasonication for 3.5 hours to obtain a uniform graphene aqueous dispersion, wherein the mass fraction of graphene in the graphene aqueous dispersion was 5%.

[0134](2) Preparation of Component A

[0135] Mix 60g of water-based epoxy resin, 10g of organic bentonite, 20g of silica powder, 20g of barium sulfate, 15g of water, 1g of dispersant PE100, ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
adhesivityaaaaaaaaaa
quality scoreaaaaaaaaaa
Login to View More

Abstract

The invention relates to a water-based graphene conductive anti-corrosion coating and a preparation method thereof. The raw materials include component A and component B; the component A is mainly prepared from the following raw materials in parts by weight: water-based epoxy resin 40-60 parts, 20-60 parts of fillers, 2-4 parts of additives, 10-20 parts of water; the component B is mainly prepared from the following raw materials in parts by weight: 5-10 parts of graphene aqueous dispersion, 10 parts of zinc oxide -20 parts, 40-60 parts of water-based epoxy curing agent; the preparation method of the graphene aqueous dispersion comprises the following steps: mixing graphene, carboxymethyl cellulose and water, shearing and dispersing for 1h-2h, to obtain the mixture; The mixture was sonicated for 3h-4h. The water-based graphene conductive anti-corrosion coating, the solvent is water, energy saving and environmental protection, and the addition of conductive filler graphene and zinc oxide is small, well dispersed in water, and can form a conductive network, has excellent conductive anti-corrosion effect, especially suitable for storage Anticorrosion of tanks, pipelines, underground grids, etc.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to water-based graphene conductive anticorrosion coatings and a preparation method thereof. Background technique [0002] Anti-corrosion coatings are widely used in modern industry, transportation, energy, marine engineering and other departments. With the rapid development of my country's petroleum industry, railway, highway bridge, metallurgical industry, electric power and energy industry, machinery and textile industry, industrial product field, automobile, ship and container, etc., there is an urgent need for continuous innovation in the field of anti-corrosion coatings . In some special fields such as power transportation, storage tanks, and pipelines, on the one hand, it is required that metal materials not only have anti-corrosion properties, but also maintain the electrical conductivity of the material. [0003] Conductivity means that the coating has the ability to condu...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/00C09D5/24C09D5/08C09D7/20
CPCC08K2003/2296C08K2201/001C09D5/08C09D5/24C09D7/20C09D163/00C08K13/06C08K3/042C08K3/22
Inventor 欧阳晓平李伟华孟国哲曹文凯
Owner 泽铱(佛山)工业技术有限公司
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More