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A kind of super amphiphilic neutral metal surface roughening treatment liquid and its preparation method and application

A neutral metal and surface roughening technology, applied in the field of neutral metal surface roughening treatment liquid and its preparation, can solve the problems of not necessarily meeting the coating adhesion requirements, unknown to meet the requirements, insufficient adhesion and other problems , to achieve the effect of improving hydrophilic and lipophilic performance, strong compatibility and high adhesion

Active Publication Date: 2022-01-07
株洲绿智新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But this invention only checks the adhesion of the rubber elastic element bonding material, which belongs to the solvent-diluted oil-based material, and has good bonding and adhesion with conventional metals, while for other such as water-based materials or water-based oil-based mixed materials, This roughening method does not necessarily meet the requirements of coating adhesion; the metals treated by this roughening method are only general steel, stainless steel and aluminum. It is not known whether the roughening effect is uniform and whether the adhesion meets the requirements; for special coating materials with higher adhesion requirements and both water-based and oil-based materials, such as nano-scale high-temperature-resistant and wear-resistant coating materials, the roughening The treatment can only reach the micron size, and the roughening layer does not meet the required micro-nano crystal phase morphology, which will obviously lead to insufficient adhesion; the stronger the acidity of the roughening treatment solution, the better the roughening effect and the shorter the treatment time. However, strong acidity will cause environmental and safety hazards for use and waste liquid post-treatment.

Method used

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  • A kind of super amphiphilic neutral metal surface roughening treatment liquid and its preparation method and application
  • A kind of super amphiphilic neutral metal surface roughening treatment liquid and its preparation method and application
  • A kind of super amphiphilic neutral metal surface roughening treatment liquid and its preparation method and application

Examples

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Embodiment 1

[0076]This embodiment provides a super-amphiphilic neutral metal surface roughening treatment solution, the super-amphiphilic neutral metal surface roughening treatment solution is based on its total mass of 100%, including the following components: Lanification component A 10 %, haze component B 28% and haze component C 62%;

[0077] The dehydration component A includes alkylsiloxane-modified nano silicon dioxide solution and 1-(3-propanesulfonyl)-2-pyrrolidone bisulfate; the dehydration component B includes C14 fatty acid and The hydroalcoholic liquid of C16 fatty acid and 1-(3-propanesulfonyl)-2-pyrrolidone p-toluenesulfonate; Based on the total mass of the metal surface roughening treatment liquid as 100%, the haze component C Including N, N-dimethyl-N-(2-hydroxyethyl) 2-hydroxyhexadecyl quaternary ammonium phosphate (lane accelerator) 2%, DL-sodium malate (lane dispersant) 3 %, polyethylene glycol diglycidyl ether (penetrating agent) 5%, disodium edetate (water softener)...

Embodiment 2

[0088] This embodiment provides a super-amphiphilic neutral metal surface roughening treatment solution, the super-amphiphilic neutral metal surface roughening treatment solution is based on its total mass of 100%, including the following components: Lanification component A 10 %, haze component B18% and haze component C 72%;

[0089] The dehydration component A includes alkylsiloxane-modified nano-silica solution and 1-(3-propanesulfonyl)-2-pyrrolidone trifluoroacetate; the dehydration component B includes C16 Hydroalcoholic liquid of fatty acid and 1-(3-propanesulfonyl)-2-pyrrolidone trifluoromethanesulfonate; based on the total mass of the metal surface roughening treatment liquid as 100%, the haze component C Including N,N-Dimethyl-N-(2-hydroxyethyl) 2-hydroxyhexadecyl quaternary ammonium phosphate (lane accelerator) 5%, dextran sodium sulfate (lane dispersant) 5% %, ethylene glycol diglycidyl ether (penetrating agent) 10%, disodium edetate (water softener) 5%, 1-hydroxyb...

Embodiment 3

[0100] This embodiment provides a super-amphiphilic neutral metal surface roughening treatment liquid, the super-amphiphilic neutral metal surface roughening treatment liquid includes the following components based on its total mass of 100%: Lanification component A 5 %, haze component B 30% and haze component C 65%;

[0101] The dehydration component A includes alkylsiloxane-modified nano-silica solution and 1-(3-propanesulfonyl)-2-pyrrolidone trifluoroacetate; the dehydration component B includes C16 Hydroalcoholic liquid of fatty acid and 1-(3-propanesulfonyl)-2-pyrrolidone p-toluenesulfonate; based on the total mass of the metal surface roughening treatment liquid as 100%, the haze component C includes N,N-Dimethyl-N-(2-hydroxyethyl) cetyl quaternary ammonium phosphate (lane accelerator) 4%, sodium lauryl sulfate (lane dispersant) 8%, butylene glycol Diglycidyl ether (penetrating agent) 5%, trisodium nitrilotriacetate (water softener) 10%, methyl benzotriazole (metal corr...

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Abstract

The invention provides a super-amphiphilic neutral metal surface roughening treatment solution and its preparation method and application. The super-amphiphilic neutral metal surface roughening treatment solution comprises the following components according to its total mass: 2-10% of lyzed component A, 3-30% of lyzed component B and 60-95% of lyzed component C, said lyzed component A includes the nano silicon dioxide solution modified by alkylsiloxane and a mixture of a catalyst, the haze component B includes a mixture of a fatty acid hydroalcoholic liquid and a catalyst. The metal surface roughening treatment liquid described in the present invention realizes the micro-nano-scale roughening of the metal surface through the principle of "binary synergy" of micro-nano materials, and achieves super-hydrophilic and super-oleophilic effects on the surface, and the surface coating material is more compatible , higher metal surface adhesion. The pH of the coarsening treatment liquid in the present invention is neutral, it is environmentally safe, recyclable, can realize zero discharge, and has very broad application prospects.

Description

technical field [0001] The invention relates to the technical field of metal surface engineering materials, in particular to a metal surface roughening treatment liquid and its preparation method and application, in particular to a neutral metal surface roughening treatment liquid with superhydrophilic and superlipophilic effects and its Preparation methods and applications. Background technique [0002] At present, the main ways to improve the adhesion of metal surfaces are: physical mechanical methods, such as shot blasting, sandblasting, etc.; chemical methods, such as pickling and phosphating, silanization, vitrification, etc. The purpose of these several treatment methods is to increase the metal surface adhesion by increasing the specific surface area or increasing the roughness of the metal surface. [0003] Physical mechanical processes such as sandblasting and shot blasting mainly use physical mechanical force to physically strike the metal surface, so that uneven ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F1/14
CPCC23F1/14
Inventor 周建辉廖景文刘文锋邓建青
Owner 株洲绿智新材料科技有限公司
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