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Low-dielectric-constant heat-conducting silica gel sheet and preparation method thereof

A technology of low dielectric constant and thermally conductive silica gel sheet, which is applied in chemical instruments and methods, heat exchange materials, etc., and can solve problems such as difficult industrial production, complicated process, and inability to fill gaps in electronic components.

Inactive Publication Date: 2020-07-07
SUZHOU TIANMAI THERMAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This method has a high thermal conductivity, but the process is complicated, it is difficult to realize industrial production, and the epoxy system has high curing hardness, which is not suitable for thermal interface filling materials. Moreover, the dielectric constant of this method is still greater than 4.0. Cannot meet the requirement of low dielectric constant
Chinese patent document CN 109721750 A discloses a low dielectric constant nano-aramid fiber / boron nitride heat-conducting film and its preparation method. The material obtained by this method has a low dielectric constant, but low thermal conductivity and high hardness. , cannot be applied to high-power heat dissipation components such as chips, let alone fill gaps between electronic components

Method used

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  • Low-dielectric-constant heat-conducting silica gel sheet and preparation method thereof
  • Low-dielectric-constant heat-conducting silica gel sheet and preparation method thereof
  • Low-dielectric-constant heat-conducting silica gel sheet and preparation method thereof

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preparation example Construction

[0036] In addition, the present invention also provides a preparation method of the low dielectric constant thermally conductive silica gel sheet, comprising the following steps:

[0037]S1. Under the condition of 100-180°C, use silane coupling agent to treat the low dielectric constant heat-conducting powder for 2-5 hours;

[0038] S2. At 50-100°C, add vinyl silicone oil to the processed powder and stir for 1-2 hours; after it is uniform, drop to room temperature and add inhibitors, rubber reinforcement additives, and hydrogen-containing silicone oil to continue stirring 0.5-1.5 hours; then add the platinum catalyst and stir evenly, and vacuumize for 0.5-1.5 hours; after pressing to the required thickness, cure at 100-200°C to obtain the low dielectric constant thermally conductive silica gel sheet.

[0039] Further, in step S1, the low dielectric constant thermally conductive powder is processed by using a kneader, a planetary mixer, a dynamic mixer, a high-speed disperser o...

Embodiment 1

[0041] This embodiment provides a low dielectric constant thermally conductive silica gel sheet, the formula of which includes the following components by weight:

[0042]

[0043] The preparation method of the low dielectric constant thermally conductive silica gel sheet of the present embodiment is as follows:

[0044] 1. Use a kneader to treat the mixed powder of boron nitride, silicon micropowder and white carbon black with silane coupling agent KBM5210 at 120°C for 2 hours. The dielectric constant of boron nitride is 3.2, and the average particle size is 180um. Silica powder chooses a powder with a dielectric constant less than 3, and the average particle size is 2um; the specific surface area of ​​white carbon black is 150m 2 / g.

[0045] 2. At 50°C, add vinyl silicone oil with a viscosity of 1000cps and silicone resin with a viscosity of 6000cps to the processed powder and stir for 1 hour; after it is uniform, drop to room temperature and add the inhibitor 3-methyl-...

Embodiment 2

[0048] This embodiment provides a low dielectric constant thermally conductive silica gel sheet, the formula of which includes the following components by weight:

[0049]

[0050] 1. Using a kneader, use the silane coupling agent KBM3103C to treat the mixed powder of boron nitride and aluminum hydroxide for 2 hours at 120°C; the dielectric constant of boron nitride is 3.2, the average particle size is 100um, and aluminum hydroxide Dielectric constant 3.4, average particle size 50um;

[0051] 2. At 50°C, add vinyl silicone oil with a viscosity of 2000cps to the processed powder, and stir for 1 hour; after it is uniform, drop to room temperature and add silicone resin with a viscosity of 6000cps and inhibitor 3,5-dimethyl Base-1-hexyn-3-ol and hydrogen-containing silicone oil with a viscosity of 50cps continue to stir for 0.5 hours; then add a platinum catalyst with a platinum content of 3000ppm and stir evenly, and vacuumize for 0.5 hours; after pressing to the required thi...

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Abstract

The invention discloses a low-dielectric-constant heat-conducting silica gel sheet, which comprises low-dielectric-constant heat-conducting powder, vinyl silicone oil, hydrogen-containing silicone oil, a silicone rubber reinforcing agent, a platinum catalyst, an inhibitor and a silane coupling agent. The low-dielectric-constant heat-conducting powder accounts for 40%-90% of the total mass; the vinyl silicone oil accounts for 4-59% of the total mass; wherein the hydrogen-containing silicone oil accounts for 0.4%-1% of the total mass of the silicone oil, the silicone rubber reinforcing agent accounts for 1%-4% of the total mass of the silicone oil, the platinum catalyst accounts for 0.2%-1% of the total mass of the silicone oil, the inhibitor accounts for 0.01%-0.03% of the total mass of thesilicone oil, and the silane coupling agent accounts for 0.1%-0.6% of the total mass of the heat conduction powder; and the dielectric constant of the low-dielectric-constant heat-conducting powder is less than or equal to 4. The invention further discloses a preparation method of the low-dielectric-constant heat-conducting silica gel sheet. The low-dielectric-constant heat-conducting silica gelsheet not only has the characteristics of high heat conductivity coefficient, low hardness and high insulating strength of a common heat-conducting sheet, but also can be used for thermal interface filling, and has low interference to signals, which is not possessed by the common heat-conducting sheet.

Description

technical field [0001] The invention relates to the technical field of thermally conductive interface materials, in particular to a low dielectric constant thermally conductive silica gel sheet and a preparation method thereof. Background technique [0002] With the miniaturization and continuous improvement of the performance of electronic products, its electronic components are becoming more and more dense, and the transmission and reception, shielding and enhancement of signals are also particularly important. [0003] In order to solve the heat dissipation problem of electronic products, materials such as thermal silica sheet, thermal paste, thermal adhesive, etc. are usually used to fill the interface, so that the heat can be conducted in time. These thermal interface materials usually use aluminum oxide, aluminum nitride, oxide Magnesium, zinc oxide, etc., even carbon fiber, graphene, and these materials are filled with boron nitride, aluminum hydroxide, and silicon di...

Claims

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Application Information

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IPC IPC(8): C08L83/07C08L83/05C08L83/04C08K13/06C08K9/06C08K3/38C08K7/26C08K3/22C08K3/36C08J5/18C09K5/14
CPCC08J5/18C08J2383/07C08J2483/04C08J2483/05C08K3/36C08K7/26C08K9/06C08K13/06C08K2003/2227C08K2003/385C08K2201/003C08K2201/006C09K5/14
Inventor 周腾吴庆迪刘晓阳谢毅
Owner SUZHOU TIANMAI THERMAL TECH
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