Microbial electrochemical systems and methods for controlling production and elimination of hydrogen peroxide
A technology of microbial electrochemistry and hydrogen peroxide, applied in chemical instruments and methods, electrochemical biological combination treatment, biological water/sewage treatment, etc., can solve problems such as poor methylene blue effect, achieve obvious effects, save costs, reduce The effect of consumption
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Embodiment 1
[0086] The schematic diagram of the microbial electrochemical system is shown in image 3 As shown, the H-type dual-chamber BES, the anode chamber 6 and the cathode chamber 7 are composed of a chamber separated by a bipolar membrane 5 (diameter 16mm); the role of the bipolar membrane 5 is to maintain a lower cathode pH and avoid h + Leakage to the anode; the working volume of the anode chamber 6 is 60mL, and the working volume of the cathode chamber 7 is 260mL; the anode 61 in the anode chamber 6 is made of carbon fiber brush (6.0cm diameter, 7.0cm length), pre-heated at 450°C Treated for 30 minutes, then pre-incubated with mature biofilm in the MFC reactor, and then transferred to the BES reactor; two different cathode electrodes were submerged in the cathode chamber 7 of the BES reactor; one was nanocarbon modified The Pt carbon cathode 72 (the projected surface area is 60cm 2 ), the other is a carbon cloth electrode 71 of the same size; the distance between the anode and t...
Embodiment 2
[0089] Adopt the device test of embodiment 1; System performance under different catholyte pH
[0090] Concentration in MB 60mgL -1 , initial Fe 2+ At a concentration of 2.5 mmol / L and an external resistance of 4 Ω, the effect of catholyte pH on MB degradation and residual H 2 o 2 Effect of removal; in MEC mode, the MB degradation efficiency is greatly affected by the pH value in the cathode chamber; the KTOC, decolorization efficiency and TOC removal efficiency increase with the increase of pH value, reaching the maximum at pH = 3.0, respectively value, the optimum pH value of 3.0 observed in this study is consistent with the conventional Fenton method; in addition to the Fenton method, the pH value of the electrolyte in the cathode compartment may affect the H 2 o 2 The electrochemical process; the acidic cathodic chamber electrolyte on the H in BES 2 o 2 generation is beneficial; the pH of the electrolyte in the cathodic chamber not only determines the H 2 o 2 resid...
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