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Quantum dot doped high-brightness polymer dispersed liquid crystal and preparation method thereof

A technology of dispersing liquid crystals and quantum dots, which is applied in the field of high-brightness polymer-dispersed liquid crystals and its preparation, can solve the problems of insufficient color and low brightness, and achieve excellent liquid crystal display effects, excellent curing effects, and simple process effects

Active Publication Date: 2020-10-02
江阴金书简新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since this traditional polymer-dispersed liquid crystal display uses three primary colors to mix according to a certain light intensity ratio to achieve the purpose of display, there are problems such as low brightness and insufficient color.

Method used

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  • Quantum dot doped high-brightness polymer dispersed liquid crystal and preparation method thereof
  • Quantum dot doped high-brightness polymer dispersed liquid crystal and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Example 1: Preparation of quantum dot-doped high-brightness polymer-dispersed liquid crystal sample 1

[0042] First, the transformation method of the hydrothermal kettle with electrocatalytic device: at room temperature, add 1.0g polyvinylidene fluoride to 50mL of N-methyl-2-pyrrolidone solution with a concentration of 0.01g / mL, and keep it at a speed of 500r / min 1h, then add the conductive agent SuperP carbon of 1.0g wherein, keep 1h under the rotating speed of 500r / min, add 8.0g acetylene black under the constant situation of keeping stirring rate, treat that acetylene black adds, continue to stir 2h, again to Add 1g of platinum nanoparticles with a particle size of 100nm to the mixture, stir for 1h, and prepare a mixed slurry; use an automatic coating dryer to evenly smear the slurry on the surface of two high-purity graphite carbon electrode rods with a diameter of 8mm and a length of 120mm. Coating with a thickness of 30 μm, and further drying at 80°C for 24 hours...

Embodiment 2

[0043] Example 2: Preparation of high-brightness polymer-dispersed liquid crystal sample 2 doped with quantum dots

[0044] First, the transformation method of the hydrothermal kettle with electrocatalytic device: at room temperature, add 1.0g polyvinylidene fluoride to 50mL of N-methyl-2-pyrrolidone solution with a concentration of 0.1g / mL, and keep it at a speed of 500r / min 1h, then add 1.0g of conductive agent Super P carbon to it, keep 1h under the rotating speed of 500r / min, add 8.0g acetylene black under the situation of keeping stirring rate constant, treat that acetylene black is added, continue to stir for 2h, then Add 1 g of platinum nanoparticles with a particle size of 50 nm to the mixture, stir for 1 h, and prepare a mixed slurry; use an automatic coating dryer to evenly smear the slurry on the surface of two high-purity graphite carbon electrode rods with a diameter of 8 mm and a length of 120 mm , coated with a thickness of 30 μm, and further dried at 80°C for 2...

Embodiment 3

[0045] Example 3: Preparation of high-brightness polymer-dispersed liquid crystal sample 3 doped with quantum dots

[0046]First, the transformation method of the hydrothermal kettle with electrocatalytic device: at room temperature, add 1.0g polyvinylidene fluoride to 50mL of N-methyl-2-pyrrolidone solution with a concentration of 0.2g / mL, and keep it at a speed of 500r / min. 1h, then add 1.0g of conductive agent Super P carbon to it, keep 1h under the rotating speed of 500r / min, add 8.0g acetylene black under the situation of keeping stirring rate constant, treat that acetylene black is added, continue to stir for 2h, then Add 1 g of platinum nanoparticles with a particle size of 80 nm to the mixture, stir for 1 h, and prepare a mixed slurry; use an automatic coating dryer to evenly smear the slurry on the surface of two high-purity graphite carbon electrode rods with a diameter of 8 mm and a length of 120 mm , coated with a thickness of 30 μm, and further dried at 80°C for 2...

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Abstract

The invention discloses a quantum dot doped high-brightness polymer dispersed liquid crystal and a preparation method thereof, and belongs to the technical field of preparation and application of liquid crystal materials. A liquid crystal thin film sequentially comprises a first transparent conductive glass layer coated with quantum dots, a liquid crystal thin layer doped with the quantum dots anda second transparent conductive glass layer from top to bottom, wherein the first transparent conductive glass layer and the second transparent conductive glass layer are both conductive glass platedwith indium tin oxide, and the conductive surfaces of the first conductive glass and the second conductive glass are opposite. Particularly, the modified quantum dots are prepared by adopting a specially-made hydrothermal kettle with electric catalysis; the polymer dispersed liquid crystal is prepared by a quantum dot doping and ultraviolet light curing method; the technical route has the advantages of being simple in preparation process, small in raw material irritation, suitable for large-scale production and application and the like, the prepared polymer dispersed liquid crystal is high incontrast ratio, high in binding power and free of yellowing, and precious experience is provided for improving the comprehensive performance of the polymer dispersed liquid crystal.

Description

technical field [0001] The patent of the invention belongs to the preparation and application of liquid crystal materials, in particular to a high-brightness polymer-dispersed liquid crystal doped with quantum dots and its preparation method. [0002] technical background [0003] Quantum dots are quasi-zero-dimensional multi-atom materials, also known as "artificial atoms", and their dimensions in three dimensions are only about 1-10nm. This order of magnitude is comparable to the de Broglie wavelength of electrons and holes. quite. According to the relevant theory of quantum mechanics, when the size of a bulk material in a certain dimension is as small as the de Broglie wave wavelength of electrons and holes, the movement of electrons and holes in this dimension will be restricted, that is, subject to quantum constraints. Therefore, materials will exhibit a series of special quantum effects, such as discretization of energy levels, surface effects, quantum tunneling effect...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K19/02C09K19/54G02F1/1334G02F1/1333C09K11/02B01J19/08
CPCC09K19/02C09K19/544C09K19/54G02F1/1334G02F1/1333C09K11/025B01J19/087
Inventor 洪希杭王冬马梦凡
Owner 江阴金书简新材料科技有限公司