Self-healing conductive ionic gel as well as preparation method and application thereof
A conductive ion, self-healing technology, applied in the direction of conductive materials, conductive materials, conductors, etc., can solve the problems of complex preparation process, low mechanical strength, weak tensile performance, etc., achieve high mechanical strength, improve durability and use The effect of life and high stretchability
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Embodiment 1
[0038]The monomer mol ratio of polymer PEO (molecular weight is 100kg / mol) and monomer AA is 1.0:0.6, photoinitiator 2-hydroxyl-4'-(2-hydroxyethoxy)-2-methyl propiophenone ( I2959, 0.01mol% of AA monomer), electrolyte salt LiTFSI (7wt% of the mixed liquid mass), solvent deionized water (water content when the total mass of PAA and PEO polymer accounts for 40% of the mixed liquid mass).
[0039] The above raw materials are mixed, fully dissolved by magnetic stirring, and a clear and transparent mixed solution is obtained. Put the glass bottle containing the mixed solution into a vacuum defoaming mixer for 10 minutes, and then put it into a plexiglass glove box for deaeration (N 2 Environment), to avoid free radical quenching during free radical polymerization, then pour the mixture into a self-made glass plate mold in the glove box, and irradiate crosslinking under ultraviolet light (365nm, 72W) for 1h. After demoulding the cross-linked ion gel, put it in a constant temperatur...
Embodiment 2
[0041] The monomer molar ratio of polymer PEO (molecular weight is 100kg / mol) and monomer AA is 1.0:0.8, all the other parameters and steps are identical with embodiment 1, obtain PAA 0.8 -PEO 100k / 1.0 -7% Li conductive hydrogel.
Embodiment 3
[0043] The monomer molar ratio of polymer PEO (molecular weight is 100kg / mol) and monomer AA is 1.0:1.0, all the other parameters and steps are identical with embodiment 1, obtain PAA 1.0 -PEO 100k / 1.0 -7% Li conductive hydrogel.
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