Laminate, composite polarizing plate and image display device
A composite polarizing and laminated body technology, which is applied in the direction of polarizing elements, lighting devices, layered products, etc., can solve the problems of transparent conductive layer corrosion without countermeasures, and achieve the effect of less change in resistance value
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[0186] Hereinafter, although an Example is given and this invention is demonstrated further concretely, this invention is not limited to these examples. In the examples, parts and % indicating content or usage-amount are based on weight unless otherwise indicated. In addition, the measurement of each physical property in the following example was performed by the following method.
[0187] (1) Determination of thickness:
[0188] Measurement was performed using a digital micrometer "MH-15M" manufactured by Nikon Corporation.
[0189] (2) Determination of moisture permeability of adhesive layer
[0190] A triacetyl cellulose film (TAC film, thickness: 25 μm, manufactured by Konica Minolta Co., Ltd.) was bonded to the adhesive surface of the adhesive sheet (thickness of the adhesive layer: 50 μm) used in the examples. Thereafter, the release film of the pressure-sensitive adhesive sheet was peeled off to obtain a sample for measurement. Then, using this measurement sample, t...
manufacture example 1
[0195] [Manufacturing example 1] Production of polarizing film
[0196] A polyvinyl alcohol film with a thickness of 30 μm (the average degree of polymerization is about 2400, and the degree of saponification is more than 99.9 mol%) is uniaxially stretched to about 4 times by dry stretching. After immersion in water for 40 seconds, it was immersed in an aqueous solution having a weight ratio of iodine / potassium iodide / water of 0.052 / 5.7 / 100 at 28° C. for 30 seconds to perform a dyeing process. Thereafter, it was immersed in an aqueous solution having a weight ratio of potassium iodide / boric acid / water of 11.0 / 6.2 / 100 at 70° C. for 120 seconds. Next, after washing with pure water at 8°C for 15 seconds, it was dried at 60°C for 50 seconds and then at 75°C for 20 seconds while maintaining a tension of 300 N. A polarizing film with a thickness of 12 μm.
manufacture example 2
[0197] [Manufacturing example 2] Production of rubber-based adhesive 1
[0198] 100 parts by weight of polyisobutylene (trade name: OPPANOL B80, Mw: about 750,000, manufactured by BASF Corporation) and tricyclodecane bis(tricyclodecane) as a polyfunctional radical polymerizable compound were adjusted so that the solid content was 15% by weight. Methanol diacrylate (trade name: NK Ester A-DCP, bifunctional acrylate, molecular weight: 304, manufactured by Shin-Nakamura Chemical Industry Co., Ltd.) 10 parts by weight, benzophenone ( A rubber-based adhesive 1 (solution) was prepared using a toluene solution (adhesive solution) of 0.5 parts by weight of Wako Pure Chemical Industries, Ltd. and 10 parts by weight of perhydroterpene phenol.
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