A modified resin material for purifying domestic water and its preparation method

The technology of modified resin and modifier is applied in the field of modified resin material for purifying domestic water and its preparation, which can solve the problems of high fluorine content, unsatisfactory purification effect, difficult treatment, etc. Fields of application and added value, responsive effects

Active Publication Date: 2022-04-26
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a modified resin material for purifying domestic water and its preparation method, through the selective adsorption of fluorine in domestic water, effectively remove fluorine in water, and solve the problem of domestic water in the prior art. High fluorine content, difficult treatment, and unsatisfactory purification effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Mix 94% of polypropylene copolymer, 5% of purification modifier, 0.5% of phenolic heat stabilizer 1010 (Ciba SC), and 0.5% of processing aid calcium stearate in proportion, then add bismuth with an aspect ratio of 38:1 Screw extruder, processing temperature of each section: zone 1 180°C, zone 2 180°C, zone 3 185°C, zone 4 185°C, zone 5 190°C, zone 6 190°C, zone 7 190°C, zone 8 190°C, A modified resin material for purifying domestic water can be obtained by melt extrusion and granulation under the conditions of 190°C in the ninth zone and a screw speed of 250r / min.

[0031] Wherein the purification modifying agent preparation process is as follows:

[0032] Add 200g of divinylbenzene and vinylphenyl-N,N,N-trimethylammonium hydroxide polymer into 6000mL of distilled water at room temperature and stir for 18 hours with a concentration of 2mol / LH 2 SO 4 Adjust the pH of the solution to 1.8; 300g Zr(SO 4 ) 2 4H 2 O was added to the above solution, stirred and reacted fo...

Embodiment 2

[0034] After mixing 90.4% of homopolypropylene, 8% of purification modifier, 0.8% of phenolic heat stabilizer 1076 (Ciba SC), and 0.8% of processing aid calcium stearate, add the Twin-screw extruder, processing temperature of each section: Zone 1 190°C, Zone 2 190°C, Zone 3 190°C, Zone 4 195°C, Zone 5 195°C, Zone 6 195°C, Zone 7 200°C, Zone 8 200°C 1. Under the conditions of 200°C in the ninth zone and 250r / min screw speed, melt extrusion and granulation can obtain a modified resin material for purifying domestic water.

[0035] Wherein the purification modifying agent preparation process is as follows:

[0036] Add 100g of divinylbenzene and vinylphenyl-N,N,N-trimethylammonium hydroxide polymer into 2500mL of distilled water at room temperature and stir for 16 hours, with a concentration of 1.5mol / L H 2 SO 4 Adjust the pH of the solution to 1.6; 180g Zr(SO 4 ) 2 4H 2 O was added to the above solution, stirred and reacted for 4 hours at 28°C, adjusted the pH of the soluti...

Embodiment 3

[0038]Mix 45.2% of copolymerized polypropylene, 50% of homopolypropylene, 4% of purification modifier, 0.4% of phosphite heat stabilizer 168 (Ciba SC), and 0.4% of zinc stearate, a processing aid, and add in proportion A twin-screw extruder with a length-to-diameter ratio of 40:1, the processing temperature of each section: 190°C for the first zone, 190°C for the second zone, 195°C for the third zone, 195°C for the fourth zone, 200°C for the fifth zone, 200°C for the sixth zone, 200°C for the seventh zone Zone 210°C, Zone 8 210°C, Zone 9 210°C, and screw speed 250r / min under the conditions of melt extrusion and granulation to obtain a modified resin material for purifying domestic water.

[0039] Wherein the purification modifying agent preparation process is as follows:

[0040] Add 300g of divinylbenzene and vinylphenyl-N,N,N-trimethylammonium hydroxide polymer into 6600mL of distilled water at room temperature and stir for 20 hours, with a concentration of 2.5mol / L H 2 SO ...

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PUM

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Abstract

The invention discloses a modified resin material for purifying domestic water and a preparation method thereof, which consists of the following components by weight percentage: 88-97.6% of polypropylene; 2-10% of purification modifier; 0.2% of heat stabilizer -1%; processing aid 0.2-1%; the present invention utilizes the selective adsorption of Zr to fluorine to prepare divinylbenzene and vinylphenyl-N,N,N-trimethyl loaded Zr(IV) ammonium hydroxide polymer, and use it as a purification modifier to modify the polypropylene material, and prepare a modified resin material for purifying domestic water with fast adsorption speed and strong adsorption force, and the obtained modified resin material can be used to prepare Domestic water pipes, containers and other products have improved the functionality of polypropylene materials and increased the application fields and added value of polypropylene materials.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a modified resin material for purifying domestic water and a preparation method thereof. Background technique [0002] Water is an important part of the human body. As people pay more and more attention to health and diseases, they pay more attention to water quality. Due to the discharge of fertilizers and industrial waste, as well as the large amount of fluorine in rocks in some parts of northern my country, the fluorine content in tap water is relatively high. Excessive fluoride intake can cause chronic fluorosis in the body and affect the health of bones and teeth. At present, the commonly used technologies for removing fluorine in water include precipitation method and adsorption method, and the precipitation method requires a large amount of precipitant and the sediment will cause secondary pollution. The chemical adsorption method has relatively flexible adsorb...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L23/14C08L25/18C08K5/098C02F1/28C02F101/14
CPCC08L23/14C08L23/12C02F1/288C08L2205/02C08L2205/03C08L2203/18C02F2101/14C08L25/18C08K5/098
Inventor 杨桂生计娉婷朱敏廖雄兵
Owner HEFEI GENIUS NEW MATERIALS
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