Magnetic carbon-supported TiO2 photocatalyst and preparation method thereof
A technology of photocatalyst and magnetic carbon, which is applied in the direction of catalyst activation/preparation, physical/chemical process catalyst, metal/metal oxide/metal hydroxide catalyst, etc. It can solve secondary pollution, weak photocatalytic performance of catalyst, electronic The problem of high probability of hole recombination achieves the effects of mild reaction conditions, suitable for large-scale production, and simple operation
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[0045] The present invention provides the magnetic carbon-supported TiO described in the technical scheme 2 The preparation method of photocatalyst comprises the following steps:
[0046] Carbon-coated Fe prepared by hydrothermal method 3 o 4 ;
[0047] Coating the carbon with Fe 3 o 4 and TiO 2 The sol was mixed, and the magnetic carbon-supported TiO was obtained by ultrasonic 2 catalyst of light.
[0048] The present invention prepares carbon-coated Fe by hydrothermal method 3 o 4 . In the present invention, carbon-coated Fe was prepared by hydrothermal method 3 o 4 , where Fe 3 o 4 There is almost no hysteresis, superparamagnetism, and the carbon material has a positive effect on Fe 3 o 4 The coating effect is good, and the coating rate is high, which is conducive to obtaining magnetic carbon-supported TiO with high photocatalytic performance and recycling rate. 2 catalyst of light.
[0049] In the present invention, the hydrothermal method is specifically ...
Embodiment 1
[0077] (1) Carbon coated Fe 3 o 4 Preparation of:
[0078] Take 0.75g FeCl 3 , 0.5g polyvinylpyrrolidone is placed in 50mL distilled water (the mass ratio of ferric chloride and polyvinylpyrrolidone is 1.5:1, the volume ratio of the total mass of ferric chloride and polyvinylpyrrolidone to water is 1.25g: 50mL ), stirred at a speed of 200r / min for 30min, then added 12.5mL of 80% aqueous solution of hydrazine hydrate and 15mL of 2mol·L -1 Sodium hydroxide solution (the ratio of the amount of ferric chloride to hydrazine hydrate is 1:1, the ratio of the amount of ferric chloride to sodium hydroxide is 1:8, keep at 180°C for 6h, cool, Then centrifuge at 1500r / min for 10min, then alternately wash 3 times with distilled water and absolute ethanol to obtain Fe 3 o 4 ;
[0079] Take 1.35g of glucose and the above Fe 3 o 4 Mixed (carbon source and Fe 3 o 4 The ratio of the amount of the substance is 9:1), add 400mL distilled water, wait for the glucose to dissolve completely...
Embodiment 2
[0087] Using the same raw material and preparation method in Example 1, glucose is replaced by starch, carbon source and Fe 3 o 4 The ratio of the amount of substance is replaced by 18:1.
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