Check patentability & draft patents in minutes with Patsnap Eureka AI!

Magnetic carbon-supported TiO2 photocatalyst and preparation method thereof

A technology of photocatalyst and magnetic carbon, which is applied in the direction of catalyst activation/preparation, physical/chemical process catalyst, metal/metal oxide/metal hydroxide catalyst, etc. It can solve secondary pollution, weak photocatalytic performance of catalyst, electronic The problem of high probability of hole recombination achieves the effects of mild reaction conditions, suitable for large-scale production, and simple operation

Pending Publication Date: 2020-12-18
QINGHAI NORMAL UNIV
View PDF7 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

TiO 2 As a basic N-type semiconductor material, it has a special crystal structure and surface structure, and has the advantages of low price, strong photocatalytic activity, stable chemical properties, wide application range, low dissolution rate and non-toxicity. important raw material, but the TiO 2 There are still some limitations for photocatalysts
[0003] First, TiO 2 Its own band gap is large, and the probability of electron-hole recombination is high during the photoreaction process, which makes the photocatalytic efficiency low and the photocatalytic performance of the catalyst is weak; secondly, TiO 2 The smaller the particle size, the stronger the catalytic performance, but the smaller the particle size of TiO 2 The lighter the quality, the more difficult it is to recycle, the lower the reuse rate, and the incomplete recycling is likely to cause secondary pollution

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Magnetic carbon-supported TiO2 photocatalyst and preparation method thereof
  • Magnetic carbon-supported TiO2 photocatalyst and preparation method thereof
  • Magnetic carbon-supported TiO2 photocatalyst and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0045] The present invention provides the magnetic carbon-supported TiO described in the technical scheme 2 The preparation method of photocatalyst comprises the following steps:

[0046] Carbon-coated Fe prepared by hydrothermal method 3 o 4 ;

[0047] Coating the carbon with Fe 3 o 4 and TiO 2 The sol was mixed, and the magnetic carbon-supported TiO was obtained by ultrasonic 2 catalyst of light.

[0048] The present invention prepares carbon-coated Fe by hydrothermal method 3 o 4 . In the present invention, carbon-coated Fe was prepared by hydrothermal method 3 o 4 , where Fe 3 o 4 There is almost no hysteresis, superparamagnetism, and the carbon material has a positive effect on Fe 3 o 4 The coating effect is good, and the coating rate is high, which is conducive to obtaining magnetic carbon-supported TiO with high photocatalytic performance and recycling rate. 2 catalyst of light.

[0049] In the present invention, the hydrothermal method is specifically ...

Embodiment 1

[0077] (1) Carbon coated Fe 3 o 4 Preparation of:

[0078] Take 0.75g FeCl 3 , 0.5g polyvinylpyrrolidone is placed in 50mL distilled water (the mass ratio of ferric chloride and polyvinylpyrrolidone is 1.5:1, the volume ratio of the total mass of ferric chloride and polyvinylpyrrolidone to water is 1.25g: 50mL ), stirred at a speed of 200r / min for 30min, then added 12.5mL of 80% aqueous solution of hydrazine hydrate and 15mL of 2mol·L -1 Sodium hydroxide solution (the ratio of the amount of ferric chloride to hydrazine hydrate is 1:1, the ratio of the amount of ferric chloride to sodium hydroxide is 1:8, keep at 180°C for 6h, cool, Then centrifuge at 1500r / min for 10min, then alternately wash 3 times with distilled water and absolute ethanol to obtain Fe 3 o 4 ;

[0079] Take 1.35g of glucose and the above Fe 3 o 4 Mixed (carbon source and Fe 3 o 4 The ratio of the amount of the substance is 9:1), add 400mL distilled water, wait for the glucose to dissolve completely...

Embodiment 2

[0087] Using the same raw material and preparation method in Example 1, glucose is replaced by starch, carbon source and Fe 3 o 4 The ratio of the amount of substance is replaced by 18:1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
thicknessaaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention provides a magnetic carbon-loaded TiO2 photocatalyst. The magnetic carbon-loaded TiO2 photocatalyst comprises Fe3O4, a carbon material coated on the surface of the Fe3O4, and TiO2 loadedon the surface of the carbon material. According to the invention, the carbon material is used as a carrier, which is beneficial to TiO2 loading, so that the catalytic performance of the photocatalyst is improved; Fe3O4 is used as a magnetic core, and Fe3O4 and TiO2 are tightly combined together through a carbon material, so that the photocatalyst has relatively strong magnetism, and recycling ofthe photocatalyst is facilitated. Results of the embodiment show that the magnetic carbon-supported TiO2 photocatalyst provided by the invention catalyzes and degrades methylene blue under ultraviolet irradiation, and the degradation rate can reach 99.61%; meanwhile, the recovery rate of the magnetic carbon-supported TiO2 photocatalyst provided by the invention can reach 98.57%, and the magneticcarbon-supported TiO2 photocatalyst still has a good catalytic effect after being recycled for 8 times.

Description

technical field [0001] The invention relates to the technical field of catalysts, in particular to a magnetic carbon-supported TiO 2 Photocatalyst and its preparation method. Background technique [0002] With the increasingly severe environmental and energy problems, more and more researchers have begun to study the photocatalysis of semiconductors to catalyze the oxidation and degradation of harmful and toxic pollutants. TiO 2 As a basic N-type semiconductor material, it has a special crystal structure and surface structure, and has the advantages of low price, strong photocatalytic activity, stable chemical properties, wide application range, low dissolution rate and non-toxicity. important raw material, but the TiO 2 There are also some limitations for photocatalysts. [0003] First, TiO 2 Its own band gap is large, and the probability of electron-hole recombination is high during the photoreaction process, which makes the photocatalytic efficiency low and the photo...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/745B01J37/10B01J37/34
CPCB01J23/745B01J23/002B01J37/10B01J37/343B01J35/33B01J35/39
Inventor 王慧春魏晶晶王志鸽胡樱贾慧萍张浩然甘禹鑫王正莉谢惠春王发春
Owner QINGHAI NORMAL UNIV
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More