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Method for treating urea in reclaimed water

A technology for regenerating water and urea, applied in the field of ultrapure water treatment, can solve the problems of huge area, hydraulic retention time, poor impact resistance, etc., achieve excellent carbon removal and nitrogen removal performance, good hydrophobicity, and improve treatment efficiency Effect

Pending Publication Date: 2021-02-05
CHINA ELECTRONICS SYST ENG NO 2 CONSTR
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Two-stage biological treatment requires huge footprint and hydraulic retention time, and is less impact resistant

Method used

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  • Method for treating urea in reclaimed water
  • Method for treating urea in reclaimed water
  • Method for treating urea in reclaimed water

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach

[0046] As a specific embodiment of the present invention, the regenerated water enters from the lower part of the pool and is discharged from the upper overflow port, the carbon-nitrogen ratio is selected to be 5-7, the hydraulic retention time of the membrane aerated biological reaction tank is 2-4h, and the aeration pressure Controlled at 0.02MPa.

[0047] As a specific embodiment of the present invention, the carbon source should be easily decomposable organic matter, and the carbon source is acetic acid, citric acid organic acid, sodium acetate organic acid salt, methyl alcohol, ethanol alcohols and acetone organic solvents. A sort of.

[0048] As a specific embodiment of the present invention, the heat exchanger in S1 includes a housing 1; one end of the housing 1 is provided with a motor 2; the motor 2 is bolted to one end of the housing 1, and the motor The output shaft of 2 extends into the housing 1, and the end of the output shaft of the motor 2 is provided with a r...

Embodiment 1

[0053] Example 1: In a liquid crystal panel factory, the proportion of reclaimed water in raw water is 55%, and the urea content is as high as 4-5ppm from June to August; the implementation of this case includes the following steps:

[0054] The first step: reclaimed water temperature 20 ℃, flow 450m 3 / h, the water temperature is adjusted to 24°C through the heat exchanger, the heat source temperature is 36°C, and the return water temperature is 30°C;

[0055] Step 2: The heated regenerated water enters the membrane aerated biological reaction tank. The water enters from the lower part of the tank and is discharged from the upper overflow port. The carbon-nitrogen ratio is selected as 6.5. The hydraulic retention time of the membrane aerated biological reaction tank is 2 hours, and the aeration pressure is controlled. At 0.02MPa; the added carbon source is sodium acetate, the nitrogen source is ammonium chloride, and the urea content in the effluent is stable at 0.05-0.1ppm; ...

Embodiment 2

[0059] Example 2: In an electronics factory, the proportion of recycled water in raw water is 40%, and the urea content is as high as 3-3.5ppm from June to August. The implementation of this case includes the following steps:

[0060] The first step: reclaimed water temperature 20 ℃, flow 450m 3 / h, the water temperature is adjusted to 24°C through the heat exchanger, the heat source temperature is 36°C, and the return water temperature is 30°C;

[0061] Step 2: The heated regenerated water enters the membrane aerated biological reaction tank. The water enters from the lower part of the tank and is discharged from the upper overflow port. The carbon-nitrogen ratio is selected as 5.6. The hydraulic retention time of the membrane aerated biological reaction tank is 2 hours, and the aeration pressure is controlled. At 0.02MPa; the added carbon source is citric acid, the nitrogen source is ammonium chloride, and the urea content in the effluent is stable at 0.05-0.1ppm;

[0062] ...

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Abstract

The invention belongs to the technical field of ultrapure water treatment, and particularly relates to a method for treating urea in reclaimed water. The method comprises the following steps that S1,the reclaimed water is fed into a reclaimed water tank, the water in the reclaimed water tank is conveyed through a water pump, and the water temperature is regulated to 23 + / -1 DEG C through a heat exchanger; S2, a biological membrane is arranged in the membrane aeration biological reaction tank, the biological membrane is made of a PVDF material, and screened strains are used in the membrane aeration biological reaction tank; and S3, before the reclaimed water enters a glass filler filter, hydrochloric acid is added to adjust the pH value to 6.5-6.8, a bactericide and a flocculant are addedat the same time, water produced by the glass filler reactor enters a preparation system of an ultrapure water syste, subsequently, the wastewater passes through a cation exchange resin tower, a decarburization acid tower, an anion exchange resin tower, a reverse osmosis membrane, a mixed bed type ion exchange resin tower and a degassing membrane device to be prepared into ultrapure water to be supplied to a water supply point for use.

Description

technical field [0001] The invention belongs to the technical field of ultrapure water treatment, in particular to a method for treating urea in regenerated water. Background technique [0002] In the field of semiconductor, liquid crystal panel and other electronic equipment manufacturing, in order to clean the product, it is necessary to use a large amount of ultrapure water containing a very small amount of impurities, ions and organic substances; among them, in the semiconductor manufacturing process, accompanied by the reduction of semiconductor production , The expansion of the wafer size has put forward higher and higher requirements for the ultrapure water used. [0003] The ultrapure water used in the semiconductor manufacturing process is mainly produced by the ultrapure water manufacturing system, and then supplied to the point of use. The pure water manufacturing system includes: a pretreatment system, a manufacturing system, a polishing system; a pretreatment sy...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14C02F103/04C02F101/34C02F101/38
CPCC02F9/00C02F3/02C02F1/001C02F1/66C02F1/52C02F1/50C02F1/42C02F1/441C02F2103/04C02F2101/38C02F2101/34C02F2305/06Y02W10/10
Inventor 戎宇舟熊江磊陈炜彧罗嘉豪周伟高康张浩马兴峰付至友
Owner CHINA ELECTRONICS SYST ENG NO 2 CONSTR