Full conversion method and device for producing light aromatic hydrocarbon from catalytic diesel oil
A technology that catalyzes diesel and light aromatics. It is applied in the production of bulk chemicals, hydrocarbon oil treatment products, and aromatics hydrogenation refining. Aromatics and other issues
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Embodiment 1
[0139] In this example, the process of preparing light aromatics by catalytic diesel full conversion is as follows figure 1 shown. It includes hydrofining catalytic diesel oil, separating impurities, and selective conversion, and then sending the >210°C heavy tail oil obtained after selective conversion into the post-saturation reaction zone for selective hydrogenation saturation treatment, specifically:
[0140] Wherein the raw material, hydrorefining catalyst, and hydrorefining reaction conditions are the same as Comparative Example 1, and the selective conversion catalyst and reaction conditions are shown in Table 3.
[0141] table 3
[0142]
[0143] Table 3 lists the selective conversion catalyst composition and the reaction conditions employed. Preparation of the selective conversion catalyst: 70wt% zeolite beta (silicon-aluminum molecular ratio SAR=25) and 30wt% alumina are kneaded and extruded to obtain a catalyst carrier. Proper amount of nickel nitrate and ammo...
Embodiment 2
[0154] In this example, the process of preparing light aromatics by catalytic diesel full conversion is as follows figure 1 shown. It includes hydrofining catalytic diesel oil, separating impurities, and selective conversion, and then sending the >210°C heavy tail oil obtained after selective conversion into the post-saturation reaction zone for selective hydrogenation saturation treatment, specifically:
[0155] Wherein the raw material, hydrorefining catalyst, and hydrorefining reaction conditions are the same as Comparative Example 1, and the selective conversion catalyst and reaction conditions are shown in Table 6.
[0156] Table 6
[0157]
[0158] Table 6 lists the selective conversion catalyst composition and the reaction conditions employed.
[0159] Hydrocracking catalyst B3: After fully mixing hydrogen-type mordenite (SAR=45), hydrogen-type zeolite beta (SAR=25), hydrogen-type ZSM-5 (SAR=27) and pseudo-boehmite, kneading and extruding , After drying at 120°C, ...
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