The invention relates to a method for smelting low-silicon pig iron by using iron ore with a complex mineral structure, and belongs to the technical field of ironmaking. The method comprises the following steps of uniformly mixing limonite, nonferrous smelting iron-containing tailings, secondary resources, fine-grained magnetite concentrate, fine-grained vanadium-titanium magnetite concentrate andhematite, piling, taking the uniformly mixed ore in the middle of a material pile, mixing the uniformly mixed ore with SYP synergist, dolomite, limestone, quicklime and coke powder, pelletizing, sintering the obtained pellets to obtain a finished product sinter, crushing, spraying a CaCl2 solution, screening, and blending the sintered ore with the particle size of more than 5mm, the pellet ore and the lump brown iron ore into a blast furnace for blast furnace smelting to obtain a low-silicon qualified pig iron. According to the method, secondary resource reutilization is achieved, on one hand, environmental pollution is reduced, meanwhile, the production cost can be saved, and application and popularization are easy.