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Solid polymer slow-release paraffin control ball and preparation method and use method thereof

A technology of solid polymers and high molecular polymers, which is applied to drilling compositions, chemical instruments and methods, and earthwork drilling and mining, and can solve problems such as large fluctuations in release concentration, fast release speed, and large fluctuations in dosing concentration. , to achieve the effects of high storage stability, safe and convenient transportation, and long effective period

Inactive Publication Date: 2021-02-12
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Adding liquid anti-wax agent to the oil sleeve ring by air will cause a large loss of dosing, and the medicine will gather above the moving liquid surface, which has the disadvantage of not being able to reach the oil-water interface. At the same time, there will be large fluctuations in the concentration of the intermittent dosing and it is difficult to reach the oil pipe only by molecular diffusion. shortcoming
Installing a process string containing solid anti-wax agents downhole can release effective anti-wax components to oil layers and screens, but there are disadvantages such as fast release speed, need to cooperate with workover measures, and large fluctuations in release concentration. Anti-wax adverse effects

Method used

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  • Solid polymer slow-release paraffin control ball and preparation method and use method thereof
  • Solid polymer slow-release paraffin control ball and preparation method and use method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] This embodiment provides a solid polymer slow-release anti-wax ball, which is formed by high-molecular polymer, surfactant, density regulator and oil auxiliary agent through high-temperature and high-pressure blending injection molding, wherein the high-molecular polymer, surface The mass percentages of active agent, density regulator and oil auxiliary agent are 80-95%, 3-10%, 0-2.0% and 0-1.5% respectively.

[0027] The present invention delays and prevents wax deposition on wellbore pipes and rods of oil production wells through the joint action of high molecular polymers and surfactants, wherein the high molecular polymers have long-chain alkyl structures similar to wax molecules, and their polar chain segments are Distort the wax crystal and crystal form, prevent the wax crystal from continuing to grow; the surfactant adsorbs on the surface of the wax crystal or the surface of the wax formation, causing the polarity of the wax crystal surface to reverse, thus playing...

Embodiment 2

[0029] On the basis of Example 1, this example provides a solid polymer slow-release anti-wax ball, which is molded by high-temperature and high-pressure blending injection molding of the following mass percentages: polymer 93%, surfactant 6% , Density regulator 0.5% and oil auxiliary agent 0.5%.

[0030] In this embodiment, the polymer is composed of styrene-maleate copolymer and low-density polyethylene, and the mass percentages are 35% and 58% respectively; the surfactant is an alkyl petroleum sulfonate; The density regulator is potassium chloride; the oil auxiliary agent is industrial grade white oil.

[0031] The preparation process of the solid polymer slow-release anti-wax ball is as follows:

[0032] Mix the high molecular polymer, surfactant and density regulator in the formula quantity, add it to the crusher for crushing, stir evenly, mix the crushed product and oil auxiliary agent into the high-temperature and high-pressure injection molding machine for injection m...

Embodiment 3

[0034] On the basis of Example 1, this example provides a solid polymer slow-release anti-wax ball, which is injection molded by high temperature and high pressure blending with the following mass percentages: 95% polymer, 3.5% surfactant , Oil adjuvant 1.5%.

[0035] In this example, the high molecular polymer is ethylene-vinyl acetate copolymer and low-density polyethylene, and the mass percentages are 46% and 49% respectively; the surfactant is alkyl petroleum sulfonate; the oil auxiliary agent is industrial grade white oil.

[0036] The preparation process of the solid polymer slow-release anti-wax ball is as follows:

[0037] Mix the high molecular polymer and surfactant in the formulated amount and add it to the crusher for crushing, stir evenly, mix the crushed product and oil auxiliary agent and add it to a high-temperature and high-pressure injection molding machine for injection molding (injection temperature 170°C, injection pressure 11MPa), stable After pressing ...

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Abstract

The invention provides a solid polymer slow-release paraffin control ball and a preparation method and a use method thereof. The solid polymer slow-release paraffin control ball is formed by a high-molecular polymer, a surfactant, a density regulator and an oil auxiliary agent through high-temperature and high-pressure blending injection molding, and paraffin precipitation of a wellbore pipe rod of a producing well is delayed and prevented through the combined action of the high-molecular polymer and the surfactant, the high-molecular polymer has a long-chain alkyl structure similar to a wax molecule, and a polar chain link part of the high-molecular polymer enables a wax crystal and a crystal form to be distorted, so that the wax crystal is prevented from continuously depositing and growing; and the surfactant is adsorbed on the wax crystal surface or the wax precipitation surface, so that the polarity of the wax crystal surface is reversed, and the wax control effect is achieved. Thesolid polymer slow-release paraffin control ball is periodically and quantitatively added into an oil jacket annulus from a wellhead manually or in cooperation with automatic filling equipment, can directly reach an oil layer or a designed position, slowly and stably releases effective components in the oil well produced liquid soaking process, prolongs the paraffin removal period, reduces the oil well production cost, and guarantees the production efficiency and the crude oil yield.

Description

technical field [0001] The invention belongs to the technical field of wax deposition prevention and control in well bores of oil production wells, and in particular relates to a solid polymer slow-release anti-wax ball, a preparation method and a use method thereof. Background technique [0002] In the process of oil production, when the temperature of crude oil drops to a certain level, tiny wax crystals will be precipitated, and the wax crystals will combine with each other to form a three-dimensional network space structure, and paraffin will continue to crystallize and accumulate on downhole equipment such as sucker rods and tubing , causing wax deposition, resulting in oil well pump jamming during the production process, increased pumping unit load, difficulty in starting, or even failure to start pumping, increased back pressure, or blockage of gathering and transportation pipelines, which in turn increases the workload of wellbore and pipeline heat cleaning, etc. Mor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): E21B37/06C09K8/524
CPCE21B37/06C09K8/524
Inventor 刘学文刘丹刘伟王鹏程李莉陈栋杨文飞解维涛貟懿徐贵东吕鹏
Owner PETROCHINA CO LTD
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