Wire insulation sheath material with self-repairing function and preparation method thereof
An insulating skin, self-healing technology, applied in the direction of organic insulators, insulators, plastic/resin/wax insulators, etc., can solve the problem of easy expansion of damaged surface of wire insulation skins, and achieve the effect of increasing elasticity and toughness, and repairing external damage.
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Embodiment 1
[0026] (1) Add 45 parts of polydimethylsiloxane to 25 parts of dimethyl sulfoxide, stir and heat to 70°C, then add 25 parts of hexamethylene diisocyanate, heat up to 110°C and react for 6 hours to obtain Polyurethane prepolymer, add 20 parts of polyvinyl chloride successively, 40 parts of chlorinated rubber, continue to react for 4 hours;
[0027] (2) Add 25 parts of 4,4'-diaminodiphenyl disulfide to the reaction system in step (1) successively, raise the temperature to 100°C and react for 8 hours;
[0028] (3) Add 15 parts of activated calcium carbonate, 15 parts of talcum powder, 15 parts of alumina and 6 parts of phosphoric acid ester to the system after the reaction in step (2), and stir at 110°C for 5 hours to obtain the wire insulation sheath material.
Embodiment 2
[0030] (1) Add 45 parts of polydimethylsiloxane to 20 parts of N,N-dimethylacetamide, stir and heat to 60°C, add 20 parts of methylene diphenyl diisocyanate, and heat up to 100°C React for 8 hours to obtain the polyurethane prepolymer, add 25 parts of polyvinyl chloride and 40 parts of chlorinated rubber successively, and continue to react for 5 hours;
[0031] (2) Add 20 parts of 4,4'-diaminodiphenyl disulfide to the system in step (1) sequentially, and raise the temperature to 110°C for 6 hours;
[0032] (3) Add 20 parts of activated calcium carbonate, 10 parts of talcum powder, 10 parts of alumina and 8 parts of phosphite to the system after the reaction in step (2), and stir at 110°C for 5 hours to obtain the wire insulation sheath material.
Embodiment 3
[0034] (1) Add 50 parts of polydimethylsiloxane to 30 parts of N,N-dimethylformamide, stir and heat to 80°C, add 20 parts of hexamethylene diisocyanate and 10 parts of toluene diisocyanate, Raise the temperature to 120°C and react for 6 hours to obtain the polyurethane prepolymer, add 15 parts of polyvinyl chloride and 30 parts of chlorinated rubber in sequence, and continue to react for 3 hours;
[0035] (2) Add 30 parts of 2,2'-dithiodiethanol to the system in step (1) successively, raise the temperature to 120°C and react for 5 hours;
[0036] (3) Add 10 parts of activated calcium carbonate, 20 parts of talcum powder, 20 parts of alumina and 5 parts of phosphoric acid ester to the system after the reaction in step (2), stir at 110°C for 5 hours to obtain the wire insulation sheath material.
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