Recycling method of inactivated non-noble metal vinyl chloride catalyst carrier
A catalyst carrier, non-precious metal technology, applied in chemical recovery, application, solid/semi-solid fertilizer and other directions, can solve the problems of cumbersome process steps, failure to realize the reuse of activated carbon carrier, low energy efficiency ratio, etc.
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Embodiment 1
[0049] A recovery and reuse method for a deactivated non-noble metal vinyl chloride catalyst carrier, comprising pretreatment, activation, primary loading, granulation and coating.
[0050] The pretreatment includes drying under reduced pressure, advanced treatment, washing and drying.
[0051] The decompressed drying is to collect the deactivated non-precious metal activated carbon catalyst in the process of preparing vinyl chloride by calcium carbide method, put it into a closed container, reduce the pressure to -0.07MPa, and heat up to 160°C for drying. The drying time is 4h, until the non-precious metal activated carbon The water content of the catalyst is less than 2%.
[0052] The advanced treatment includes pretreatment, pickling and alkali washing.
[0053] (1) Pretreatment, put the dried non-precious metal activated carbon catalyst into 2 times the volume of 95% ethanol for impregnation, raise the temperature to 35°C, stir at a speed of 50RPM, and stir for 30min; fil...
Embodiment 2
[0091] A recovery and reuse method for a deactivated non-noble metal vinyl chloride catalyst carrier, comprising pretreatment, activation, primary loading, granulation and coating.
[0092] The pretreatment includes drying under reduced pressure, advanced treatment, washing and drying.
[0093] The decompression drying is to collect the deactivated non-precious metal activated carbon catalyst in the process of preparing vinyl chloride by calcium carbide method, put it into a closed container, reduce the pressure to -0.08MPa, and heat up to 170°C for drying. The drying time is 4h, until the non-precious metal activated carbon The water content of the catalyst is less than 2%.
[0094] The advanced treatment includes pretreatment, pickling and alkali washing.
[0095] (1) Pretreatment, put the dried non-precious metal activated carbon catalyst into 3 times the volume of 95% ethanol for impregnation, raise the temperature to 40°C, stir at 60RPM, and stir for 40min; filter out so...
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