Compound, display panel and display device
A compound and organic technology, applied in the field of display panels, display devices, and compounds, can solve the problems of low luminous efficiency and achieve high luminous efficiency, improved solubility, and good hole transport ability
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Embodiment 1
[0175] Embodiment 1: the preparation of compound H1
[0176] (1)
[0177] Under a nitrogen atmosphere, add about 100mL of anhydrous toluene to a 250mL reaction flask, then sequentially add compound A1 (4mmol), compound a1 (4mmol), sodium tert-butoxide t-BuONa (10mmol), catalyst tris(dibenzylideneacetone ) Dipalladium Pd 2 (dba) 3 (0.2mmol) and the ligand 2-bicyclohexylphosphine-2',6'-dimethoxybiphenyl S-Phos (0.6mmol), heated to 110°C and reacted overnight. After the reaction is complete, cool to room temperature, add dichloromethane DCM / H 2 O was extracted, and the collected organic phase was washed with anhydrous Na 2 SO 4 After drying, the filtrate was collected by suction filtration, the solvent was spun off and purified by column chromatography to obtain intermediate compound B1 (yield 80%).
[0178] MALDI-TOF (m / z): C31H20BrN: Calculated: 485.08, Found: 485.30.
[0179] (2)
[0180] Under a nitrogen atmosphere, compound B1 (1 mmol) was added to anhydrous tetr...
Embodiment 2~10
[0187] Embodiment 2~10: the preparation of compound H2~H10
[0188] The difference between the preparation method of compounds H2-H10 and Example 1 is that one or more of the raw material compounds C1 and c1 in step 3 was replaced to finally obtain the corresponding compounds, see Table 1 for details.
[0189] The raw material compounds C2 and C3 in Table 1 were prepared by referring to the preparation method of compound C1.
[0190] The difference is: in the preparation of compound C2, compound b1 is replaced by b2. The yield of compound C2 was 65%. MALDI-TOF (m / z): C44H27NS: Calculated: 601.19, Tested: 601.40.
[0191]
[0192] In the preparation of compound C3, compound b1 was replaced by b3. The yield of compound C3 was 63%. MALDI-TOF (m / z): C50H32N2: Calculated: 660.26, Tested: 660.45.
[0193]
[0194] Table 1: Synthetic parameters of compounds H2-H10
[0195]
[0196]
[0197] Simulated calculation of energy levels of compounds: using density functiona...
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