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Xylooligosaccharide prepared from corn straw pulp cores and method thereof

A technology of corn stalks and xylo-oligosaccharides, which is applied in the preparation of oligosaccharides and sugar derivatives, chemical instruments and methods, etc., can solve the problems of cumbersome production process of xylo-oligosaccharides, and achieve the convenience of industrial production and simple operation process , the effect of improving the efficiency of enzymatic hydrolysis

Active Publication Date: 2021-04-30
BEIHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problems of tedious process and low yield in traditional xylo-oligosaccharide production and processing methods, the present invention provides a kind of xylo-oligosaccharide prepared from corn stalk pith. The mass concentration of the xylo-oligosaccharide is 21.5-23.6g / mL. The invention also discloses the preparation method of the above-mentioned xylo-oligosaccharides, which effectively improves the yield of xylo-oligosaccharides through steps such as pulverization, heteropoly acid pretreatment, enzyme hydrolysis, enzyme inactivation and purification, and solves the problem of traditional technology The cumbersome production process of xylo-oligosaccharides

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Dry, mold-free corn stalks were selected for dehulling and peeling to obtain corn stalk pith, which was crushed, washed, and dried in an oven at 45°C to constant weight for use. Take 5g of dried corn stalk core powder, add 75mL of deionized water, add solid heteropoly acid-phosphotungstic acid with a mass of 0.01g~0.1g and mix evenly for pretreatment. The reaction temperature is 75°C and the reaction time is 3h , down to room temperature after the reaction. Use 3 times the volume of 95% ethanol, let it stand overnight, filter under reduced pressure, and collect the filtrate; carry out enzymatic hydrolysis on the collected filtrate, add 500IU / g xylanase, and the enzymatic hydrolysis time is 6h, to obtain the enzymatic hydrolysis solution; The enzymolysis solution is treated with enzyme inactivation, and the enzymolysis solution is incubated at 100°C for 10 minutes to inactivate the enzyme, and then centrifuged in a high-speed centrifuge at 4000rpm for 15 minutes to remov...

Embodiment 2

[0035] Dry, mold-free corn stalks were selected for dehulling and peeling to obtain corn stalk pith, which was crushed, washed, and dried in an oven at 45°C to constant weight for use. Take 5g of dried corn stalk core powder, add 75mL of deionized water, add solid heteropoly acid-phosphotungstic acid with a mass of 0.08g and mix evenly for pretreatment. The reaction temperature is 55℃~95℃, and the reaction time is 3h , down to room temperature after the reaction. Use 3 times the volume of 95% ethanol, let it stand overnight, filter under reduced pressure, and collect the filtrate; carry out enzymatic hydrolysis on the collected filtrate, add 500IU / g xylanase, and the enzymatic hydrolysis time is 6h, to obtain the enzymatic hydrolysis solution; The enzymolysis solution is treated with enzyme inactivation, and the enzymolysis solution is incubated at 100°C for 10 minutes to inactivate the enzyme, and then centrifuged in a high-speed centrifuge at 4000rpm for 15 minutes to remove...

Embodiment 3

[0039] Dry, mold-free corn stalks were selected for dehulling and peeling to obtain corn stalk pith, which was crushed, washed, and dried in an oven at 45°C to constant weight for use. Take 5g of dried corn stalk core powder, add 75mL of deionized water, add solid heteropoly acid-phosphotungstic acid with a mass of 0.08g and mix evenly for pretreatment. The reaction temperature is 75°C, and the reaction time is 1-4h. Cool down to room temperature after the reaction. Use 3 times the volume of 95% ethanol, let it stand overnight, filter under reduced pressure, and collect the filtrate; carry out enzymatic hydrolysis on the collected filtrate, add 500IU / g xylanase, and the enzymatic hydrolysis time is 6h, to obtain the enzymatic hydrolysis solution; The enzymolysis solution is treated with enzyme inactivation, and the enzymolysis solution is incubated at 100°C for 10 minutes to inactivate the enzyme, and then centrifuged in a high-speed centrifuge at 4000rpm for 15 minutes to rem...

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Abstract

The invention relates to the field of xylooligosaccharide, in particular to a method for preparing xylooligosaccharide from corn stalk pith cores, and aims to realize high-value utilization of corn stalks. According to the method, corn straw pith cores are adopted as a raw material, and xylooligosaccharide is prepared by combining solid heteropolyacid with an enzymolysis method; the acidity and oxidizability of the solid heteropolyacid are utilized to enhance the depolymerization effect of the lignocellulose raw material, and then the depolymerization effect is combined with an enzyme hydrolysis method, so that the enzyme hydrolysis efficiency and the directional hydrolysis capability are greatly improved, and the yield of xylooligosaccharide is remarkably improved. The method disclosed by the invention is simple in preparation process, mild in reaction condition and environment-friendly, the obtained xylooligosaccharide is high in purity and high in yield, the dosage of enzyme is small in the subsequent enzymolysis method, and the cost is saved.

Description

technical field [0001] The invention belongs to the technical field of xylo-oligosaccharide production and processing, and in particular relates to a method for preparing xylo-oligosaccharide from corn stalk pith. Background technique [0002] Agricultural and forestry biomass materials such as corn stalks, wheat stalks, corncobs, bagasse, straw, bamboo, etc., have potential utilization value in many aspects. Some countries have made great achievements in using these biomass by-products to manufacture high value-added products. my country is a large agricultural country, and corn is one of the food crops in my country, which has abundant resources. Corn stalk husks are widely used in the fields of glulam and particleboard, but the resulting pith has not been fully utilized. Using corn stalks as raw materials to develop some new uses, such as the preparation of functional xylooligosaccharides, not only makes full use of corn stalks, but also increases farmers' income, which...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P19/14C12P19/12C12P19/04C12P19/00C07H1/06C07H3/06C07H3/04
CPCC12P19/14C12P19/12C12P19/04C12P19/00C07H1/06C07H3/06C07H3/04Y02P60/87
Inventor 时君友潘晴徐文彪段喜鑫
Owner BEIHUA UNIV