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Preparation method for preparing isobutanol and high-octane gasoline component oil

A technology for high-octane gasoline and isobutanol, which is applied in the preparation of organic compounds, the preparation of liquid hydrocarbon mixtures, chemical instruments and methods, etc., can solve the problems of reducing the quality of the environment, high cost of use, polluting the environment, etc. To achieve the effect of reducing vehicle exhaust emissions, improving quality and improving safety

Inactive Publication Date: 2021-05-07
上海禹岩化工科技中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Most of the existing petroleum is imported, and the cost of use is relatively high. In the preparation process of the existing gasoline preparation process, MTBE is used as a raw material that is carcinogenic. After leakage, it is easy to dissolve with groundwater and pollute the environment, reducing the environmental impact. high quality, low security

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Isobutanol and high-octane gasoline component oil raw materials: 700-970 parts by weight of methanol, 10-30 parts by weight of chain extender, 30-300 parts by weight of naphtha, and 1-3 parts by weight of catalyst molecular sieve.

[0026] The method for preparing above-mentioned isobutanol and high-octane gasoline component oil may further comprise the steps:

[0027] Step 1: Add 1%~3% of the chain extender nano light-burned basic magnesia to 99.9% coal-to-methanol at room temperature, stir and mix for 2 hours, stand still and continue to react for 24 hours, and partially react into isopropanol and Isobutanol.

[0028] Step 2: Add the straight distilled naphtha from crude oil with a distillation range of 70-170°C and an octane number of about 60 to the mixed liquid that has been reacted with light-burned basic magnesium oxide extender and 99.9% coal-to-methanol, and heat 90-100 ° C to make a mixed gas;

[0029] Step 3: The mixed gas is reacted with a molecular formul...

Embodiment 2

[0031] Isobutanol and high-octane gasoline component oil raw materials: 800 parts by weight of methanol, 30 parts by weight of chain extender, 200 parts by weight of naphtha, and 2 parts by weight of molecular sieve catalyst.

[0032] Step 1: Add 1%~3% of the chain extender nano light-burned basic magnesia to 99.9% coal-to-methanol at room temperature, stir and mix for 2 hours, stand still for 24 hours, and partially make isopropanol and Isobutanol;

[0033] The second step: add hydrogenated naphtha to the methanol mixture after the reaction of nano light-burned basic magnesium oxide, and heat it to 90-100°C to make a mixed gas;

[0034] The third step: the mixed gas is reacted with ZSM-5 zeolite solid acid catalyst to produce 4.6% isopropanol, 40% isobutanol, 27% light aromatics and 22% isoparaffins, and the product yield is 93.6%.

Embodiment 3

[0036] Isobutanol and high-octane gasoline component oil raw materials: 700 parts by weight of methanol, 30 parts by weight of chain extender, 300 parts by weight of light hydrocarbons, and 2 parts by weight of molecular sieve catalyst.

[0037] The first step: add 1%~3% of the chain extender nano light-burned basic magnesium oxide to 99.9% coal-based methanol at room temperature, stir and mix for 2 hours, and continue to react for 24 hours to make a mixture containing part of isopropanol and In modified methanol of isobutanol;

[0038] Step 2: Add the light hydrocarbons separated from the natural gas condensate into the 99.9% coal-to-methanol mixture that has been reacted with nano light-burned basic magnesium oxide, and heat it to 90-100°C to make a mixed gas;

[0039] The third step: the mixed gas is catalyzed by ZSM-5 zeolite solid acid fixed bed to produce oil containing 4.6% isopropanol, 45% isobutanol and 47% light aromatics, isoparaffins, and high-octane gasoline compo...

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PUM

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Abstract

The invention discloses a preparation method for preparing isobutanol and high-octane gasoline component oil, which is prepared from the following raw material components in parts by weight: 700 parts-970 parts by weight of methanol, 10 parts-30 parts by weight of a chain extender, 30 parts-300 parts by weight of naphtha and 1 part- parts by weight of a catalyst molecular sieve, methanol, the chain extender, naphtha and the catalyst molecular sieve react to prepare isobutanol and gasoline, the problem of petroleum import is reduced, the use cost is reduced, methanol is prepared from coal-made carbon monoxide and hydrogen through a reaction, automobile exhaust emission is reduced, the problem that a raw material MTBE adopted in a traditional gasoline preparation method has carcinogenicity is solved, the environment pollution caused by the raw material leakage can be prevented, the environment quality is improved, the preparation safety is improved, the naphtha can be the light hydrocarbon separated from the natural gas condensate oil and the naphtha hydrogenated from the coal tar, the raw material source is wide, and the preparation cost is reduced.

Description

technical field [0001] The invention relates to the technical field of fine chemicals, in particular to a method for preparing isobutanol and high-octane gasoline component oil. Background technique [0002] In recent years, the country has attached great importance to environmental protection and gradually reduced the use of methyl tert-butyl ether in gasoline as a gasoline antiknock agent. Methyl tert-butyl ether (MTBE) is carcinogenic. After leakage, it will dissolve in groundwater and pollute groundwater. It cannot be degraded for decades. The United States and some European countries have banned the use of MTBE in gasoline. The practical value of isobutanol as a gasoline antiknock agent instead of MTBE and ethanol has doubled. At the same time, isobutanol is an important chemical basic raw material with high economic value. The development prospects are quite good. In 2020, the national methanol production capacity will be about 95 million tons. In 2019, the annual c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C29/34C07C31/10C07C31/12C10G3/00
CPCC07C29/34C10G3/42C10G2300/305C07C31/10C07C31/12Y02P30/20
Inventor 赵鉴明
Owner 上海禹岩化工科技中心