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Efficient alkoxylated imidazoline derivative corrosion inhibitor as well as preparation method and application thereof

A technology of chemical imidazoline and rust inhibitor, which is applied in the field of preparation of high-efficiency alkoxylated imidazoline derivative rust inhibitor, can solve problems such as environmental and health damage, nitrite toxicity, and weak rust inhibitory effect, and achieve Increase steric resistance, prevent slump loss, and improve service life

Active Publication Date: 2021-06-01
SHENYANG POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Some oxide film-type rust inhibitors such as potassium dichromate will reduce the compressive strength of concrete more (20%-40%), while stannous chloride has a shorter action time. The commonly used rust inhibitors are sodium nitrite and nitrite Although calcium nitrate has little effect on the strength of concrete and has a good anti-rust effect, they only have anti-rust effect when used in a large amount, and nitrite is toxic and has certain damage to the environment and health. Banned in some countries
Precipitated film-type rust inhibitors such as glycerophosphate sodium salt and hydroxyphosphate often have weak binding force with metals, and the texture is porous and loose, so their anti-rust effect is weaker than that of oxidized film layers.

Method used

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  • Efficient alkoxylated imidazoline derivative corrosion inhibitor as well as preparation method and application thereof
  • Efficient alkoxylated imidazoline derivative corrosion inhibitor as well as preparation method and application thereof
  • Efficient alkoxylated imidazoline derivative corrosion inhibitor as well as preparation method and application thereof

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preparation example Construction

[0017] The present invention also provides a method for preparing a high-efficiency alkoxylated imidazoline derivative rust inhibitor, comprising the following steps

[0018] (1) Mix the fatty acid containing 16 to 20 carbon atoms and hydroxyethylethylenediamine into the reaction kettle, and add xylene as a water carrier, dehydrate and stir the reaction at a certain temperature, and decompress after the reaction Remove xylene to obtain imidazoline derivative intermediate;

[0019] (2) Take a certain amount of imidazoline derivative intermediate into an autoclave, add a certain amount of propylene oxide first under high pressure and a certain temperature, then add a certain amount of ethylene oxide, and obtain the final product after aging.

[0020] The fatty acid is one of hexadecadienoic acid, oleic acid or linoleic acid, linolenic acid, octadecadienoic acid, eicosatrienoic acid or eicosapentaenoic acid. Fatty acid and hydroxyethylethylenediamine are mixed according to the m...

Embodiment 1

[0023] (1) Mix 0.5mol oleic acid with 0.525mol hydroxyethylethylenediamine, add 75g of xylene, react and dehydrate at 160-180°C until the water output is 0.45-0.5mol water, then heat up to 210-230°C for reaction Dehydration until the water yield is 0.45-0.5 mol of water, and xylene is removed under reduced pressure after the reaction is completed.

[0024] (2) Take 0.5 mol of the imidazoline derivative intermediate into the autoclave, first add 0.5 mol of propylene oxide, then add 25 mol of ethylene oxide, and obtain the final product after aging.

[0025] (3) The prepared saturated Ca(OH) containing 1.15% NaCl 2 Pour the solution into three glass ground-mouth bottles, add 0.3% of the above-mentioned rust inhibitor, put a steel bar into the solution, and close the bottle cap tightly. Use a voltmeter to measure the natural potential of the steel bar at 1d, 3d, 5d, and 7d respectively, and compare it with the blank.

Embodiment 2

[0027] (1) Mix 0.5mol linoleic acid with 0.54mol hydroxyethylethylenediamine, add 82g of xylene, react and dehydrate at 160-180°C until the water output is 0.45-0.5mol water, and then heat up to 210-230°C The reaction is dehydrated until the water output is 0.45-0.5mol water, and the xylene is removed under reduced pressure after the reaction is completed.

[0028] (2) Take 0.5 mol of the imidazoline derivative intermediate into the autoclave, first add 1 mol of propylene oxide, then add 30 mol of ethylene oxide, and obtain the final product after aging.

[0029] (3) The prepared saturated Ca(OH) containing 1.15% NaCl 2 Pour the solution into three glass grinding bottles, add 0.6% of the above-mentioned rust inhibitor, put a steel bar into the solution, and close the bottle cap tightly. Use a voltmeter to measure the natural potential of the steel bar at 1d, 3d, 5d, and 7d respectively, and compare it with the blank.

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Abstract

The invention discloses application of an efficient alkoxylated imidazoline derivative corrosion inhibitor. When the efficient alkoxylated imidazoline derivative corrosion inhibitor is used, standard cement, standard sand, water and the corrosion inhibitor are mixed in proportion, stirred uniformly, compacted until slurry is returned, and then inserted into a steel bar, and corrosion inhibitor molecules are adsorbed to the surface of the steel bar through diffusion to play a role in corrosion inhibition. Due to the introduction of an alkoxy chain segment, the molecules have the structure of a polycarboxylic acid water reducer monomer, the compatibility of the corrosion inhibitor molecules and concrete can be realized to the greatest extent, the physical and chemical properties of the concrete cannot be seriously influenced, the steric hindrance of the molecules can be increased, the immersion of chloride ions can be blocked, the effect of dispersing the concrete can be achieved, the slump loss of the concrete is prevented, obvious delayed coagulation is not caused, and the service life of the steel bar in an erosion environment can be prolonged to a great extent.

Description

technical field [0001] The invention relates to the technical field of rust inhibitors, in particular to a preparation method of a high-efficiency alkoxylated imidazoline derivative rust inhibitor and its application in reinforced concrete. Background technique [0002] Reinforced concrete is a building material widely used in modern society. It is used in the construction of structures in all walks of life and plays a great role in the construction of the national economy. However, due to the aggravation of environmental pollution and other reasons, reinforced concrete structures often begin to show cracks, corrosion of steel bars and other deterioration phenomena after a short period of use. The premature failure of reinforced concrete structures caused by corrosion of steel bars is a prominent disaster in the world today. Therefore, preventing the corrosion of steel bars from the source becomes the key, among which the use of steel bar rust inhibitor is the most convenie...

Claims

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Application Information

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IPC IPC(8): C04B24/32C04B28/00C08G65/28C04B103/61C04B111/20
CPCC04B24/32C04B28/00C08G65/263C04B2103/61C04B2111/20C04B14/06C04B32/02
Inventor 杨振声杨健张晓娟贾长英邹明旭王永杰
Owner SHENYANG POLYTECHNIC UNIV
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