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Bionic marine antifouling skin and preparation method thereof

A marine anti-fouling and skin technology, applied in the field of bionic materials, can solve the problems of reduced application value, micro-nano structure damage to anti-fouling performance, failure, etc., and achieve the effect of strong anti-fouling ability

Active Publication Date: 2021-06-04
JILIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the new non-toxic anti-fouling and anti-corrosion technologies include low surface energy type, micro-nano structure bionic type, etc. However, the adhesion between the low-surface coating and the substrate is poor, and the micro-nano structure of the micro-nano structure bionic coating is easy to be damaged in complex and harsh environments. The anti-fouling performance will be invalid if it is destroyed, so that their application value will be greatly reduced.
Biomimetic super slippery surface (SLIPS) is a new type of high-efficiency and green antifouling technology. SLIPS is a binary surface composed of lubricating fluid / porous microstructure. The currently reported SLIPS is easy to lose under the action of fluid erosion and long-term Poor use stability and poor adhesion on the substrate, these shortcomings limit their engineering applications

Method used

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  • Bionic marine antifouling skin and preparation method thereof
  • Bionic marine antifouling skin and preparation method thereof
  • Bionic marine antifouling skin and preparation method thereof

Examples

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Embodiment 1

[0033] (1) Preparation of biomimetic microcapsules

[0034] The natural polymer calcium alginate is used as the wall material, and the silicone oil or edible oil is used as the core material to prepare biomimetic microcapsules to simulate the secretion of coral mucus. First, silicone oil or edible oil is added to a certain amount of deionized water and a surfactant (such as Span 80), and the mass fraction of the surfactant is 5 to 20 wt%, and then magnetically stirred for a certain period of time (5 minutes to 1 hour) to prepare the oil / Water emulsion, then add calcium alginate solution (mass ratio of calcium alginate to silicone oil / edible oil ranges from 2:1 to 0.5:1) and sonicate for 1 hour, then slowly add 3 to 5% calcium chloride The solution was magnetically stirred, and the formation of capsules was observed under a microscope. After a large number of capsules were formed, the obtained solution was moved into a vacuum drying oven to dry in vacuum for several hours, and...

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PUM

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Abstract

The invention discloses a bionic marine antifouling skin and a preparation method thereof, and belongs to the technical field of bionic materials. The bionic marine antifouling skin is composed of a bottom layer, a porous microstructure layer, microcapsules, coral-imitating tentacles and coral-imitating mucus; the bottom layer is formed by compounding silicone rubber and polyurethane, and the thickness of the bottom layer is 1-5 mm; the porous structure layer is made of a silicon rubber material, and the thickness of the porous structure layer is 1-5mm; the aperture of the porous structure is 1-100mu m, and the porous structure layer also comprises 1-3wt% of microcapsules, wherein the microcapsules wrap silicone oil or edible oil; the surface of the porous structure layer is also provided with coral-imitating tentacles, the coral-imitating tentacles are made of silicon rubber, the tentacles are trapezoidal cylinders or circular truncated cones, the height h of the tentacles is 5-15mm, the distance a of circle centers of the tentacles ranges from 1 mm to 5 mm, and the ratio m: n of the diameter of the tail ends of the tentacles to the diameter of the bottoms of the tentacles ranges from 0.5 to 0.8; and the coral-imitating mucus is silicone oil or edible oil and is coated on the surface of the porous structure layer. The material has the characteristics of strong adsorption and antifouling property, and by adding the microcapsule, the stability of SLIPS is improved.

Description

technical field [0001] The invention belongs to the technical field of bionic materials. Background technique [0002] Marine biofouling refers to a phenomenon in which fouling organisms in the ocean such as bacteria, algae, and barnacles adhere to underwater surfaces. Any surface immersed in the ocean is affected by marine biofouling. When marine biofouling occurs, it will gradually accumulate on the underwater surface, resulting in an increase in surface roughness, resulting in an increase in the sailing resistance of the hull. In order to maintain the speed, more fuel consumption is required, which directly brings about an increase in transportation costs. . Excess fuel use also enhances CO 2 , SO 2 Emissions of greenhouse gases, leading to the greenhouse effect. Biofouling will also accelerate the corrosion of underwater surfaces, causing surface damage, affecting the safety of equipment and facilities in the ocean, and increasing maintenance costs. Marine biofoulin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/36C08J7/04C08L83/04C08L5/04C08L91/06C08J9/26C09D183/04C09D175/04C09D5/16C09D191/00
CPCC08J9/365C08J7/04C08L83/04C08J9/26C09D183/04C09D175/04C09D191/00C09D5/1675C09D5/1662C09D5/1656C09D5/1693C08L2205/03C08L2205/025C08J2383/04C08J2483/04C08J2475/04C08J2491/00C08J2405/04C08J2201/0422C08J2201/0444C08L5/04C08L91/06C08L75/04
Inventor 田丽梅靳会超王建福殷玥高铭谣商延赓赵杰孙霁宇
Owner JILIN UNIV
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