Repairing agent, and method for stably repairing mercury-polluted soil by adopting repairing agent
A restoration agent and soil technology, applied in the field of contaminated soil treatment and restoration, can solve the problems of small amount of mercury-contaminated soil, low concentration of mercury content, low technical threshold, etc., and achieve the effect of low price, low acid leaching concentration, and easy promotion
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Embodiment 1
[0062] (1) Collect mercury-contaminated soil, remove stones and plant rhizomes, crush them, mix them evenly, and air-dry them naturally (select samples to measure their moisture content), pass through an 80-mesh sieve after grinding, and weigh 24 parts after fully mixing Samples, 3 samples are used as blank samples, 21 samples are used as processed samples, each sample is accurate to 200.0g, and the test processing steps are shown in Table 1.
[0063] (2) Determination of blank sample CK 1 、CK 2 、CK 3 The total amount of mercury pollution and acid leaching concentration.
[0064] (3)CK 1 、CK 2 、CK 3 The average value of mercury content in the sample is 2403mg / kg. According to the calculation of the molar ratio S:Hg, empirical parameter ratio, etc., the added quality of calcium polysulfide, ferrous sulfate, humic acid powder in each sample, calcium polysulfide water agent The active ingredient content is about 29%, so the mass percent of calcium polysulfide, ferrous sulfa...
Embodiment 2
[0068] (1) On-site excavation of 10 square meters (m 3 ) Mercury polluted soil, soil density is 1.8g / cm 3 After mechanical stirring and mixing, 6 mixed samples were collected to determine the total amount of mercury pollution and acid leaching concentration.
[0069] (2) Obtaining the average concentration of mercury content in the mercury-contaminated soil by the data is 3187mg / kg, calculates and learns to need calcium polysulfide 212kg (calcium polysulfide aqua is 730kg), ferrous sulfate 540kg, humic acid powder 180kg, Actually add calcium polysulfide aqua 720kg, ferrous sulfate 525kg, humic acid powder 175kg, the mass percent of calcium polysulfide, ferrous sulfate and humic acid powder is 23%: 58%: 19%, humic acid powder grain The diameter is 80 mesh.
[0070] (3) the CK 1 、CK 2 、CK 3 、CK 4 、CK 5 、CK 6 The samples were sieved for the first time and sieved for the second time to make the soil particle size 3 cm. Weigh the calcium polysulfide water agent according t...
Embodiment 3
[0074] (1) On-site excavation of 10 square meters (m 3 ) Mercury polluted soil, soil density is 1.8g / cm 3 After mechanical stirring and mixing, 6 mixed samples were collected to determine the total amount of mercury pollution and acid leaching concentration.
[0075] (2) The average concentration of mercury content in mercury-contaminated soil obtained from the data is 2209mg / kg, and it is calculated that 147kg of calcium polysulfide (calcium polysulfide aqua 506kg), 540kg of ferrous sulfate, and 180kg of humic acid powder are needed. Add calcium polysulfide aqua 500kg, ferrous sulfate 500kg, humic acid powder 150kg, the mass percent of calcium polysulfide aqua, ferrous sulfate and humic acid powder is 18%: 63%: 19%, humic acid powder The particle size is 80 mesh.
[0076] (3) the CK 1 、CK 2 、CK 3 、CK 4 、CK 5 、CK 6 The samples were sieved for the first time and sieved for the second time to make the soil particle size 3 cm. Weigh the calcium polysulfide water agent ac...
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