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A method for increasing the content of sodium bicarbonate-extracted phosphorus in livestock and poultry feces biochar

A technology of livestock and poultry manure and sodium bicarbonate, which is applied in the field of resource utilization of solid waste, can solve the problems of low efficiency and achieve the effects of abundant resources, improved operation and low price

Active Publication Date: 2022-01-04
INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CN107352766A discloses a method of using microbial electrocatalysis to promote the conversion of organic phosphorus to inorganic phosphorus in sludge. This method will solve the problem of low efficiency of converting organic phosphorus in sludge into inorganic phosphorus and then releasing it to the supernatant. Through the use of microbial electrolysis cells supplemented by free nitrous acid (FNA) pretreatment to realize the conversion of organic phosphorus to inorganic phosphorus in sludge, so as to better realize the simultaneous recovery and utilization of nitrogen and phosphorus
However, the technical solutions disclosed in the above-mentioned patent applications do not involve the regulation of phosphorus in livestock and poultry manure, let alone the regulation of phosphorus in livestock and poultry manure pyrolysis biochar

Method used

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  • A method for increasing the content of sodium bicarbonate-extracted phosphorus in livestock and poultry feces biochar
  • A method for increasing the content of sodium bicarbonate-extracted phosphorus in livestock and poultry feces biochar
  • A method for increasing the content of sodium bicarbonate-extracted phosphorus in livestock and poultry feces biochar

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The laboratory selected pig manure from a farm in Zhejiang Province, and processed it according to the following steps:

[0023] Pig manure (PM) samples were dried in an oven at 85°C for 5 hours to reduce the moisture content to below 0.1wt%, and after cooling, they were ground and sieved to obtain a finely ground sample with a particle size of ≤100 mesh; %: The ratio of 20wt% is uniformly mixed, and then the resulting mixture and the finely ground sample are respectively placed in a fixed-bed pyrolysis reactor, and the mixture is mixed with N 2 As a protective gas with a flow rate of 80mL min -1 , the heating rate of the reactor was 15°C·min -1 , the final pyrolysis temperature was set at 600°C, and the pyrolysis was carried out at a constant temperature for 45 minutes, and then cooled to room temperature with the furnace to obtain livestock and poultry manure biochar PMB (100% pig manure pyrolysis biochar) and PC20 (20% rice bran + 80% pig manure mixed pyrolyzed bio...

Embodiment 2

[0032] Bamboo chips, rice husks and wood chips were selected as additives for comparison, and compared with that of rice bran in Example 1, the addition ratio was 20%. The biochar preparation and phosphorus detection were consistent with those in Example 1, and the results are shown in Table 2. Among them, PM is pig manure, and the obtained biochar is sequentially recorded as PMB (100% pig manure pyrolysis biochar), PB20 (20% bamboo chips + 80% pig manure mixed pyrolysis biochar), PC20 (20% rice bran + 80% % pig manure mixed pyrolysis biochar), PR20 (20% chaff + 80% pig manure mixed pyrolysis biochar), PW20 (20% sawdust + 80% pig manure mixed pyrolysis biochar).

[0033] Table 2 Comparison of the impact of different additives on phosphorus form (g / kg)

[0034]

[0035]

[0036] It can be seen from the above table that, compared with the original pig manure and pig manure biochar, the mixed pyrolysis of pig manure with wood chips, bamboo chips, and rice husks as additive...

Embodiment 3

[0037] Example 3: Biochar Characteristics

[0038] The main performance indicators of 100% pig manure pyrolysis biochar (PM100) and biochar PC10, PC20 and PC30 obtained by adding 10%, 20%, 30% rice bran and pig manure mixed pyrolysis are shown in Table 4. It can be seen from Table 4 that the ash and volatile content of biochar obtained by adding rice bran and pig manure mixed pyrolysis decreased, and the fixed carbon content increased. The content of Cu, the main heavy metal pollutant in livestock and poultry manure is reduced, and the leaching property of TCLP is reduced to 0. Therefore, the ecological risk of heavy metals is lower than that of pig manure alone. The above results indicated that, compared with the pyrolysis of pig manure alone, the mixed pyrolysis of rice bran and pig manure significantly increased the NaHCO content in biochar. 3 -P content, on the other hand has better environmental safety.

[0039] Table 4 The main technical indicators of biochar

[0040]...

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Abstract

The invention belongs to the technical field of resource utilization of solid waste, and relates to a method for increasing the content of sodium bicarbonate-extracted phosphorus in livestock and poultry manure biochar. The method comprises: drying the livestock and poultry manure until the water content is below 0.1 wt%. The obtained dry sample is finely ground to a particle size of ≤100 mesh, and then the obtained finely ground sample is uniformly mixed with rice bran, and then the obtained modified mixed sample is pyrolyzed and then cooled in a furnace to obtain livestock and poultry feces biochar. The invention is simple in operation and low in cost, and can effectively solve the problem of low effective phosphorus content in biochar prepared by existing pig manure pyrolysis, so that the phosphorus in the decomposed biochar can be easily absorbed and utilized by plants. Direction transformation, compared with the biochar obtained by pyrolysis of livestock and poultry manure alone, the content of phosphorus extracted by sodium bicarbonate is increased by >100%.

Description

technical field [0001] The invention belongs to the technical field of resource utilization of solid waste, and in particular relates to a method for increasing the content of phosphorus extracted from sodium bicarbonate in livestock and poultry feces biochar. Background technique [0002] Due to the lack of timely and harmless treatment and scientific utilization of livestock and poultry manure in key areas of my country's agriculture and animal husbandry industry, the problem of environmental pollution caused by its arbitrary discharge has become increasingly prominent. In recent years, the pyrolysis carbonization technology of livestock and poultry manure has received extensive attention. This technology uses anaerobic medium-temperature carbonization of livestock and poultry manure to completely decompose pathogenic bacteria and antibiotics. It can not only passivate harmful heavy metals, but also retain most of the phosphorus in the manure in biochar. Since the form of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10B53/00C10B53/02C10B57/04C10B57/10
CPCC10B53/00C10B57/10C10B57/04C10B53/02Y02E50/10
Inventor 余广炜江汝清汪印
Owner INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI