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Electroslag remelting oxygenation inhibition method

A technology for electroslag remelting and slag melting, which is applied to devices and coatings that apply liquid to the surface, which can solve problems such as scrapping, hot cracks in steel ingots, and inability to effectively control them. The effect of liquid oxygenation and inhibition of secondary oxidation

Inactive Publication Date: 2021-06-18
ANGANG STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Whether it is dissolved oxygen or combined oxygen, they will bring a series of hazards to molten steel or solid steel: 1) The dissolved oxygen in molten steel can oxidize the added alloy elements, such as aluminum, boron, zirconium, rare earth, etc. Ineffective, and at the same time, endogenous non-metallic and sundries will be generated; during the solidification process of molten steel, the solubility of oxygen decreases as the temperature decreases, and the precipitated oxygen reacts with carbon to form carbon monoxide bubbles, which cause the steel ingots and castings to rise and lead to scrapping; during the solidification process Oxygen precipitated in the form of FeO can form a eutectic with a melting point of 940°C with FeS, and precipitate along the grain boundary, causing hot cracks in the steel ingot during hot processing
2) After the molten steel is solidified, most of the dissolved oxygen is transformed into non-metallic inclusions in the steel, causing great harm to the processing performance and serviceability of the steel
This patent uses physical methods to block the air and slag, which can effectively prevent the oxygenation of the slag, but it cannot be effectively controlled, because the oxides in the slag cause the oxygenation of the steel sample
[0006] In short, the existing technologies all suppress the oxygenation of the electroslag remelting process by means of blocking the air and changing the composition of the slag, but none of them can effectively suppress the oxygenation of the molten steel caused by the slag oxides.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The present invention is used to carry out electroslag remelting suppression oxygen increase test, adopting the shot blasting treatment method to treat the oil stains and iron oxide scales left on the surface of the consumable electrode: the treatment time is 30min, and the surface roughness is 50μm. Coating material adopts corundum powder + aluminum powder, corundum powder Al 2 o 3 The mass percentage content is 95%, and the particle size is 100 mesh; the aluminum metal powder Al content is 98%, and the particle size is 100 mesh; according to the mass ratio of 1:4, corundum powder: metallic aluminum powder is prepared. The surface of the consumable electrode is sprayed by electrostatic powder spraying process, and the coating thickness is 10 μm. Other operations are operated in accordance with the conventional process of inhibiting oxygenation.

Embodiment 2

[0028] Using the present invention to carry out the electroslag remelting suppression oxygen increase test, adopting the shot peening treatment method to treat the oil stains and iron oxide scales left on the surface of the consumable electrode: the treatment time is 45min, and the surface roughness is 100μm. Coating material adopts corundum powder + aluminum powder, corundum powder Al 2 o 3 The mass percentage content is 97%, and the particle size is 200 mesh; the aluminum metal powder Al content is 99%, and the particle size is 200 mesh; according to the mass ratio of 1:5, corundum powder: metallic aluminum powder is prepared. The surface of the consumable electrode is sprayed by electrostatic powder spraying process, and the coating thickness is 25 μm. Other operations are operated in accordance with the conventional process of inhibiting oxygenation.

Embodiment 3

[0030] Using the present invention to carry out the electroslag remelting suppression oxygen increase test, adopting the sandblasting treatment method to treat the oil stains and iron oxide scales left on the surface of the consumable electrode: the treatment time is 60min, and the surface roughness is 150μm. Coating material adopts corundum powder + aluminum powder, corundum powder Al 2 o 3 The mass percentage content is 99%, and the particle size is 300 mesh; the aluminum metal powder Al content is 99.5%, and the particle size is 300 mesh; according to the mass ratio of 1:6, corundum powder: metallic aluminum powder is prepared. The surface of the consumable electrode is sprayed by electrostatic powder spraying process, and the coating thickness is 40 μm. Other operations are operated in accordance with the conventional process of inhibiting oxygenation.

[0031] The invention effectively prevents the secondary oxidation of the consumable electrode in the electroslag remel...

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Abstract

The invention relates to the technical field of electroslag remelting, in particular to an electroslag remelting oxygenation inhibition method. The method specifically comprises the following steps: 1) treating the surface of a consumable electrode, specifically, treating the surface of the consumable electrode by a mechanical polishing treatment mode so that the surface roughness of the consumable electrode reaches 50-150 [mu] m; 2) preparing coating component and carrying out proportioning, specifically, adopting corundum powder and aluminum powder as coating materials, and preparing the corundum powder and the metal aluminum powder according to a mass ratio of 1:4-1:6; 3) setting a spraying mode and parameters, specifically, carrying out surface spraying treatment on the consumable electrode by an electrostatic powder spraying process; and 4) carrying out other operations according to a conventional oxygenation inhibition process, specifically, enhancing inert gas protection to stop contact between air and slag; and adding a deoxidizing agent to inhibit slag oxygenation and molten steel oxygenation. The method is simple in process, safe, reliable, low in cost and efficient, and can effectively inhibit electroslag remelting molten steel oxygenation.

Description

technical field [0001] The invention relates to the technical field of electroslag remelting, in particular to a method for suppressing oxygen increase in electroslag remelting. Background technique [0002] Electroslag Remelting (ESR for short) is one of the main methods of special metallurgy and belongs to the secondary refining technology, so it is also called electroslag refining. The purpose of electroslag remelting is to remove harmful impurity elements and non-metallic inclusions in metals, purify metals, and obtain steel ingots with uniform and dense crystal structure. Electroslag remelting steel has the characteristics of high purity, low sulfur content, few inclusions, dense metallographic structure and uniform chemical composition. It has been widely used in aerospace, military industry, nuclear power, automobile, petrochemical and other key fields. The electroslag remelting furnace has simple structure, low production cost, convenient operation, and high metal y...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B9/18C22B9/187C21C7/06B05D7/14B05D1/06
CPCC22B9/18C21C7/06C21C7/0006B05D7/14B05D1/06
Inventor 万雪峰曹东臧绍双廖相巍张越裴兰科张晓光赵亮刘磊李佳东
Owner ANGANG STEEL CO LTD
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