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A temperature-sensitive adhesive resin plugging agent and its preparation method and application

A technology of temperature-sensitive adhesion type and plugging agent, which is applied in chemical instruments and methods, fibrous fillers, dyed organic silicon compound treatment, etc., can solve the problem of leakage plugging success rate of large cracks, low adhesion strength of resin materials, Problems such as low success rate of one-time plugging, to achieve the effects of not being affected by pressure fluctuations, enhancing the retention capacity, and having a wide range of density applications

Active Publication Date: 2022-05-03
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Commonly used bridging plugging materials include rigid calcium carbonate particles, elastic particles, flexible fibers, etc. Bridging plugging slurry has achieved good application results in plugging formations with permeability and micro-fracture loss, but for large The plugging of fractured leakage formations generally has problems such as low success rate of one-time plugging and high frequency of re-leakage
According to statistics, the global bridging plugging success rate is less than 40%. The main reason is that bridging plugging materials form a plugging layer through bridging, tensioning and filling. Linear contact, the plugging layer formed by the wellbore fluid column and formation pressure difference is easily damaged by pressure fluctuations, resulting in re-leakage, resulting in a low success rate of leakage plugging in large fractures
However, the thermoplastic resin elastomer materials used in the plugging agents provided by the above two patents are all single-type resin materials, which are industrial products and have not been modified. Their melting points, melting ranges, and densities are fixed values, and they are used alone. Or the plugging agent compounded with other bridging plugging materials such as sheet materials and flexible materials, which can only undergo melting reaction under specific and narrow temperature conditions, and the use temperature is limited, and the unmodified resin The material has low adhesion strength, and it is difficult to achieve high-strength adhesion and sealing effect under high temperature conditions

Method used

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  • A temperature-sensitive adhesive resin plugging agent and its preparation method and application

Examples

Experimental program
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Effect test

Embodiment 1

[0062] A temperature-sensitive adhesive resin plugging agent, comprising the following raw materials in parts by mass:

[0063] 88 parts of thermoplastic resin matrix, 12 parts of melting temperature regulator, 5 parts of organic lipid melting range regulator, 4 parts of modified solid-phase filled melting range regulator, and 30 parts of modified density regulator.

[0064] Wherein, the thermoplastic resin matrix is ​​polyamide; the melting temperature regulator is phthalic acid; and the organic lipid melting range regulator is diisodecyl phthalate.

[0065] The modified solid-phase filled melting range modifier is modified calcium carbonate, which is prepared according to the following method:

[0066] Add 25g of dried calcium carbonate into 500mL of dichloromethane, and ultrasonically disperse for 30min to obtain suspension a; add 20mL of vinyltrimethoxysilane dropwise to suspension a for 30min, and ultrasonically disperse for 10min to obtain Suspension b was left to react...

Embodiment 2

[0080] A temperature-sensitive adhesive resin plugging agent, comprising the following raw materials in parts by mass:

[0081] 85 parts of thermoplastic resin matrix, 12 parts of melting temperature regulator, 4 parts of organic lipid melting range regulator, 3 parts of modified solid-phase filled melting range regulator, and 30 parts of modified density regulator.

[0082] Wherein, the thermoplastic resin matrix is ​​polystyrene; the melting temperature regulator is a combination of phthalic acid and 3-phenylpropionic acid, wherein the mass ratio of phthalic acid and 3-phenylpropionic acid is 1:2; the organic lipid melting range modifier is dibutyl phthalate;

[0083] The modified solid-phase filled melting range modifier is modified zeolite powder, and its preparation method is the same as that of modified calcium carbonate in Example 1, except that calcium carbonate is replaced by zeolite powder.

[0084] The modified density regulator is modified barite, and its preparat...

Embodiment 3

[0088] A temperature-sensitive adhesive resin plugging agent, comprising the following raw materials in parts by mass:

[0089] 80 parts of thermoplastic resin matrix, 10 parts of melting temperature regulator, 5 parts of organic lipid melting range regulator, 3 parts of modified solid-phase filling type melting range regulator, and 20 parts of modified density regulator.

[0090] Wherein, the thermoplastic resin matrix is ​​a combination of low-density polyethylene and high-density polyethylene, wherein the mass ratio of the low-density polyethylene to high-density polyethylene is 1:1; the melting temperature regulator is Phthalic acid; the organic lipid melting range modifier is dioctyl phthalate;

[0091] The modified solid-phase filled melting range regulator is modified silica, and its preparation method is the same as that of modified calcium carbonate in Example 1, except that calcium carbonate is replaced by silicon dioxide.

[0092] The modified density regulator is ...

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Abstract

The invention provides a temperature-sensitive adhesive resin plugging agent as well as its preparation method and application. The temperature-sensitive adhesive resin plugging agent comprises the following raw materials in parts by mass: 75-90 parts of a thermoplastic resin matrix, 5-15 parts of a melting temperature regulator, 2-8 parts of an organic lipid melting range regulator, and 0.5-6 parts of permanent solid-phase filling melting range regulator, and 0-30 parts of modified density regulator. The temperature-sensitive adhesive blocking agent of the present invention is based on different types of thermoplastic resins. When the temperature reaches the melting point of the blocking agent particles in the water phase, the surface of the blocking agent particles begins to melt and has a certain viscosity. Particles can be bonded to each other, and the particles of the lost circulation agent can also be bonded to the wall of the lost channel of the drilling fluid, which not only enhances the residence ability of the lost lost circulation agent in the lost channel, but also improves the overall density of the particles of the lost circulation agent accumulated in the sealing layer. Strength, making it less susceptible to pressure fluctuations, improving the success rate of one-time plugging and effectively avoiding re-leakage.

Description

technical field [0001] The invention relates to a temperature-sensitive adhesive resin plugging agent, a preparation method and application thereof, and belongs to the technical field of oil and gas drilling engineering. Background technique [0002] Lost circulation is a common phenomenon in the process of oil drilling. According to statistics, the occurrence rate of lost circulation accounts for 20%-25% of the total number of wells in the world. Lost circulation will not only cause huge economic losses to the drilling project, but also lead to a serious drop in well pressure, which will have a great impact on the stability of the inner wall of the oil well. In severe cases, it will lead to blowout accidents, which seriously threaten the safety of drilling operations. sex. [0003] Aiming at well leakage accidents at home and abroad, plugging materials such as bridging, water-absorbing / oil-absorbing resin, curable, high-water loss, and polymer gel have been developed succe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/42C09C1/02C09C1/30C09C1/42C09C3/12
CPCC09K8/426C09C1/021C09C1/027C09C1/42C09C1/3081C09C3/12
Inventor 白英睿孙金声吕开河王金堂刘敬平黄贤斌金家锋
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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