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Transparent conductive barrier film and preparation method and application thereof

A transparent conductive and barrier film technology, which is applied in the direction of equipment for manufacturing conductive/semiconductive layers, cable/conductor manufacturing, conductive layers on insulating carriers, etc., can solve the problem of poor carrier extraction and injection efficiency, dielectric layer It is difficult to balance conductivity and barrier properties, and the intermediate metal layer is susceptible to corrosion, etc., to achieve the effects of efficient extraction and injection, excellent transparency, and low cost

Active Publication Date: 2021-08-24
HEBEI UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to provide a transparent conductive barrier film, its preparation method and application. The transparent conductive barrier film is a film based on a DMD structure with excellent transparency, conductivity, barrier properties and mechanical flexibility. The thin film can solve the difficulty of balancing the conductivity and barrier properties of the dielectric layer in the silver-based multilayer transparent conductive film of the DMD structure, which makes the extraction and injection efficiency of the carrier poor when the multilayer transparent conductive film is used as a transparent electrode of an optoelectronic device , or multi-layer transparent conductive film in the process of storage and use, the middle metal layer is easily corroded, resulting in the deterioration of the photoelectric performance of the film

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  • Transparent conductive barrier film and preparation method and application thereof
  • Transparent conductive barrier film and preparation method and application thereof
  • Transparent conductive barrier film and preparation method and application thereof

Examples

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Embodiment 1

[0041] Such as image 3 As shown, the substrate 1 is a PET substrate, and the metal layer 3 is an Ag layer. The film thickness of the Ag layer is 11 nm, and the thickness of the first dielectric layer 2 and the second dielectric layer 4 are both 40 nm. The first dielectric layer 2 is formed by alternately depositing the first ITO layer 21 and the first AZO layer 22, each of the first ITO layer 21 and the first AZO layer 22 have a thickness of 10 nm; the second dielectric layer 4 is composed of the second AZO layer 41 and the second ITO layer 42 are alternately deposited, and each of the second ITO layer 42 and the second AZO layer 41 has a thickness of 10 nm.

[0042] The specific preparation steps of the transparent conductive barrier film in this embodiment are as follows:

[0043] (1) Clean the PET substrate.

[0044] (2) Put the PET substrate on the substrate stage in the cavity of the multi-target magnetron sputtering thin film deposition equipment pre-installed with h...

Embodiment 2

[0049] The structure of the transparent conductive barrier film in this embodiment is similar to that in Embodiment 1, the difference is that the metal layer in this embodiment is an Ag(O) layer, and the Ag(O) layer is formed in an argon-oxygen mixed gas atmosphere. It is formed by sputtering Ag targets under the conditions. The film thickness of the Ag(O) layer is 9 nm. Both the thickness of the first dielectric layer and the second dielectric layer are 40nm. The structures of the first dielectric layer and the second dielectric layer are the same as those in Embodiment 1, and will not be repeated here.

[0050] The specific preparation steps of the transparent conductive barrier film in this embodiment are as follows:

[0051] (1) Clean the PET substrate.

[0052] (2) Put the PET substrate on the substrate stage in the cavity of the multi-target magnetron sputtering thin film deposition equipment pre-installed with high-purity Ag target, ITO target and AZO target.

[005...

Embodiment 3

[0063] Such as Figure 4 As shown, the substrate 1 in this embodiment is a PET substrate, and the metal layer 3 includes CuO x seed layer 31 and Ag layer 32 . CuO x The seed layer 31 is made by sputtering and depositing a Cu layer (with a thickness of 1 nm) after oxidation, and the film thickness of the Ag layer 32 is 7 nm. Both the first dielectric layer 2 and the second dielectric layer 4 have a thickness of 40nm, wherein the first dielectric layer 2 is alternately deposited by the first ITO layer 21 and the first AZO layer 22, each of the first ITO layer 21 and the first AZO layer The thickness of the layers 22 is 10 nm; the second dielectric layer 4 is formed by alternately depositing the second AZO layer 41 and the second ITO layer 42 , each of the second ITO layer 42 and the second AZO layer 41 has a thickness of 10 nm.

[0064] The specific preparation steps of the transparent conductive barrier film in this embodiment are as follows:

[0065] (1) Clean the PET subs...

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Abstract

The invention provides a transparent conductive barrier film and a preparation method and application thereof. The transparent conductive barrier film is structurally characterized in that a first dielectric layer, a metal layer and a second dielectric layer are sequentially arranged on a substrate; and at least one of the first dielectric layer and the second dielectric layer is formed by alternately depositing two or more than two transparent conductive oxide films with different structures. The film provided by the invention is a multi-layer transparent conductive barrier film based on a medium / metal / medium structure, has excellent transparency, conductivity, barrier property and mechanical flexibility, and can effectively solve the problem that in the storage and use processes of the transparent conductive film with the medium / metal / medium structure, a metal layer is easily corroded by water and oxygen in atmosphere and active ions in other layers in a device. Meanwhile, the high conductivity of the dielectric layer can ensure the efficient extraction and injection of device carriers, and the high-conductivity dielectric layer can be conveniently applied to the fields of solar cells, light-emitting diodes, electrochromism, electromagnetic shielding, anti-radiation films and the like.

Description

technical field [0001] The invention relates to the technical field of transparent conductive films, in particular to a transparent conductive barrier film, its preparation method and application. Background technique [0002] The rapid development of flexible electronic devices in the fields of energy, display, and wearable devices poses new challenges to the flexibility of transparent conductive films (TCFs). Traditional transparent conductive oxide films represented by indium tin oxide (ITO) and fluorine-doped tin oxide (FTO) have been difficult to meet the requirements of flexible electronic devices due to their inherent mechanical brittleness and poor conductivity at low temperature deposition. development needs. Silver-based multilayer transparent conductive films based on dielectric / metal / dielectric (DMD) structures are expected to become ideal flexible materials to replace traditional transparent conductive oxides due to their good photoelectric properties, outstand...

Claims

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Application Information

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IPC IPC(8): H01B5/14H01B13/00
CPCH01B5/14H01B13/0026Y02P70/50
Inventor 路万兵蒋树刚于威武利平刘红燕刘海旭刘啸宇王新占
Owner HEBEI UNIVERSITY