Preparation method and processing equipment of bio-based modified low-heat-generation reinforcing agent

A processing equipment and bio-based technology, applied to chemical instruments and methods, mixers with rotating stirring devices, mixers, etc., can solve problems affecting product performance, difficulty in eating powder, vulcanization effects, etc., to improve efficiency and quality , Good processing technology, reduce the effect of compression heat generation

Inactive Publication Date: 2021-09-03
ZHEJIANG WEIXIANG TECH GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This modification method has the disadvantages of high production cost and low quality, especially when the produced product is used in the production of rubber field, it is difficult to eat powder, and the quality of rubber products is low. When used for natural rubber and various synthetic rubber, In terms of reinforcement, it is not as good as ordinary fillers such as calcium carbonate, clay, etc. The comprehensive performance of the rubber material is not ideal, and it has a certain impact on vulcanization. Adding a large amount will affect the performance of the product, so it cannot be widely used in various rubber products.
[0004] Another important factor for the above problems is that when the materials are mixed, the contact area between the materials becomes smaller due to the defect of the mixing equipment, so that high-quality mixing cannot be achieved, which affects the non-metallic mineral materials. modification effect

Method used

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  • Preparation method and processing equipment of bio-based modified low-heat-generation reinforcing agent
  • Preparation method and processing equipment of bio-based modified low-heat-generation reinforcing agent
  • Preparation method and processing equipment of bio-based modified low-heat-generation reinforcing agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The embodiment of the present invention proposes a preparation method of a bio-based modified low heat generation enhancer, comprising the following steps:

[0034]S1, the non-metallic mineral material is pounded and desanded and ground to a particle size of 10 μm and added to the first stirred tank, and then added to the first stirred tank with a mass fraction of 10% sodium chloride and a mass fraction of 20% calcium carbonate Solution, stirred at 750r / min for 30min, then heated to 85°C and kept for 13min, stirred at 2000r / min for 55min, added silane coupling agent Si-69 and stearic acid, kept for 10min, continued high-speed stirring and heated to 100 ℃, add zinc oxide and phenolic resin, and keep for 10 minutes to obtain modified kaolin;

[0035] S2. Put the modified biomass, lignin, petroleum resin and urotropine into the second stirring tank, stir and mix to obtain a bio-based modified low-heat enhancer.

[0036] In this embodiment, in S2, the petroleum resin is Co...

Embodiment 2

[0046] Different from Example 1, the embodiment of the present invention proposes a preparation method of a bio-based modified low heat generation enhancer, including the following steps:

[0047] S1, the non-metallic mineral material is pounded and desanded and ground to a particle size of 15 μm and added to the first stirred tank, and then added to the first stirred tank with a mass fraction of 10% sodium chloride and a mass fraction of 20% calcium carbonate Solution, stirred at 650r / min for 40min, then heated to 80°C and kept for 15min, stirred at 1500r / min for 60min, added silane coupling agent Si-69 and stearic acid, kept for 15min, continued high-speed stirring and heated to 95 ℃, add zinc oxide and phenolic resin, and keep for 15 minutes to obtain modified kaolin;

[0048] S2. Put the modified biomass, lignin, petroleum resin and urotropine into the second stirring tank, stir and mix to obtain a bio-based modified low-heat enhancer.

[0049] In this embodiment, in S2, ...

Embodiment 3

[0053] Different from Example 1, the embodiment of the present invention proposes a preparation method of a bio-based modified low heat generation enhancer, including the following steps:

[0054] S1, the non-metallic mineral material is pounded and desanded and ground to a particle size of 5 μm and added to the first stirred tank, and then added to the first stirred tank with a mass fraction of 10% sodium chloride and a mass fraction of 20% calcium carbonate Solution, stirred at 850r / min for 20min, then heated to 90°C and kept for 10min, stirred at 2500r / min for 50min, added silane coupling agent Si-69 and stearic acid, kept for 5min, continued high-speed stirring and raised to 105 ℃, add zinc oxide and phenolic resin, and keep for 5 minutes to obtain modified kaolin;

[0055] S2. Put the modified biomass, lignin, petroleum resin and urotropine into the second stirring tank, stir and mix to obtain a bio-based modified low-heat enhancer.

[0056] In this embodiment, in S2, th...

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PUM

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Abstract

The invention relates to a preparation method of a bio-based modified low-heat-generation reinforcing agent, which comprises the following steps: S1, pounding a non-metallic mineral material, desanding, grinding, adding the non-metallic mineral material into a first stirring kettle, adding sodium chloride and a calcium carbonate solution into the first stirring kettle, stirring, heating, adding a silane coupling agent Si-69 and stearic acid, mixing, continuously stirring at a high speed and heating; adding zinc oxide and phenolic resin to obtain modified kaolin; S2, putting the modified biomass, lignin, petroleum resin and urotropine into a second stirring kettle, and stirring and mixing to obtain the bio-based modified low-heat-generation reinforcing agent. The invention further provides equipment used in the method. The reinforcing agent disclosed by the invention is high in surface activity, easy to mix into a rubber sizing material, good in processing technology, capable of effectively reducing compression heat generation of the sizing material, improving the bonding effect of a tire body and a belt ply cord fabric sizing material with a steel wire, improving physical and mechanical properties such as aging resistance of the sizing material and the like, and capable of partially replacing carbon black and white carbon black.

Description

technical field [0001] The invention relates to the technical field of rubber reinforcing fillers, in particular to a preparation method and processing equipment of a bio-based modified low heat generation reinforcing agent. Background technique [0002] At present, the reinforcing agents for rubber are mainly carbon black and white carbon black. The lignin and bio-based modified low-heat reinforcing agent is a combination of lignin and bio-based modified materials and functional organic materials with modified It is compounded and mixed with non-metallic mineral nano-materials such as kaolin and imonite. It can replace about 30% of carbon black and white carbon black, reduces the amount of carbon black, and saves the petroleum energy used in the production of carbon black. Used together with carbon black and white carbon black in the rubber compound to achieve a synergistic effect. Using this reinforcing agent in the tire rubber compound can not only maintain the original ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/06C08L57/02C08L45/02C08L97/00C08K3/34C08K3/22C08K9/06C08K3/26C08K3/36B01F7/00B01F7/18B01F13/10B01F15/00
CPCC08L61/06C08L57/02C08L45/02C08L97/005C08K2003/265C08K2003/2296C08K3/346C08K3/22C08K9/06C08K3/26C08K3/36
Inventor 张立王廷山戴圣佳陶莉
Owner ZHEJIANG WEIXIANG TECH GRP CO LTD
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