Defoaming agent for papermaking

A technology of defoaming agent and auxiliary agent, applied in the field of defoaming agent for papermaking, can solve problems such as affecting production efficiency, low foam breaking rate, easy generation of bubbles, etc., achieving excellent wetting and spreading performance, improving molecular hydrophilicity, Good foam breaking effect

Pending Publication Date: 2021-11-02
海宁美浪有机硅科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] During the papermaking and pulping process, the slurry will generate a lot of surface active substances in situ, and at the same time, the high mechanical force will cause a large amount of air to be mixed in, which is easy to generate air bubbles. When the foaming phenomenon is serious, the efficiency of pulp washing will be greatly reduced, and the It brings great difficulties to transportation and bleaching, affects the quality of pulp, seriously affects production efficiency, and increases the risk of environmental pollution. However, the traditional silicone defoamer has a low foam breaking rate in the actual use process. Therefore, The invention provides a defoamer for papermaking, which reduces the surface tension of the defoamer and improves the foam breaking rate

Method used

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  • Defoaming agent for papermaking

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Effect test

Embodiment 1

[0035] Please refer to Table 1, the present invention provides a technical solution: a defoamer for papermaking, composed according to the mass ratio, including 30 components of active components, 10 components of emulsifiers, 20 components of auxiliary agents, 8 components Components of solvent and 32 components of water, the active component is a mixture of ethylene glycol monostearate, modified silicone and ethylene bisstearic acid amide in a mass ratio of 1:3:1, with defoaming effect;

[0036] Among them, the modified silicone is prepared from amino-terminated silicone intermediates, silicone monomers, and silane coupling agents under the catalysis of a basic catalyst;

[0037] Concretely, the preparation method of modified organosilicon comprises the following steps:

[0038] (1) Add amino-terminated organosilicon intermediates, a mixture of octamethylcyclotetrasiloxane and dimethylcyclosiloxane, and a silane coupling agent sequentially into the reactor at a mass ratio o...

Embodiment 2

[0051] Please refer to Table 1, the present invention provides a technical solution: a defoamer for papermaking, composed according to the mass ratio, including 28 components of active components, 15 components of emulsifiers, 18 components of auxiliary agents, 6 components Component solvent and 33 component water, the active component is a mixture of ethylene glycol monostearate and modified silicone in a mass ratio of 1:1, which has defoaming effect;

[0052] Among them, the modified silicone is prepared from amino-terminated silicone intermediates, silicone monomers, and silane coupling agents under the catalysis of a basic catalyst;

[0053] Concretely, the preparation method of modified organosilicon comprises the following steps:

[0054](1) According to the mass ratio of 1:50:1, add amino-terminated organosilicon intermediate, dimethylcyclosiloxane and 1,3,5,7-tetramethylcyclotetrasiloxane to the reactor in sequence The mixture and the silane coupling agent are stirred...

Embodiment 3

[0067] Please refer to Table 1, the present invention provides a technical solution: a defoamer for papermaking, composed according to the mass ratio, including 32 components of active components, 18 components of emulsifiers, 17 components of auxiliary agents, 9 components Component solvent and 34 component water, the active component is a mixture of modified silicone and ethylene bis stearic acid amide in a mass ratio of 2:1, which has defoaming effect;

[0068] Among them, the modified silicone is prepared from amino-terminated silicone intermediates, silicone monomers, and silane coupling agents under the catalysis of a basic catalyst;

[0069] Concretely, the preparation method of modified organosilicon comprises the following steps:

[0070] (1) According to the mass ratio of 1:50:1, add amino-terminated organosilicon intermediate, octamethylcyclotetrasiloxane and 1,3,5,7-tetramethylcyclotetrasiloxane to the reactor in sequence a mixture of alkane and a silane coupling ...

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Abstract

The invention discloses a defoaming agent for papermaking, which comprises an active component, an emulsifier, an auxiliary agent, a solvent and water in a mass ratio of (25-35):(5-15):(15-25):(3-13):(27-37), and the active component is one or a combination of more of ethylene glycol monostearate, modified organic silicon and ethylene bisstearamide; and the modified organic silicon is prepared from an amino-terminated organic silicon intermediate, an organic silicon monomer and a silane coupling agent under the catalytic action of a basic catalyst. According to the defoaming agent, modified organic silicon serving as an active component of the defoaming agent is low in surface tension and excellent in wetting and spreading performance, meanwhile, due to introduction of amino groups, the molecular hydrophilicity is improved, the dispersity in water can be improved, the defoaming agent is used for defoaming a water-based system, the emulsification of the defoaming agent is promoted, in addition, the amino groups can be ionized to carry positive charges, and a good bubble breaking effect is achieved on a bubble film with negative electricity.

Description

technical field [0001] The invention relates to the technical field of defoamers, in particular to a defoamer for papermaking. Background technique [0002] The function of the defoamer is divided into defoaming and foam suppression. After the foam is generated, when the defoamer touches the foam, it immediately reacts with the hydrophobic segment molecules on the foam surface to form a double film layer. The surface tension of the defoamer is very low. Traction by the surrounding foaming film layer with high surface tension will cause the imbalance of the bubble stress, which will cause the bubble to burst. If the foam has not yet been produced, the defoamer can penetrate into the foaming system in the form of particles, destroying the elasticity of the bubble film, thereby inhibiting its formation. [0003] During the papermaking and pulping process, the slurry will generate a lot of surface active substances in situ. At the same time, the high mechanical force will cause...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D19/04C08G77/46
CPCB01D19/0404B01D19/0409B01D19/0413B01D19/0418B01D19/0436C08G77/46B01D19/0495
Inventor 徐德林
Owner 海宁美浪有机硅科技有限公司
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