Anti-ultraviolet repair material as well as preparation method and application thereof
A repair material and anti-ultraviolet technology, applied in the field of polymer materials, can solve the problems of poor sealing between the heat shrinkable tube and the base material, increasing difficulty in heat dissipation, affecting power production, etc., and achieve good ability to shield ultraviolet light and resist photoaging Good, restore the effect of the original performance
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[0054] Preparation of the main molecule: 1 g of β-cyclodextrin (β-CD) was dissolved in 100 mL of water, and then 0.2 g of particle size (≤20 nm) of nano-PBO was dispersed into β-CD solution with ultrasound method, ultrasonic time Controlled at 40 min; irradiated the dispersion at a 50 W ultraviolet lamp, and then separated from a high-speed frozen centrifuge to obtain a solid product 5 times with pure water. After rationing, the body molecular cyclodextrin was purified. Light shield β-CD-PBO.
[0055]The preparation of the object molecules: 12.8 mmol AD-COOH was dissolved in 20 ml of sulfoxide, 2 h at 80 ° C, and the excess chloride was rotated, and the reaction was formed using a rotary evaporator. 12.8mmol Chloride organic intermediate AD-COCL (chloride); dissolved AD-COCl in 100 ml of anhydrous dichloromethane, dripped into 8.3 mmol hema and 11.5 mmol triethylamine, reacted under ice bath conditions for 5h After another, 1 M dilute hydrochloric acid, 1 M sodium hydrogencarbonat...
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