The invention is suitable for preparing a solar cell back film, and provides a blend film containing graphene and a preparation method thereof. The blend film is a blend membrane of titanium dioxide graft, PVDF, PMMA, PPA and graphene, and the titanium dioxide graft is modified titanium dioxide with a silane coupling agent KH570 grafted on the surface. In the existence of the graft, the titanium dioxide has non-uniformity phenomenon in the blend membrane, so that when the blend membrane is used as the solar cell back film, the cohesive force between the film and other backboard base materials is greatly increased, and the existence of the PMMA, PPA and graphene also improves the aging resistance, heat conductivity and surface smoothness of the solar cell back membrane. The preparation method comprises the following steps: first grafting the silane coupling agent KH570 onto the surface of the titanium dioxide, mixing weighted TiO2 graft, PVDF, PMMA, PPA and graphene, uniformly mixing, extruding to form strips, cutting the strips into granules, drying the granules, extruding the granules by virtue of a single screw, and tape casting to obtain the blend film.