Anti-static black PET film for mobile phone and preparation method of anti-static black PET film
An antistatic and black technology, applied in the field of PET materials, can solve the problems of poor antistatic ability, highly toxic indium, poor antistatic effect, etc., and achieve good shading, good antibacterial performance and antistatic performance, and excellent shading performance and the effect of antistatic properties
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Embodiment 1
[0036] The invention provides an antistatic black PET film for mobile phones:
[0037]Composition of raw materials (parts by weight): 5 parts of manganese dioxide-loaded silver nano-powder, 0.5 parts of tetrazole polymer, 3 parts of polyaniline-coated nano-titanium dioxide / benzotriazole composite, 80 parts of PET resin, 2 parts of coupling agent , 0.1 part of molybdenum disulfide, 1 part of polysulfide rubber, 0.1 part of antioxidant 1010. The coupling agent is a mixture of silane coupling agent KH602 and titanate coupling agent TMC-2 with a mass ratio of 5:2.
[0038] The preparation method of tetrazole polymer is as follows:
[0039] The synthetic route is as follows:
[0040]
[0041] in N 2 Under protection, 1mol polyacrylamide (n=100), 0.01mol diethyl azodicarboxylate, 1.2mol PCl 5 After mixing, stir and react for 1-2h, add 1.05mol TMSN 3 , Continue to react for 40-50h to obtain the tetrazole polymer, which is isolated and the yield is 57%.
[0042] The tetrazole...
Embodiment 2
[0056] The invention provides an antistatic black PET film for mobile phones:
[0057] Composition of raw materials (parts by weight): 12 parts of manganese dioxide-loaded silver nano-powder, 1 part of tetrazole polymer, 10 parts of polyaniline-coated nano-titanium dioxide / benzotriazole composite, 100 parts of PET resin, 4 parts of coupling agent , 0.4 parts of boron nitride, 2 parts of ethylene-vinyl acetate copolymer, 0.3 parts of antioxidant DLTP. The coupling agent is a mixture of silane coupling agent KH792 and titanate coupling agent TMC-3 with a mass ratio of 2:1.
[0058] The preparation method of tetrazole polymer is as follows:
[0059] in N 2 Under protection, 1mol polyacrylamide (n=100), 0.01mol diethyl azodicarboxylate, 1.2mol PCl 5 After mixing, stir the reaction for 2h, add 1.05mol TMSN 3 , continue to react for 50h to obtain the tetrazole polymer, which is isolated and the yield is 55%.
[0060] The preparation method of manganese dioxide loaded silver nan...
Embodiment 3
[0072] The invention provides an antistatic black PET film for mobile phones:
[0073] Composition of raw materials (parts by weight): 7 parts of manganese dioxide-loaded silver nano-powder, 0.7 parts of tetrazole polymer, 6 parts of polyaniline-coated nano-titanium dioxide / benzotriazole composite, 90 parts of PET resin, 3 parts of coupling agent , 0.2 parts of graphite, 1.5 parts of styrene-butadiene thermoplastic elastomer, 0.2 parts of antioxidant 1076. The coupling agent is a mixture of silane coupling agent KH550 and titanate coupling agent TMC-114 with a mass ratio of 7:3.
[0074] The preparation method of tetrazole polymer is as follows:
[0075] in N 2 Under protection, 1mol polyacrylamide (n=100), 0.01mol diethyl azodicarboxylate, 1.2mol PCl 5 After mixing, stir and react for 1.5h, add 1.05mol TMSN 3 , and continue to react for 48h to obtain the tetrazole polymer, which is isolated with a yield of 59%.
[0076] The preparation method of manganese dioxide loaded ...
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