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Zinc-containing solid waste treatment method and system

A treatment method and technology for a treatment system are applied in the field of zinc-containing solid waste treatment methods and systems, and can solve the problems of impurity chlorine affecting production, high cost, and low recovery rate.

Pending Publication Date: 2021-11-16
CHINA ENFI ENGINEERING CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most iron-vanadium slag, goethite slag, sulfur slag, lead-silver slag, etc. are disposed of in the form of stockpiling, but long-term stockpiling will pollute groundwater sources
[0003] In related technologies, most zinc-containing solid wastes are treated by wet treatment or pyrolysis. However, the process of wet treatment has relatively long process, large reagent consumption, impurity chlorine affects production, and low recovery rate.
However, pyroprocessing has problems such as high energy consumption, high labor intensity, low operation rate, large smoke volume, and large carbon emissions.
The volatilization kiln process not only needs to consume crushed coke, which is costly, but generally the kiln slag cannot be directly applied to other industries, and it needs to be stockpiled or further recovered carbon and iron

Method used

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  • Zinc-containing solid waste treatment method and system
  • Zinc-containing solid waste treatment method and system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0074] The type of zinc-containing solid waste is conventional zinc leaching slag, and the mass ratio of zinc-containing solid waste, flux and reducing agent is 100:0:2.

[0075] Drying the zinc-containing solid waste, flux and reducing agent, the moisture content of the dried zinc-containing solid waste, flux and reducing agent is 1%, and melting the dried zinc-containing solid waste, flux and reducing agent to obtain For high-temperature melt, coke is added in the reduction furnace 3 to reduce and smelt the first slag. The temperature of the reduction smelting is 1200°C, and the reduction time is 2 hours to obtain ferroalloy and zinc-containing flue gas, and then the zinc-containing flue gas enters the zinc powder condenser Get Zinc Dust.

Embodiment 2

[0077] The method of embodiment 2 is the same as that of embodiment 1, except that the mass ratio of zinc-containing solid waste, flux and reducing agent is 100:1:5.

[0078] The zinc-containing solid waste, flux and reducing agent are dried, and the moisture content of the dried zinc-containing solid waste, flux and reducing agent is 1%, and the dried zinc-containing solid waste, flux and reducing agent are smelted to obtain high temperature Melt, add anthracite in the reduction furnace 3 to carry out reduction smelting of the first slag, the temperature of reduction smelting is 1300 ℃, and the reduction time is 3h to obtain ferroalloy and zinc-containing flue gas, and then the zinc-containing flue gas enters the zinc rain condenser to obtain zinc liquid.

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Abstract

The invention relates to the technical field of non-ferrous metal metallurgy, in particular to a zinc-containing solid waste treatment method and system. The treatment method comprises the following steps that zinc-containing solid waste, a flux and a reducing agent are dried, the dried zinc-containing solid waste, the flux and the reducing agent are molten, so that first molten slag and first flue gas are obtained, the first slag is subjected to reduction smelting in a reducing atmosphere, so that second slag and zinc-containing flue gas, or metal alloy and zinc-containing flue gas, or sulfonium and zinc-containing flue gas is obtained, the zinc-containing flue gas is subjected to cooling or oxidation treatment, so that a zinc-containing product is obtained, and the zinc-containing product comprises any one of zinc powder, zinc liquid or zinc oxide. The zinc-containing solid waste treatment method is short in technological process, less in related matching, small in occupied area and low in investment cost, reduces the use of a reducing agent and fuel, and reduces carbon emission and environmental pollution.

Description

technical field [0001] The invention relates to the technical field of nonferrous metal smelting, in particular to a method and system for treating zinc-containing solid waste. Background technique [0002] At present, the zinc-containing solid waste produced by the non-ferrous smelting industry and the iron and steel industry, except for some solid waste with high value, can be used in collaboration with lead and copper industries. Most iron-vanadium slag, goethite slag, sulfur slag, lead-silver slag, etc. are disposed of in the form of stockpiling, but long-term stockpiling will pollute groundwater sources. [0003] In related technologies, most zinc-containing solid wastes are treated by wet treatment or pyrolysis. However, the process of wet treatment has a relatively long process, a large consumption of reagents, impurity chlorine affects production, and the recovery rate is not high. However, pyrolysis has problems such as high energy consumption, high labor intensity...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B19/30C22B19/20C22B7/04
CPCC22B19/30C22B19/20C22B7/04C22B7/001Y02P10/20
Inventor 许良彭思尧吴卫国陈霞张阁宋言
Owner CHINA ENFI ENGINEERING CORPORATION
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