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Medicament for preventing phosphogypsum tailing reuse wastewater from scaling and preparation method thereof

A phosphogypsum and chemical technology, applied in the field of phosphorus chemical industry, can solve the problems of poor use effect, affect the production of enterprises, reduce the temperature of the conveying pipeline, etc., and achieve the effect of convenient recycling operation, reducing economic costs, and prolonging the fouling cycle.

Pending Publication Date: 2021-12-07
湖南中天青鼎工程科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the process of wastewater reuse, the SiF stored in the wastewater 6 2- 、K + 、Na + Plasma is continuously enriched, and the temperature of the wastewater discharged from the production workshop to the tailings pond is high, which eventually leads to the supersaturation of fluorosilicate in the wastewater. Salt precipitates in the pipeline, causing the pipeline to be blocked and affecting the production of the enterprise
[0003] At present, the measures to prevent and control fluorosilicate scaling at home and abroad mainly include cleaning pipes with water, reducing slurry concentration, adding chemical reagents to clean pipes, and mechanical cleaning pipes, etc., but the above-mentioned technologies are not effective enough to meet the production needs of enterprises. ; Therefore, it is urgent to find an easy-to-operate and low-cost technology to solve the problem of fouling of phosphogypsum reuse wastewater pipelines

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Embodiment 1, take calcium oxide, magnesium carbonate, sodium hydroxide and mix and make alkaline compound, the ratio of calcium oxide, magnesium carbonate, sodium hydroxide is 6:3:2, the ratio of adding water is the basic compound quality 10 times, after stirring for 30 minutes, add sodium dodecylbenzenesulfonate with 0.3 times the mass of the basic compound, stir and evaporate at a constant temperature of 80°C for 30 minutes, and obtain the phosphogypsum wastewater scale inhibitor.

[0022] The test water used in this example is the reuse wastewater of a phosphogypsum tailings pond of a phosphorus chemical enterprise in Hubei. The wastewater contains 1.234g / L of fluorosilicate ions. : 300, after stirring for 30 minutes, add aluminum chloride, the ratio of aluminum chloride to waste water is 1: 1800, filter, and the concentration of fluorosilicate ions in the liquid sample drops to 0.560g / L.

Embodiment 2

[0023] Example 2. Calcium oxide, calcium carbonate, magnesium carbonate, and sodium hydroxide were weighed and mixed to make an alkaline compound. The mass ratio of calcium oxide, calcium carbonate, magnesium carbonate, and sodium hydroxide was 6:2:4:1, and The proportion of water is 20 times the mass of the basic compound. After stirring for 30 minutes, add sodium dodecylbenzenesulfonate 0.1 times the mass of the basic compound, stir and evaporate at a constant temperature of 80°C for 35 minutes to obtain the phosphogypsum wastewater scale inhibitor.

[0024] The test water used in this example is the reuse wastewater of a phosphogypsum tailings pond of a phosphorus chemical enterprise in Hubei. The wastewater contains 1.234g / L of fluorosilicate ions. : 270, after stirring for 30 minutes, add aluminum chloride, the ratio of aluminum chloride to wastewater is 1: 1500; filter, the concentration of fluorosilicate ions in the liquid sample drops to 0.430g / L.

Embodiment 3

[0025] Embodiment 3, take calcium oxide, calcium carbonate, magnesium carbonate, sodium hydroxide, potassium hydroxide and mix and make alkaline compound, the mass ratio of calcium oxide, calcium carbonate, magnesium carbonate, sodium hydroxide, potassium hydroxide is 6 : 2:4:1:1, the ratio of adding water is 20 times the mass of the basic compound, after stirring for 30 minutes, add sodium dodecylbenzene sulfonate 0.1 times the mass of the basic compound, and evaporate at a constant temperature of 80°C for 35 minutes. A phosphogypsum wastewater scale inhibitor is obtained.

[0026] The test water used in this example is the reuse wastewater of a phosphogypsum tailings pond of a phosphorus chemical enterprise in Hubei. The wastewater contains 1.234g / L of fluorosilicate ions. : 270, after stirring for 30 minutes, add aluminum chloride, the ratio of aluminum chloride to waste water is 1: 1300; filter, the concentration of fluosilicate ions in the liquid sample drops to 0.290g / L....

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PUM

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Abstract

The invention discloses amedicament for preventing phosphogypsum tailing reuse wastewater from scaling and a preparation method thereof. The components of the medicament comprise an alkaline compound, a solubilizer and water; the contents of the alkaline compound, the solubilizer and the water are as follows: 3-10% of the alkaline compound, 0.1-5% of the solubilizer and the balance of water. The preparation method comprises the following steps of S1, weighing a calcium-containing compound, a sodium-containing compound, a magnesium-containing compound and a potassium-containing compound in proportion, mixing, adding water, and uniformly stirring to obtain an anti-scaling mixture, S2, adding the weighed solubilizer into the anti-scaling mixture, and uniformly stirring again, and S3, evaporating the anti-scaling mixture added with the solubilizer to remove excessive moisture, and crushing to obtain the prepared medicament.

Description

technical field [0001] The invention relates to the field of phosphorus chemical industry, in particular to a medicament for preventing fouling of waste water reused from phosphogypsum tailings and a preparation method thereof. Background technique [0002] The production of phosphoric acid by wet method refers to the dissolution of phosphate rock with sulfuric acid, hydrochloric acid, nitric acid and other acids. The dissolved waste slag and waste water are discharged to the tailings pond for stacking and settlement, and the settled waste water is then reused. During the process of wastewater reuse, the SiF stored in the wastewater 6 2- 、K + 、Na + Plasma is continuously enriched, and the temperature of the wastewater discharged from the production workshop to the tailings pond is high, which eventually leads to the supersaturation of fluorosilicate in the wastewater. Salt precipitates in the pipeline, causing the pipeline to be blocked and affecting the production of t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/08C02F103/10
CPCC02F5/08C02F2103/10
Inventor 张岳安戴锐刘争辉邓金元
Owner 湖南中天青鼎工程科技股份有限公司