Medicament for preventing phosphogypsum tailing reuse wastewater from scaling and preparation method thereof
A phosphogypsum and chemical technology, applied in the field of phosphorus chemical industry, can solve the problems of poor use effect, affect the production of enterprises, reduce the temperature of the conveying pipeline, etc., and achieve the effect of convenient recycling operation, reducing economic costs, and prolonging the fouling cycle.
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Embodiment 1
[0021] Embodiment 1, take calcium oxide, magnesium carbonate, sodium hydroxide and mix and make alkaline compound, the ratio of calcium oxide, magnesium carbonate, sodium hydroxide is 6:3:2, the ratio of adding water is the basic compound quality 10 times, after stirring for 30 minutes, add sodium dodecylbenzenesulfonate with 0.3 times the mass of the basic compound, stir and evaporate at a constant temperature of 80°C for 30 minutes, and obtain the phosphogypsum wastewater scale inhibitor.
[0022] The test water used in this example is the reuse wastewater of a phosphogypsum tailings pond of a phosphorus chemical enterprise in Hubei. The wastewater contains 1.234g / L of fluorosilicate ions. : 300, after stirring for 30 minutes, add aluminum chloride, the ratio of aluminum chloride to waste water is 1: 1800, filter, and the concentration of fluorosilicate ions in the liquid sample drops to 0.560g / L.
Embodiment 2
[0023] Example 2. Calcium oxide, calcium carbonate, magnesium carbonate, and sodium hydroxide were weighed and mixed to make an alkaline compound. The mass ratio of calcium oxide, calcium carbonate, magnesium carbonate, and sodium hydroxide was 6:2:4:1, and The proportion of water is 20 times the mass of the basic compound. After stirring for 30 minutes, add sodium dodecylbenzenesulfonate 0.1 times the mass of the basic compound, stir and evaporate at a constant temperature of 80°C for 35 minutes to obtain the phosphogypsum wastewater scale inhibitor.
[0024] The test water used in this example is the reuse wastewater of a phosphogypsum tailings pond of a phosphorus chemical enterprise in Hubei. The wastewater contains 1.234g / L of fluorosilicate ions. : 270, after stirring for 30 minutes, add aluminum chloride, the ratio of aluminum chloride to wastewater is 1: 1500; filter, the concentration of fluorosilicate ions in the liquid sample drops to 0.430g / L.
Embodiment 3
[0025] Embodiment 3, take calcium oxide, calcium carbonate, magnesium carbonate, sodium hydroxide, potassium hydroxide and mix and make alkaline compound, the mass ratio of calcium oxide, calcium carbonate, magnesium carbonate, sodium hydroxide, potassium hydroxide is 6 : 2:4:1:1, the ratio of adding water is 20 times the mass of the basic compound, after stirring for 30 minutes, add sodium dodecylbenzene sulfonate 0.1 times the mass of the basic compound, and evaporate at a constant temperature of 80°C for 35 minutes. A phosphogypsum wastewater scale inhibitor is obtained.
[0026] The test water used in this example is the reuse wastewater of a phosphogypsum tailings pond of a phosphorus chemical enterprise in Hubei. The wastewater contains 1.234g / L of fluorosilicate ions. : 270, after stirring for 30 minutes, add aluminum chloride, the ratio of aluminum chloride to waste water is 1: 1300; filter, the concentration of fluosilicate ions in the liquid sample drops to 0.290g / L....
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