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Negative electrode lithium supplementing method and manufacturing method of lithium ion energy storage device

A production method and technology of lithium ions, which are applied in the production of lithium ion energy storage devices, and in the field of negative electrode lithium supplementation with a sandwich structure, can solve the problems of poor uniformity and low efficiency of negative electrode lithium supplementation, and achieve reduced transmission distance and good compatibility , the effect of controlling the uniformity

Active Publication Date: 2021-12-07
ZHEJIANG ZHENENG TECHN RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is to overcome the deficiencies in the prior art, provide a method for supplementing lithium at the negative electrode and a manufacturing method of a lithium-ion energy storage device, and solve the problems of low efficiency and poor uniformity of lithium supplementation at the negative electrode without losing the energy density of the battery

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  • Negative electrode lithium supplementing method and manufacturing method of lithium ion energy storage device
  • Negative electrode lithium supplementing method and manufacturing method of lithium ion energy storage device
  • Negative electrode lithium supplementing method and manufacturing method of lithium ion energy storage device

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Embodiment 1

[0032] Embodiment 1 of the present application provides a lithium-ion energy storage device. The lithium-ion energy storage device is a lithium-ion capacitor or a lithium-ion battery. Both the lithium-ion capacitor and the lithium-ion battery include a positive pole piece 8, a negative pole piece, an electrolyte, and a positive and negative pole. The separator 9 between them; the positive pole piece 8 includes a positive current collector and a positive active layer on the positive current collector; the negative pole piece is a sandwich structure, including two layers of porous double-sided copper-plated film current collectors, two The metal lithium electrode layer 6 between the porous double-sided copper-plated thin film current collectors and the negative electrode active layer 4 outside the two-layer porous double-sided copper-plated thin film current collectors, the electrolyte and the separator are both lithium ion capacitors and lithium ion capacitors. Conventional elec...

Embodiment 2

[0037] Embodiment 2 of the present application provides a method for manufacturing a lithium ion energy storage device, comprising the following steps:

[0038]S1, making a double-sided copper-plated thin film current collector 7, coating the negative electrode active material on one side of the double-sided copper-plated thin film current collector 7, then drying and cold pressing, die-cutting, slitting and other processes, and then The negative electrode active material is coated with a physical punching method to form holes such as figure 1 The shown porous negative electrode belt 5, the distribution of holes is as follows figure 2 shown.

[0039] S2, two rolls of porous negative electrode strips 5 and one roll of metal lithium electrode layer 6 are image 3 The structure and sequence are stacked together, the two layers of porous negative electrode belts are coated with the negative electrode active material side facing outward, the metal lithium electrode layer 6 is re...

Embodiment 3

[0047] Embodiment 3 of the present application provides a negative electrode lithium replenishment method: the scheme of external circuit control is to replenish lithium by means of short circuit, load connection or external power supply control; this embodiment adopts the control mode of external power supply to replenish lithium.

[0048] The control method of the external power supply is as follows: the negative pole ear is connected to the positive pole of the external power supply, the metal lithium electrode is connected to the negative pole of the external power supply, and then one or more than two test methods such as constant current, constant voltage and constant power are used to supplement lithium. . Experiments have shown that it is possible to control the lithium replenishment time by adjusting the constant current, constant voltage or constant power. At the same time, the lithium ions can be evenly transferred from the metal lithium to the negative electrode act...

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Abstract

The invention relates to a negative electrode lithium supplementing method and a manufacturing method of a lithium ion energy storage device, and the manufacturing method of the lithium ion energy storage device comprises the following steps: S1, manufacturing a porous negative electrode belt; S2, stacking two rolls of porous negative electrode belts and one roll of metal lithium electrode layer together, and pre-pressing to form a negative electrode plate with a sandwich structure; and S3, manufacturing and forming the lithium ion energy storage device. According to the negative electrode lithium supplementing method, lithium supplementing is carried out by adopting an external power supply control mode, a negative electrode lug is connected with a positive electrode of an external power supply, a metal lithium electrode is connected with a negative electrode of the external power supply, and then lithium supplementing is carried out by adopting one or more than two testing methods of constant current, constant voltage or constant power. The beneficial effects are that: the double-sided copper-plated film is used as the base material, and the single surface of the base material is coated with the negative active material, although the volume of the double-layer copper-plated film current collector is increased, the energy density of the battery can be well ensured due to the light weight of the material.

Description

technical field [0001] The invention relates to the technical field of lithium-ion capacitors and lithium-ion battery energy storage devices, in particular to a method for supplementing lithium with a negative electrode of a sandwich structure and a manufacturing method of a lithium-ion energy storage device. Background technique [0002] Lithium-ion capacitors are a new asymmetric hybrid energy storage device that uses lithium-ion negative electrode lithium-intercalated materials as the negative electrode, and activated carbon materials in supercapacitors as the positive electrode. This asymmetric hybrid energy storage device has the characteristics of high specific power and long life of a supercapacitor, and at the same time has an energy density that is more than 50% higher than that of a symmetrical electric double layer supercapacitor. It has broad application prospects in scenarios that require both high power and high energy density (vehicle energy storage, rail tran...

Claims

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Application Information

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IPC IPC(8): H01M10/42H01M4/66H01M4/80H01M10/0525H01M10/0585H01M10/0587H01G11/06H01G11/26H01G11/30H01G11/50H01G11/84H01G11/86
CPCH01M10/4235H01M10/0525H01M4/667H01M4/80H01M10/0585H01M10/0587H01G11/50H01G11/30H01G11/26H01G11/06H01G11/84H01G11/86H01M2004/027Y02E60/10Y02P70/50
Inventor 吴田马福元赵宇臧孝贤赵旭成城
Owner ZHEJIANG ZHENENG TECHN RES INST