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Corrosion-resistant, high-temperature-resistant and super-hydrophobic polyphenylene sulfide composite material and preparation method thereof

A polyphenylene sulfide and composite material technology, which is applied in the field of polyphenylene sulfide composite material and its preparation, can solve the problems of complex use environment and need to improve mechanical properties, and achieves simple preparation method, high heat resistance and mechanical properties. excellent effect

Pending Publication Date: 2021-12-21
ANHUI YUANCHEN ENVIRONMENTAL PROTECTION SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the development of the times, the purpose and use environment of PPS become more and more complex, so the performance requirements of PPS are also getting higher and higher, and a single performance often cannot meet the needs of actual production, so researchers put Focus on the research and development of PPS materials with various properties
[0003] The patent application with publication number CN109280387A discloses polyphenylene sulfide composite material and its preparation method. The prepared polyphenylene sulfide composite material has good thermal conductivity and mechanical properties, but its mechanical properties still need to be improved

Method used

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  • Corrosion-resistant, high-temperature-resistant and super-hydrophobic polyphenylene sulfide composite material and preparation method thereof

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Effect test

Embodiment 1

[0028] Corrosion-resistant, high-temperature-resistant, superhydrophobic polyphenylene sulfide composite material, its raw material ratio is as follows: polyphenylene sulfide resin 3kg, modified TiO 2 3kg, polytetrafluoroethylene 2kg, silane coupling agent 1kg, EPDM rubber grafted maleic anhydride 0.5kg, stearic acid 0.5kg. The average molecular weight of the polyphenylene sulfide resin in this embodiment is 10000, but it is not limited thereto.

[0029] Its preparation method is as follows:

[0030] (1) Preparation of modified filler: 50 grams of hydroxy silicone oil, 10 grams of tetraethyl orthosilicate, 1 gram of dibutyltin dilauric acid, and 1000 grams of hexane were added to the flask and stirred at a speed of 300 r / min for 20 minutes to make it Mix well, then add 2000 grams of TiO 2 Continue to stir for 20 minutes, finally filter, wash and dry to obtain modified TiO 2 filler.

[0031] (2) Weigh the raw materials according to the ratio in the above formula, stir in a...

Embodiment 2

[0035] Corrosion-resistant, high-temperature-resistant, superhydrophobic polyphenylene sulfide composite material, its raw material ratio is as follows: polyphenylene sulfide resin 4kg, modified SiO 2 2kg, polytetrafluoroethylene 2kg, silane coupling agent 1kg, hydrogenated styrene-butadiene-styrene graft maleic anhydride 0.5kg, stearic acid 0.5kg. The average molecular weight of the polyphenylene sulfide resin in this embodiment is 10000, but it is not limited thereto.

[0036] Its preparation method is as follows:

[0037] (1) Preparation of modified filler: 50 grams of hydroxy silicone oil, 10 grams of tetraethyl orthosilicate, 1 gram of dibutyltin dilauric acid, and 1000 grams of hexane were added to the flask and stirred at a speed of 300 r / min for 20 minutes to make it Mix well, then add 2000 g SiO 2 Continue to stir for 20 minutes, finally filter, wash and dry to obtain modified SiO 2 filler.

[0038] (2) Weigh the raw materials according to the ratio in the above ...

Embodiment 3

[0042] Corrosion-resistant, high-temperature-resistant, superhydrophobic polyphenylene sulfide composite material, its raw material ratio is as follows: polyphenylene sulfide resin 3kg; modified BaSO 4 3kg; polytetrafluoroethylene 1kg; silane coupling agent 2kg; ethylene-acrylate-glycidyl methacrylate terpolymer 0.5kg; stearic acid 0.5kg. The average molecular weight of polyphenylene sulfide resin in the present embodiment is 10000, and the melt flow index of ethylene-acrylate-glycidyl methacrylate terpolymer is 9g / 10min (190 ℃ / 2.16kg), but not only limited to this.

[0043] Its preparation method is as follows:

[0044](1) Preparation of modified filler: 50 grams of hydroxy silicone oil, 10 grams of tetraethyl orthosilicate, 1 gram of dibutyltin dilauric acid, and 1000 grams of hexane were added to the flask and stirred at a speed of 300 r / min for 20 minutes to make it Mix well, then add 2000 g BaSO 4 Continue to stir for 20 minutes, finally filter, wash and dry to obtain...

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Abstract

The invention discloses a corrosion-resistant, high-temperature-resistant and super-hydrophobic polyphenylene sulfide composite material, and relates to the technical field of polyphenylene sulfide composites, the corrosion-resistant, high-temperature-resistant and super-hydrophobic polyphenylene sulfide composite material is mainly prepared from the following raw materials by mass: 20-40% of polyphenylene sulfide resin, 10-30% of a modified filler, 10-30% of polytetrafluoroethylene, 10-20% of a silane coupling agent, 5-10% of a compatilizer, and 5-10% of stearic acid; and the preparation method of the modified filler comprises the following steps: mixing and stirring hydroxyl silicone oil, tetraethyl orthosilicate, dibutyltin dilaurate and hexane according to a mass ratio of 5: 1: 0.1: 100, then adding inorganic nanoparticles, stirring, filtering, washing and drying to obtain the modified filler. The invention also provides a preparation method of the polyphenylene sulfide composite material. The polyphenylene sulfide composite material disclosed by the invention has the beneficial effects that the polyphenylene sulfide composite material has very high heat resistance, corrosion resistance and hydrophobicity due to the adoption of the raw materials in percentage by mass and a synergistic effect among the raw materials.

Description

technical field [0001] The invention relates to the technical field of polyphenylene sulfide composite materials, in particular to a corrosion-resistant, high-temperature-resistant, superhydrophobic polyphenylene sulfide composite material and a preparation method thereof. Background technique [0002] Polyphenylene sulfide (PPS) is a new type of high-performance thermoplastic resin, which has the advantages of high mechanical strength, high temperature resistance, and chemical resistance. Therefore, it is made into pipes, fibers, coatings, etc. and is used in various fields. With the development of the times, the purpose and use environment of PPS become more and more complex, so the performance requirements of PPS are also getting higher and higher, and a single performance often cannot meet the needs of actual production, so researchers put Focus on the research and development of PPS materials with various properties. [0003] The patent application with publication num...

Claims

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Application Information

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IPC IPC(8): C08L81/02C08L27/18C08K9/06C08K9/04C08K3/22C08K3/36C08K3/30C08K3/34
CPCC08L81/02C08L2201/08C08K2003/2241C08K2003/3045C08L27/18C08K9/06C08K9/04C08K9/08C08K3/22C08K3/36C08K3/30C08K3/346
Inventor 赵羽王光应徐辉
Owner ANHUI YUANCHEN ENVIRONMENTAL PROTECTION SCI & TECH
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