Aramid fiber antibacterial dyeing one-bath treatment method

A treatment method, aramid fiber technology, applied in dyeing, textiles and papermaking, etc., can solve problems affecting aramid fiber crystallization, lower product quality, complicated process, etc., achieve good color fastness to rubbing, no harmful gas emissions, The effect of dyeing effect is obvious

Pending Publication Date: 2021-12-31
NANTONG UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The aramid structure has two layers of skin and core. The high strength and high modulus of aramid fiber is mainly determined by the inner high crystallization core layer. In the application process, especially in some humid or outdoor exposure application environments, aramid fiber It is easy to mold in the material, and when a large amount of mold gathers, it will cause damage to the aramid fiber filament, thereby reducing the quality of the product it is applied to
[0003] Therefore, when people produce aramid fibers, they need to be treated with mildew and antibacterial treatment. In the traditional treatment method, one is to add antibacterial agents during the spinning process of aramid fibers, so that the antibacterial agents can be integrated into the aramid fibers. The process of the method is relatively complicated and the cost is high. At the same time, because the antibacterial agent exists inside the aramid fiber, it will destroy the regularity of the molecules, affect the crystallization of the aramid fiber, and greatly reduce the tensile strength of the aramid fiber; The first is to graft antibacterial agents on the surface of aramid fibers through chemical reactions, but this method requires a long processing time and high cost. Multi-active groups, when the antibacterial agent is grafted onto the aramid fiber, this reaction process will have a great impact on the performance of the aramid fiber, and also greatly reduce the tensile strength of the aramid fiber

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Aramid fiber antibacterial dyeing one-bath treatment method
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  • Aramid fiber antibacterial dyeing one-bath treatment method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Prepare the dye solution according to the following process formula, put the dye solution and aramid fabric into the dyeing cup, then put the dyeing cup into the high-temperature dyeing machine, raise the temperature to 60°C, and keep it warm for 30 minutes to make the carrier and the fabric evenly interact. After the heat preservation is over, the temperature is raised to 130°C at 2°C / min, dyed for 60 minutes, and the temperature is lowered to 40°C after the dyeing is completed.

[0035] Process formula for dyeing and antibacterial treatment in the same bath:

[0036] cationic dye 2% (o.w.f.) Carrier / g·L -1

40 Sodium sulfate / g·L -1

50 Silver nitrate / g.L -1

0 pH value 4.0 temperature / ℃ 130 time / min 60 bath ratio 1:50

[0037] .

[0038] Finally, wash the dyed fabric with cold water and hot water. After washing, put the dyed fabric into a beaker and add the prepared soaping agent. Put the beaker in a w...

Embodiment 2

[0040] Prepare the dye solution according to the following process formula, put the dye solution and aramid fabric into the dyeing cup, then put the dyeing cup into the high-temperature dyeing machine, raise the temperature to 60°C, and keep it warm for 30 minutes to make the carrier and the fabric evenly interact. After the heat preservation is over, the temperature is raised to 130°C at 2°C / min, dyed for 60 minutes, and the temperature is lowered to 40°C after the dyeing is completed.

[0041] Process formula for dyeing and antibacterial treatment in the same bath:

[0042] cationic dye 2% (o.w.f.) Carrier / g·L -1

40 Sodium sulfate / g·L -1

50 Silver nitrate / g.L -1

0.3 pH value 4.0 temperature / ℃ 130 time / min 60 bath ratio 1:50

[0043] .

[0044] Finally, wash the dyed fabric with cold water and hot water. After washing, put the dyed fabric into a beaker and add the prepared soaping agent. Put the beaker in a...

Embodiment 3

[0046] First, the aramid fabric is pretreated (10g / L degreaser, soaked at 95°C for 30min, after scouring, the temperature is lowered to 40°C, washed and dried); secondly, the antibacterial aramid dyed fabric is prepared by the cationic carrier dyeing method.

[0047] Process formula for dyeing and antibacterial treatment in the same bath:

[0048] cationic dye 2% (o.w.f.) Carrier / g·L -1

40 Sodium sulfate / g·L -1

50 Silver nitrate / g.L -1

0.6 pH value 4.0 temperature / ℃ 130 time / min 60 bath ratio 1:50

[0049] .

[0050] Finally, wash the dyed fabric with cold water and hot water. After washing, put the dyed fabric into a beaker and add the prepared soaping agent. Put the beaker in a water bath at 40°C, raise the temperature to 95°C and keep it warm for 25 minutes. After soaping, cool down to 60°C, wash the fabric in hot water and then in cold water, and finally put it in an oven for drying.

[0051] The dyed f...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention provides an aramid fiber antibacterial dyeing one-bath treatment method. The method comprises the following steps of S1, sequentially adding a carrier and sodium sulfate into a cationic dye to obtain a mixed solution; S2, adding silver nitrate into the mixed solution prepared in the step S1, adjusting the pH value to 3-5 after uniform stirring, and obtaining a dye liquor; and S3, putting an aramid fabric and the dye liquor obtained in the step S2 into a dyeing cup, putting the dyeing cup into a high-temperature dyeing machine, raising the temperature to 60-100 DEG C, keeping the temperature for 20-50 minutes until the carrier and the fabric act uniformly, after heat preservation is finished, increasing the temperature to 120-140 DEG C at the speed of 2 DEG C/min, dyeing for 50-80 min, and after dyeing is finished, cooling to 40 DEG C, soaping and drying. According to the method, aramid fiber is dyed by using the cationic dye, and the dye has positive charges, so that the dye mainly exists in a dye bath in an ionic form, but the main combination mode between the dye and the fiber is not an ionic bond, but hydrogen bonds, Van der Waals' force and the like, and the dyeing effect is obvious. Meanwhile, the dyed aramid fiber has good color fastness to rubbing, soaping fastness and better color fastness to sunlight.

Description

technical field [0001] The invention belongs to the field of textile dyeing and finishing, and in particular relates to a one-bath treatment method for antibacterial dyeing of aramid fiber, which enables the aramid fiber to have an antibacterial effect while being dyed. Background technique [0002] Aramid is a new type of high-tech synthetic fiber with excellent properties such as ultra-high strength, high modulus, high temperature resistance, acid and alkali resistance, light weight, insulation, anti-aging, and long life cycle. It is widely used in composite materials and bulletproof products. , building materials, special protective clothing, electronic equipment and other fields, often used in the manufacture of ropes, ribbons, weaving, reinforced cables and optical cables, cables for ships, and packing for sealing and other products. The aramid structure has two layers of skin and core. The high strength and high modulus of aramid fiber is mainly determined by the inner...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/00D06P1/673D06P3/24
CPCD06P1/00D06P1/67341D06P3/24
Inventor 高晓红楼婷飞刘杰张雪婷房双萍邹添添
Owner NANTONG UNIVERSITY
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