Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of organic/inorganic nano composite microsphere optooptic material

An inorganic nano-composite microsphere technology, applied in the field of ophthalmic optics, can solve the problems of indistinguishable, unacceptable appearance of bright red and green, decreased vision, etc., to achieve the effect of improving the degree of vividness, good rigidity, and reducing conversion obstacles

Active Publication Date: 2022-02-11
JIANGSU SHIKEXINCAI CO LTD
View PDF8 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But in this way, some people can rely on the difference in brightness to distinguish "color" when they don't wear traditional color-blindness correction glasses, but they can't distinguish when they wear this kind of color-blindness correction glasses.
Not only that, but people who wear traditional color-blindness correction glasses will always have some decline in overall vision, and the bright red and green appearance is also unacceptable

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of organic/inorganic nano composite microsphere optooptic material
  • Preparation method of organic/inorganic nano composite microsphere optooptic material
  • Preparation method of organic/inorganic nano composite microsphere optooptic material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Embodiment 1: Preparation of organic / inorganic nanocomposite microspheres and color vision correction lenses

[0065] (1) Preparation of organic / inorganic nanocomposite microspheres:

[0066] (1) Take 3g of emulsifier RF-345 and add it to 1200g of pure water. After it is completely dissolved, add 35g of nano-iron oxide, add 150g of sodium acetate saturated aqueous solution dropwise within 70min, and then add 20g of crosslinking agent DAP; Enter nitrogen, add 150 g of dichloromethane solvent containing spiropyran compound (formula I) (spiropyran 35 g solvent 115 g), add methyl acrylate monomer 18 g and ethyl acrylate monomer 10 g, stir and heat up to 65 ° C, add Initiator ammonium persulfate 0.1g, keep warm for 18h, filter, wash and dry to obtain acrylate / spiropyran / iron oxide deep red nanospheres. The yield was 85%.

[0067] (2) The product prepared in step (1) is observed with a JEM-2100 transmission electron microscope, as figure 1 As shown, it can be seen that the...

Embodiment 2

[0072] Embodiment 2: Preparation of organic / inorganic nanocomposite microspheres and color vision correction lenses

[0073] (1) Preparation of organic / inorganic nanocomposite microspheres:

[0074] 1. Take 2.5g of emulsifier RF-345 and add it to 1100g of pure water. After it is completely dissolved, add 30g of nano-copper oxide, add 120g of sodium acetate saturated aqueous solution dropwise within 70min, and then add 20g of cross-linking agent DAP; Enter nitrogen, add 145g of dichloromethane solvent containing spiropyran compound (formula I) (spiropyran 35g solvent 110g), add methyl acrylate monomer 18g and ethyl acrylate monomer 10g, stir and heat up to 65 ° C, add Initiator ammonium persulfate 0.1g, keep warm for 16h, filter, wash and dry to obtain acrylate / spiropyran / copper oxide nanospheres. The yield was 82%.

[0075] 2. The product prepared in step 1 is observed with a transmission electron microscope, as figure 2 As shown in the figure, it can be seen that the appe...

Embodiment 3

[0081] Example 3: Preparation of organic / inorganic nanocomposite microspheres and color vision correction lenses

[0082] (1) Preparation of organic / inorganic nanocomposite microspheres:

[0083] a. Take 2.4g of emulsifier sodium dodecylbenzenesulfonate and add it to 1000g of pure water. After it is completely dissolved, add 30g of nano-cobalt oxide, add 140g of sodium acetate saturated aqueous solution dropwise within 70min, and then add the crosslinking agent butyl acrylate 20g; feed nitrogen into the reaction kettle, add 145g of dichloromethane solvent containing spiropyran compound (formula I) (105g of spiropyran 40g solvent), add 28g of methyl acrylate monomer, stir and heat up to 65°C, add Initiator sodium persulfate 0.1g, keep warm for 16h, filter, wash and dry to obtain acrylate / spiropyran / cobalt oxide nanospheres. The yield was 80%.

[0084] b. the product prepared in step a is observed through a transmission electron microscope, such as image 3 As shown in the fi...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
diameteraaaaaaaaaa
thicknessaaaaaaaaaa
Login to View More

Abstract

The invention relates to a preparation method of an organic / inorganic nano composite microsphere optooptic material, wherein the preparation method comprises the steps: I, weighing an acrylate monomer, a spiropyrane compound represented by a formula (I) and transition metal oxide nanoparticles according to a mass ratio of (1-2):(2-3):(2-4); II, adding an emulsifier, transition metal oxide nanoparticles and a sodium acetate saturated aqueous solution into water; III, adding a cross-linking agent into the reaction system, introducing nitrogen, and adding a spiropyrane compound solution; and IV, adding an acrylate monomer, adding an initiator at the temperature of 65-90 DEG C, carrying out heat preservation polymerization for 12-18 hours, filtering, washing and drying. The material prepared by the method is of a three-layer composite core-shell structure, and can be added into a resin optical material or an optical lens as a light-filtering color-complementing material. The lens material is dark in color under indoor normal light, can automatically enhance the spectral color purity of a certain wave band and the dimension of a color vision vector space, improves the color discrimination ability of a color blindness patient, and corrects color vision abnormality.

Description

technical field [0001] The invention belongs to the technical field of ophthalmology and optics, and in particular relates to a preparation method of a color vision correction optometry material. Background technique [0002] Color vision is one of the important visual functions of the eye. The seven colors of the visible spectrum in sunlight can be attributed to the three primary colors, namely red, green and blue. Retinal cone cells contain red, green and blue pigments. The human eye can recognize more than 100 different colors. Congenital abnormalities of color vision are caused by an abnormal lack of chromogenic pigments in cone cells. It can usually be divided into panchromatopsia, red-green color blindness and red-green color blindness. Monochromatic vision with only one color-sensing pigment, that is, panchromatic vision; people with two color-sensing pigments are dichromatism, and those who lack red-sensing or green-sensing pigments are red-green color blindness; t...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B01J13/14B01J13/02G02B1/00G02C7/10
CPCB01J13/14B01J13/02G02C7/102G02C7/104G02B1/00
Inventor 蹇锡高王锦艳王明华张鹤军司云凤刘洋郑永华薛晓花吴潇
Owner JIANGSU SHIKEXINCAI CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com