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Aliphatic and aromatic copolyester foaming composition, aliphatic and aromatic copolyester foamed plate and sheet, and preparation methods of aliphatic and aromatic copolyester foamed plate and sheet

A technology of aromatic copolyester and foaming composition, applied in the field of foaming materials, can solve the problems of low cell density, uncontrollable density, poor mechanical properties, etc., achieve low production cost, improve mechanical properties, and thermal insulation properties Good results

Pending Publication Date: 2022-02-18
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the low cell density of the aliphatic aromatic copolyester foamed sheet caused by the existence of inorganic nucleating agents and poor compatibility with the polymer matrix in the prior art, which is not easy to slice, has poor mechanical properties and uncontrollable density To solve the problem, provide a kind of aliphatic aromatic copolyester foaming composition, aliphatic aromatic copolyester foaming plate and sheet and preparation method thereof, the aliphatic aromatic copolyester foaming composition prepared by the present invention Foam boards and sheets are controllable degradation in line with environmental protection requirements, dense cells, easy to slice, excellent mechanical properties, simple preparation process, wide adjustable range of magnification, good thermal insulation performance, low production cost and suitable for large-scale production

Method used

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  • Aliphatic and aromatic copolyester foaming composition, aliphatic and aromatic copolyester foamed plate and sheet, and preparation methods of aliphatic and aromatic copolyester foamed plate and sheet
  • Aliphatic and aromatic copolyester foaming composition, aliphatic and aromatic copolyester foamed plate and sheet, and preparation methods of aliphatic and aromatic copolyester foamed plate and sheet
  • Aliphatic and aromatic copolyester foaming composition, aliphatic and aromatic copolyester foamed plate and sheet, and preparation methods of aliphatic and aromatic copolyester foamed plate and sheet

Examples

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preparation example Construction

[0086] The third aspect of the present invention provides a preparation method of aliphatic aromatic copolyester foamed sheet, which is characterized in that the method comprises: melting and granulating the above-mentioned aliphatic aromatic copolyester foam composition to obtain aliphatic aromatic copolyester After pelletizing, the pellets are extruded into sheets for foaming.

[0087] According to the present invention, preferably, the foaming is a compression foaming method.

[0088] In the present invention, the granulation and plate extrusion can be carried out in various existing ways, and the specific operation process is well known to those skilled in the art.

[0089] According to the present invention, the compression foaming method comprises the following steps:

[0090] (1) foaming mold is heated up to foaming temperature;

[0091] (2) Place the aliphatic aromatic copolyester board in a foaming mold, introduce a foaming agent, and perform foaming to obtain the a...

Embodiment 1

[0127] This example is used to illustrate the PBST chain extension modification, foamed plate and foamed sheet provided by the present invention.

[0128] The PBST composition provided in this example contains the PBST chain extension modification provided by the present invention, a cell nucleating agent and a processing aid.

[0129] In the presence of catalyst, with terephthalic acid (PTA) 423.8g, succinic acid (SA) 330g, 1,4-butanediol (BDO) 650g, glycerol 1g is raw material, prepares copolyester PBST1, its The melt index at 190°C and a load of 2.16 kg was 44.9 g / 10 min. Among them, the catalyst contains 0.322g of ethylene glycol antimony, 0.43g of lanthanum chloride, and 0.14g of triphenylhydroxytin.

[0130] 500g of PBST1 and 2.5g of dibenzoyl peroxide were extruded in an extruder at 160°C to prepare copolyester PBST2, which had a melt index of 1.7g / 10min at 190°C and a load of 2.16kg, and a molecular weight of The distribution is 5.95.

[0131] The cell nucleating ag...

Embodiment 2

[0143] This example is used to illustrate the PBAT chain extension modified product, foamed plate and foamed sheet provided by the present invention.

[0144] The PBAT composition provided in this example contains the PBAT chain-extended modified product provided by the present invention, a cell nucleating agent and a processing aid.

[0145] In the presence of a catalyst, 423.8g of terephthalic acid (PTA), 466.7g of 1,6-adipic acid (AA), 650g of 1,4-butanediol (BDO), and 0.5g of pyromellitic dianhydride As starting material, a copolyester PBAT1 was prepared which had a melt index of 31.7 g / 10 min at 190° C. and a load of 2.16 kg. Among them, the catalyst contained 0.288 g of tetrabutyl titanate, 0.37 g of indium chloride, and 0.1 g of dibutyltin oxide.

[0146] 500g of PBAT1 and 5g of dicumyl peroxide were extruded in an extruder at 170°C to prepare copolyester PBAT2, which had a melt index of 1.2g / 10min at 190°C and a load of 2.16kg, and a molecular weight distribution of ...

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Abstract

The invention relates to the field of foaming materials, and discloses an aliphatic and aromatic copolyester foaming composition, an aliphatic and aromatic copolyester foamed plate, an aliphatic and aromatic copolyester foamed sheet, and preparation methods of the foamed plate and the foamed sheet. The composition comprises modified aliphatic and aromatic copolyester, a foam nucleating agent and an antioxidant, wherein the foam nucleating agent is a maleic anhydride-styrene-alpha-methylstyrene copolymer microsphere with a particle size of 500-1600 nm; the melt index of the modified aliphatic and aromatic copolyester at 190 DEG C under a load of 2.16 kg is 0.1-5 g / 10 min; and based on 100 parts by weight of the aliphatic and aromatic copolyester, the use amount of the foam nucleating agent is 0.01-10 parts by weight, and the use amount of the antioxidant is 0.01-3 parts by weight. The foamed board and the foamed sheet prepared from the aliphatic and aromatic copolyester foaming composition meet the environment-friendly requirement for controllable degradation, and are compact in foam holes, easy to slice, excellent in mechanical properties, simple in process, large in the adjustable range of multiplying power, good in heat preservation performance, low in production cost and suitable for large-scale production.

Description

technical field [0001] The invention relates to the field of foam materials, in particular to an aliphatic aromatic copolyester foam composition, aliphatic aromatic copolyester foam boards and sheets and a preparation method thereof. Background technique [0002] Plastic products have the advantages of strong stability, light weight, and low production cost, so they are deeply favored by people. In recent decades, the plastic industry has developed rapidly, and the use of a large number of plastic products, especially disposable plastic products, has brought great convenience to human life. However, due to the chemical stability of general-purpose plastics (PE, PS, PVC, etc.), when they are abandoned, they will exist stably in the environment for a long time, resulting in the accumulation of a large amount of plastic waste in the environment, which brings serious harm to the environment. , Such as white pollution, agricultural white cancer and other issues. With the increa...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08L35/00C08J9/12
CPCC08J9/122C08J9/0061C08J2203/08C08J2203/06C08J2367/02C08J2205/044
Inventor 徐耀辉郭鹏吕明福祝桂香张师军高达利韩翎张伟白弈青
Owner CHINA PETROLEUM & CHEM CORP