Aliphatic and aromatic copolyester foaming composition, aliphatic and aromatic copolyester foamed plate and sheet, and preparation methods of aliphatic and aromatic copolyester foamed plate and sheet
A technology of aromatic copolyester and foaming composition, applied in the field of foaming materials, can solve the problems of low cell density, uncontrollable density, poor mechanical properties, etc., achieve low production cost, improve mechanical properties, and thermal insulation properties Good results
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[0086] The third aspect of the present invention provides a preparation method of aliphatic aromatic copolyester foamed sheet, which is characterized in that the method comprises: melting and granulating the above-mentioned aliphatic aromatic copolyester foam composition to obtain aliphatic aromatic copolyester After pelletizing, the pellets are extruded into sheets for foaming.
[0087] According to the present invention, preferably, the foaming is a compression foaming method.
[0088] In the present invention, the granulation and plate extrusion can be carried out in various existing ways, and the specific operation process is well known to those skilled in the art.
[0089] According to the present invention, the compression foaming method comprises the following steps:
[0090] (1) foaming mold is heated up to foaming temperature;
[0091] (2) Place the aliphatic aromatic copolyester board in a foaming mold, introduce a foaming agent, and perform foaming to obtain the a...
Embodiment 1
[0127] This example is used to illustrate the PBST chain extension modification, foamed plate and foamed sheet provided by the present invention.
[0128] The PBST composition provided in this example contains the PBST chain extension modification provided by the present invention, a cell nucleating agent and a processing aid.
[0129] In the presence of catalyst, with terephthalic acid (PTA) 423.8g, succinic acid (SA) 330g, 1,4-butanediol (BDO) 650g, glycerol 1g is raw material, prepares copolyester PBST1, its The melt index at 190°C and a load of 2.16 kg was 44.9 g / 10 min. Among them, the catalyst contains 0.322g of ethylene glycol antimony, 0.43g of lanthanum chloride, and 0.14g of triphenylhydroxytin.
[0130] 500g of PBST1 and 2.5g of dibenzoyl peroxide were extruded in an extruder at 160°C to prepare copolyester PBST2, which had a melt index of 1.7g / 10min at 190°C and a load of 2.16kg, and a molecular weight of The distribution is 5.95.
[0131] The cell nucleating ag...
Embodiment 2
[0143] This example is used to illustrate the PBAT chain extension modified product, foamed plate and foamed sheet provided by the present invention.
[0144] The PBAT composition provided in this example contains the PBAT chain-extended modified product provided by the present invention, a cell nucleating agent and a processing aid.
[0145] In the presence of a catalyst, 423.8g of terephthalic acid (PTA), 466.7g of 1,6-adipic acid (AA), 650g of 1,4-butanediol (BDO), and 0.5g of pyromellitic dianhydride As starting material, a copolyester PBAT1 was prepared which had a melt index of 31.7 g / 10 min at 190° C. and a load of 2.16 kg. Among them, the catalyst contained 0.288 g of tetrabutyl titanate, 0.37 g of indium chloride, and 0.1 g of dibutyltin oxide.
[0146] 500g of PBAT1 and 5g of dicumyl peroxide were extruded in an extruder at 170°C to prepare copolyester PBAT2, which had a melt index of 1.2g / 10min at 190°C and a load of 2.16kg, and a molecular weight distribution of ...
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