Magnesium hydroxide modified waste brick, preparation method thereof and application of magnesium hydroxide modified waste brick in artificial wetland system

A constructed wetland system and magnesium hydroxide technology are applied in magnesium hydroxide modified waste bricks and their preparation, and the application field in constructed wetland systems can solve the problems affecting the denitrification and phosphorus removal efficiency, the loss of magnesium hydroxide powder, and the inability to directly application and other issues, to achieve the effect of improving the efficiency of nitrogen and phosphorus removal, promoting microbial activity, and promoting resource utilization

Pending Publication Date: 2022-04-12
CHINA URBAN CONSTR DESIGN & RES INST CO LTD
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  • Application Information

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Problems solved by technology

For example, the paper "Research on the Use of Magnesium Hydroxide for Removing Ammonia Nitrogen in Wastewater" uses magnesium hydroxide as the magnesium source and adds phosphate to remove ammonia nitrogen in wastewater. However, magnesium hydroxide powder is easy to lose with water flow and cannot be directly applied to constructed wetlands. among other facilities
As another example, CN108325498A discloses a method for synchronously recovering nitrogen and phosphorus in wastewater by using magnesium hydroxide-modified sepiolite. Magnesium hydroxide-modified sepiolite is used for synchronously recovering nitrogen and phosphorus in wastewater, but it uses MgCl 2 As a magnesium source, the cost of modification is high, and the method is more suitable for loading materials with large porosity itself. For materials with low porosity such as waste bricks, the loading capacity is low, which affects the efficiency of nitrogen and phosphorus removal.

Method used

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  • Magnesium hydroxide modified waste brick, preparation method thereof and application of magnesium hydroxide modified waste brick in artificial wetland system
  • Magnesium hydroxide modified waste brick, preparation method thereof and application of magnesium hydroxide modified waste brick in artificial wetland system
  • Magnesium hydroxide modified waste brick, preparation method thereof and application of magnesium hydroxide modified waste brick in artificial wetland system

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preparation example Construction

[0040] One embodiment of the present invention proposes a preparation method of magnesium hydroxide modified waste brick, which is characterized in that it comprises the following steps:

[0041] (1) Broken and sieved construction waste bricks to obtain waste brick particles;

[0042] (2) Air plasma treatment is carried out to the above-mentioned waste brick particles to obtain waste bricks etched by plasma;

[0043] (3) Disperse the waste bricks etched by the above plasma into seawater, first ultrasonic, and dropwise add sodium hydroxide solution, second ultrasonic, wash, and dry to obtain magnesium hydroxide modified waste bricks.

[0044] In an embodiment of the present invention, in step (1), the waste building bricks include at least one of fly ash bricks, red bricks, blue bricks and gray bricks. It should be pointed out that construction waste bricks are waste clay bricks produced during building demolition, reconstruction or construction, including but not limited to f...

Embodiment 1

[0078] Example 1 A method of treating sewage by using artificial wetland system

[0079] (1) prepare modified magnesium hydroxide, comprise the steps:

[0080] Crushing and screening of waste bricks: The Hammer Crusher crushes the collected construction waste bricks (blue bricks), and the broken waste bricks are screened separately to obtain waste brick particles with uniform particle size (1-10mm);

[0081] Plasma etching: put the screened waste bricks into the plasma reaction device, set the irradiation power supply to 100w, and the irradiation time to 30min, and use air plasma to etch the surface of the waste bricks to increase the porosity and specific surface area of ​​the material ;

[0082] Ultrasonic-assisted nano-magnesium hydroxide loading: disperse 1g of waste bricks after plasma etching into 50mL of seawater (Mg 2+ concentration of 0.15mol / L), put the waste brick seawater mixed solution in the ultrasonic cell breaker, set the ultrasonic time to 60min, then slow...

Embodiment 2

[0093] Example 2 A method of treating sewage by using artificial wetland system

[0094] Same as Example 1, the difference is that when preparing modified magnesium hydroxide, the waste building bricks are made of fly ash bricks.

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Abstract

The invention provides a magnesium hydroxide modified waste brick, a preparation method thereof and application of the magnesium hydroxide modified waste brick in an artificial wetland system, and belongs to the field of water environment treatment.The preparation method of the magnesium hydroxide modified waste brick comprises the following steps that 1, building waste bricks are crushed and sieved, and waste brick particles are obtained; (2) carrying out air plasma treatment on the waste brick particles to obtain plasma-etched waste bricks; and (3) dispersing the waste brick subjected to plasma etching into seawater, carrying out first ultrasonic treatment, dropwise adding a sodium hydroxide solution, carrying out second ultrasonic treatment, cleaning, and drying to obtain the artificial wetland filler magnesium hydroxide modified waste brick. The obtained artificial wetland filler magnesium hydroxide modified waste brick is mainly used for preparing an artificial wetland system, and can effectively improve the nitrogen and phosphorus removal efficiency of the artificial wetland and improve the effluent quality.

Description

technical field [0001] The invention belongs to the field of water environment treatment, and in particular relates to magnesium hydroxide modified waste bricks, a preparation method thereof, and an application in artificial wetland systems. Background technique [0002] With the effective control of point source pollution, non-point source pollution has become an important reason that threatens the surface water environment. Among them, nitrogen and phosphorus nutrients are the main pollutants of non-point source pollution. Excessive nitrogen and phosphorus will aggravate the eutrophication of water bodies, cause black and odorous water bodies in cities, and lead to deterioration of water quality. Treatment processes such as constructed wetlands are widely used in the removal of nitrogen and phosphorus from water bodies. Among them, it is of great significance to choose fillers for constructed wetlands with high removal efficiency, long service life, cheap and easy access....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F3/30C02F3/34C02F3/32C01B25/45C05B7/00C05G3/40
Inventor 储杨阳杨龙王嗣禹周媛张敏
Owner CHINA URBAN CONSTR DESIGN & RES INST CO LTD
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