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Copper-plated basalt fiber reinforced copper-based composite material as well as preparation method and application thereof

A copper-based composite material and basalt fiber technology, applied in chemical instruments and methods, metal material coating technology, other chemical processes, etc., can solve the problems of basalt fiber strength loss, unfavorable strength of copper-based composite materials, and improvement, etc. Achieve the effect of small gap, improved high temperature resistance and abundant resources

Active Publication Date: 2022-07-15
CHANGCHUN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the sintering temperature is as high as 800-1000°C, and the holding time is as long as 3-4 hours. This sintering temperature and holding time will lead to a significant loss of strength of the basalt fiber during the sintering process, which is not conducive to the improvement of the strength of the copper-based composite material.

Method used

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  • Copper-plated basalt fiber reinforced copper-based composite material as well as preparation method and application thereof
  • Copper-plated basalt fiber reinforced copper-based composite material as well as preparation method and application thereof
  • Copper-plated basalt fiber reinforced copper-based composite material as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The present embodiment discloses a preparation method of a copper-plated basalt fiber-reinforced copper-based composite material, comprising the following steps:

[0041](1) Put the original basalt fiber into the vacuum furnace, the vacuum degree is 1-3×10 -3 Pa, heated to 400°C, and kept for 20min. Turn off the power supply, and after the temperature in the furnace drops below 50°C, take out the basalt fiber from the furnace to obtain preheated basalt fiber. The original morphology of basalt fiber is as follows figure 1 shown.

[0042] (2) The basalt fiber obtained by the treatment in step (1) was soaked in a 4 wt.% HF solution for 10 min to carry out surface roughening treatment.

[0043] (3) Put the basalt fiber obtained in step (2) into the sensitizing solution for ultrasonic vibration for 30 minutes, then put it into the activation solution for ultrasonic vibration for 30 minutes, wash and dry with alcohol for many times. The formula of the sensitizing solution...

Embodiment 2

[0051] The present embodiment discloses a preparation method of a copper-plated basalt fiber-reinforced copper-based composite material, comprising the following steps:

[0052] (1) Put the original basalt fiber into the vacuum furnace, the vacuum degree is 1-3×10 -3 Pa, heated to 400°C, and kept for 20min. Turn off the power supply, and after the temperature in the furnace drops below 50°C, take out the basalt fiber from the furnace to obtain preheated basalt fiber.

[0053] (2) The basalt fiber obtained by the treatment in step (1) was soaked in a 4 wt.% HF solution for 10 min to carry out surface roughening treatment.

[0054] (3) Put the basalt fiber obtained in step (2) into the sensitizing solution for ultrasonic vibration for 30 minutes, then put it into the activation solution for ultrasonic vibration for 30 minutes, wash and dry with alcohol for many times. The formula of the sensitizing solution is: SnCl 2 , 20 g / L; 37 wt.% HCl, 40 mL / L; the remainder is deionized...

Embodiment 3

[0060] The present embodiment discloses a preparation method of a copper-plated basalt fiber-reinforced copper-based composite material, comprising the following steps:

[0061] (1) Put the original basalt fiber into the vacuum furnace, the vacuum degree is 1-3×10 -3 Pa, heated to 400°C, and kept for 20min. Turn off the power supply, and after the temperature in the furnace drops below 50°C, take out the basalt fiber from the furnace to obtain preheated basalt fiber.

[0062] (2) The basalt fiber obtained by the treatment in step (1) was soaked in a 4 wt.% HF solution for 10 min to carry out surface roughening treatment.

[0063] (3) Put the basalt fiber obtained in step (2) into the sensitizing solution for ultrasonic vibration for 30 minutes, then put it into the activation solution for ultrasonic vibration for 30 minutes, wash and dry with alcohol for many times. The formula of the sensitizing solution is: SnCl 2 , 20 g / L; 37 wt.% HCl, 40 mL / L; the remainder is deionized...

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Abstract

The invention discloses a preparation method of a copper-plated basalt fiber reinforced copper-based composite material, which comprises the following steps: S1, carrying out preheating treatment on basalt fibers, and then carrying out roughening treatment by adopting hydrofluoric acid; s2, the basalt fibers subjected to roughening treatment are placed in a copper plating solution to be subjected to chemical copper plating treatment; and S3, the basalt fibers subjected to copper plating and copper powder are mixed and then subjected to compression molding, the copper-plated basalt fiber reinforced copper-based composite material is prepared through spark plasma sintering, and the content of the copper-plated basalt fibers in the copper-based composite material is 1%-3% by weight. The invention further provides the copper-plated basalt fiber reinforced copper-based composite material prepared through the method and application of the copper-plated basalt fiber reinforced copper-based composite material. According to the preparation method of the copper-plated basalt fiber reinforced copper-based composite material, a copper-plated layer is formed on the surface of the basalt fiber through a chemical copper plating method, so that the interface bonding between the basalt fiber and copper is improved, and the mechanical property of the copper-based composite material is improved.

Description

technical field [0001] The invention relates to the technical field of composite material preparation, in particular to a copper-plated basalt fiber-reinforced copper-based composite material and a preparation method and application thereof. Background technique [0002] Copper has excellent electrical and thermal conductivity and processing properties, and has been widely used in aerospace, marine engineering, electronics and automobiles. However, the strength of pure copper is relatively low, which has greatly limited the application of copper in some fields. The introduction of a second phase with higher strength, such as particles, whiskers, fibers, etc., into the copper matrix, thereby preparing a copper matrix composite material, not only improves the strength of the copper material, but also makes the advantages of each component fully exerted. Therefore, received extensive attention and research. [0003] As a new type of environmental protection material, basalt f...

Claims

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Application Information

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IPC IPC(8): C22C47/02C22C47/04C22C47/14C22C49/02C22C49/14C23C18/40C23C18/18B22F3/04B22F3/14C09K3/14C22C101/06
CPCC22C47/02C22C47/04C22C47/14C22C49/02C22C49/14C23C18/405C23C18/1865C23C18/1893B22F3/04B22F3/14C09K3/14B22F2999/00B22F2202/06Y02P10/25
Inventor 朱巍巍冉旭李乾邹豪豪苑嗣俊韩英祖国庆赵宇
Owner CHANGCHUN UNIV OF TECH
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