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Automobile anti-freezing cooling liquid and preparation method thereof

An antifreeze coolant and automobile technology, applied in the field of coolant, can solve the problems of affecting the cooling and anticorrosion effect of the coolant, affecting the service life of the cooling system, and unsatisfactory anticorrosion effect, so as to improve the anticorrosion effect, low cost, and good anticorrosion The effect of corrosion

Pending Publication Date: 2022-07-29
HUNAN CHERUI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, inorganic corrosion inhibitors mainly include: phosphates, chromates, molybdates, borates, nitrites and silicates, phosphates, borates, nitrites Molybdates and chromates have a good corrosion inhibition effect on carbon steel, aluminum, copper or zinc and other metals or alloys, but they are toxic to a certain extent and pollute water bodies, so their use has been restricted; Or alloys have good anti-corrosion effects, but they are expensive and costly; silicate compounds have good corrosion inhibition effects on almost every metal and alloy, but their stability changes after a certain period of storage and use. Poor, it is easy to form a gel-like substance to precipitate, which reduces the anti-corrosion performance, and the resulting gel is easy to block the pipeline
Organic corrosion inhibitors mainly include: amines, organic acids, and azole compounds. However, the existing organic corrosion inhibitors have unsatisfactory anticorrosion effects on aluminum or its alloys. These organic substances are in contact with aluminum metal. Discoloration and blackening of aluminum will affect the cooling and anti-corrosion effect of the coolant, thereby affecting the service life of the cooling system

Method used

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  • Automobile anti-freezing cooling liquid and preparation method thereof
  • Automobile anti-freezing cooling liquid and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The preparation method of the automobile antifreeze coolant of the present embodiment includes the following steps:

[0036] S1. Mix 3.5kg of propylene glycol and 0.35kg of composite corrosion inhibitor, raise the temperature to 95°C, stir into a mixed liquid, and naturally cool to room temperature;

[0037] S2, heat 3.5kg of propylene glycol to 70°C, then add 1.5kg of PEG-200, stir and mix evenly, then add 80g of sodium polyaspartate and 2g of methyl blue in turn, stir for 10min, cool to room temperature, and then mix with step S1 The mixed liquids were mixed, and stirred for 5min to obtain a mixture;

[0038] S3. Add 1.048 kg of ionized water to the mixture in step S3, and after mixing evenly, add sodium hydroxide and stir to adjust the pH to 8.0, then add 200 g of glycerol polyoxypropylene ether, and stir evenly.

[0039] The above composite corrosion inhibitor is composed of 0.5kg of water-soluble polyaniline, 1.5kg of triazole silane compound, 0.5kg of capric acid...

Embodiment 2

[0046] The preparation method of the automobile antifreeze coolant of the present embodiment includes the following steps:

[0047] S1. Mix 4.0kg of propylene glycol and 0.43kg of composite corrosion inhibitor, raise the temperature to 100°C, stir into a mixed liquid, and naturally cool to room temperature;

[0048] S2, heat 4.0kg of propylene glycol to 75°C, then add 1.0kg of PEG-200, stir and mix evenly, then add 50g of sodium polyaspartate and 5g of methyl blue in turn, stir for 10min, cool to room temperature, and then mix with step S1 The mixed liquids were mixed, and stirred for 5min to obtain a mixture;

[0049] S3, add 0.505kg of ionized water to the mixture in step S3, after mixing evenly, add sodium hydroxide and stir to adjust the pH value to 8.0, then add 100g of polyoxyethylene polyoxypropylene pentaerythritol ether, and stir evenly.

[0050] The above-mentioned composite corrosion inhibitor is composed of 1kg of water-soluble polyaniline, 1kg of triazole silane ...

Embodiment 3

[0057] The preparation method of the automobile antifreeze coolant of the present embodiment includes the following steps:

[0058] S1. Mix 3.6kg of propylene glycol and 0.41kg of composite corrosion inhibitor, raise the temperature to 100°C, stir into a mixed liquid, and naturally cool to room temperature;

[0059] S2, heat 3.6kg of propylene glycol to 70°C, then add 1.45kg of PEG-200, stir and mix evenly, then add 65g of sodium polyaspartate and 5g of methyl blue in turn, stir for 10min, cool to room temperature, and then mix with step S1 The mixed liquid is mixed, and stirred for 10min to obtain a mixture;

[0060] S3. Add 0.852kg of ionized water to the mixture in step S3, and after mixing evenly, add sodium hydroxide and stir to adjust the pH to 8.0, then add 180g of glycerol polyoxypropylene ether, and stir evenly.

[0061] The above composite corrosion inhibitor is composed of 1kg of water-soluble polyaniline, 1.2kg of triazole silane compound, 0.7kg of capric acid, 0....

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Abstract

The invention discloses an automobile anti-freezing cooling liquid and a preparation method thereof, and relates to the technical field of refrigerating fluids. The invention discloses an anti-freezing cooling liquid for an automobile. The anti-freezing cooling liquid is prepared from the following raw materials in percentage by weight: 70-80% of propylene glycol, 10-15% of PEG-200, 3.5-4.3% of a compound corrosion inhibitor, 0.5-0.8% of sodium polyaspartate, 0-0.05% of a coloring agent, 0.1-0.2% of a polyether defoaming agent and the balance of deionized water, the composite corrosion inhibitor is composed of water-soluble polyaniline, a triazole silane compound, decanoic acid, suberic acid and alkyl glycoside. The invention also provides a preparation method of the automobile anti-freezing cooling liquid. The automobile anti-freezing cooling liquid provided by the invention is environment-friendly, the preparation method is simple, and the automobile anti-freezing cooling liquid has excellent corrosion resistance to materials such as carbon steel, aluminum alloy, magnesium alloy, copper alloy, rubber or plastic sealing materials, also has excellent anti-boiling, anti-freezing and anti-scaling performance, can be stably stored for a long time, and is long in service life.

Description

technical field [0001] The invention belongs to the technical field of cooling liquids, and in particular relates to an automobile antifreeze cooling liquid and a preparation method thereof. Background technique [0002] The car engine is the core part of the car's power. Since a lot of heat is generated during the energy conversion process, the circulation of the cooling system is required to achieve the purpose of cooling, and the coolant is used to assist the heat dissipation of the engine. However, in the low temperature environment in winter Under these conditions, the coolant is easy to solidify at a low temperature, causing the cooling system of the automobile to freeze and crack, thus requiring the existing coolant to have a lower freezing point. Therefore, the antifreeze coolant has become a conventional indicator of the cooling system of the automobile engine. [0003] The traditional antifreeze coolant is composed of ethylene glycol and water mixed in a certain pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/20C23F11/173
CPCC09K5/20C23F11/173
Inventor 刘云喜刘寿喜刘欢喜张锦
Owner HUNAN CHERUI TECH CO LTD
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