Inorganic oxide conductive powder/polyaniline conductive polymer composite material and its preparation method

An inorganic oxide and conductive polymer technology, applied in the field of inorganic oxide conductive powder/polyaniline conductive polymer composite materials, can solve problems such as low conductivity, achieve high yield, reduce waste water pollution, and reduce residues. Effect

Inactive Publication Date: 2006-01-11
SOUTHWEST UNIVERSITY
View PDF0 Cites 31 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, compared with doped polyaniline, the conductivity of these oxide and binary oxi

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0022] Example 1:

[0023] 14g of aniline was weighed and dissolved in 140g of water, and 42.5g of dodecylbenzenesulfonic acid was dissolved in the mixed acid solution of 100ml [HCL]=2mol / L and added to the reactor together, and stirred on an electric mixer (the rotation speed interval was 1000~ 1500 rpm); after half an hour of emulsification, add 1.12 g of 300-1200 mesh inorganic oxide conductive powder ATO (antimony oxide doped tin oxide); after stirring for another half an hour, the mixed solution is milky white. Weigh 27.4 g Ammonium sulfate was dissolved in 274g of water, and then added dropwise to the reactor. The ice-water bath controlled the reaction temperature to 0-10°C, and the reaction occurred immediately. After 1 hour of dropwise addition, the reaction was stirred for 24 hours. Blue, blue, blue-green, green, the final solution is dark green latex, filter, separate, wash with distilled water until no sulfate radicals can be detected in the filtrate; vacuum dry at ...

Example Embodiment

[0030] Example 2:

[0031] 14g of aniline was weighed and dissolved in 140g of water, and 35.4g of camphorsulfonic acid was dissolved in 100ml of water and added to the reactor, and stirred on an electric mixer (the rotation speed range was 1000 to 1500 rpm); after half an hour of emulsification, inorganic Oxide conductive powder ATO (antimony doped tin oxide) 1.4g; after stirring for another half an hour, the mixed solution is milky white. Weigh 32.9g of ammonium persulfate and dissolve it in 274g of water, then dropwise into the reactor, ice water bath to control the reaction When the temperature is 0~10℃, the reaction occurs immediately. After 1h of dropwise addition, the reaction is carried out under stirring for 24h. The reaction solution changes from milky white to yellow-green, light blue, blue, blue-green, and green, and the final solution is dark green latex. , filtered, separated, washed with distilled water until no sulfate radicals were detected in the filtrate; va...

Example Embodiment

[0036] Example 3:

[0037] 14g of aniline was weighed and dissolved in 140g of water, 35.4g of camphorsulfonic acid or 42.5g of dodecylbenzenesulfonic acid was dissolved in 100ml [HCL]=2mol / L mixed acid solution and added to the reactor together, and stirred on an electric mixer (The speed range is 1000-1500 rpm); after half an hour of emulsification, add 1.4 g of inorganic oxide conductive powder ITO (indium-doped tin oxide); after stirring for another half an hour, the mixed solution is milky white. Weigh 27.4g of ammonium persulfate and dissolve it in 274g of water, then add it dropwise into the reactor. The ice-water bath controls the reaction temperature from 0 to 10°C. The reaction occurs immediately. Yellow-green, light blue, blue, blue-green, green, the final solution is dark green latex, filtered, separated, washed with distilled water until no sulfate radicals were detected in the filtrate; vacuum dried at 75°C to constant weight , that is, the conductive powder ITO...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Conductivityaaaaaaaaaa
Conductivityaaaaaaaaaa
Conductivityaaaaaaaaaa
Login to view more

Abstract

A process for preparing the electrically conductive inorganic oxide powder/electrically conductive high-molecular polyphenylamide compound includes such steps as proportionally mixing the aqueous solution of phenylamine with the aqueous solution of dopant acid, adding electrically conductive inorganic oxide, stirring,adding the aqueous solution of oxidant, reaction, and separating target product.

Description

technical field [0001] The invention relates to a conductive polymer composite material, in particular to an inorganic oxide conductive powder / polyaniline conductive polymer composite material synthesized by chemical oxidation in situ polymerization and a method thereof. technical background [0002] The last Nobel Prize in Chemistry in the 20th century was awarded in October 2000 to three chemists who had made outstanding achievements in the research of conductive polymers: Haig from the United States, Mark Diarmid from the United States and Hideo Shirakawa from Japan. Tree. [0003] Conductive polymers can be divided into two categories according to their conductive mechanism: one is composite conductive polymer materials, that is, various conductive fillers are added to conventional polymer materials, such as metal powder, conductive carbon black particles or fibers, etc.; The other type is the intrinsic conductive polymer material, which is f...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08G73/02C08L79/02C08K3/22
Inventor 傅相锴赵戈马丽华
Owner SOUTHWEST UNIVERSITY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap