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Light-emitting element and light-emitting device

A technology of light-emitting elements and light-emitting devices, which is applied in the direction of electroluminescent light sources, household components, electrical components, etc., and can solve the problems of leakage of external gas into light-emitting elements, high alkali metal reactive hydroxides, poor electron injection efficiency, etc. , to achieve the effects of easy production management, high electron injection efficiency, and improved life

Inactive Publication Date: 2006-08-16
IDEAL STAR INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, organic materials doped with alkali metals (used in the electron transport layer and electron injection layer) have the problem of high reactivity of alkali metals and easy formation of hydroxides.
Therefore, there are the following problems: in the manufacturing process of the light-emitting element, it must be strictly controlled to avoid the reaction of the organic material or the formed film doped with alkali metal with the water molecules and other impurities in the atmosphere; the light-emitting element or light-emitting device must be Completely sealed to avoid leakage of outside gas into the manufactured light-emitting element, reaction with water vapor, etc.
However, the electron affinity of cavity fullerene is small, and the electron injection efficiency is poor, so there is a problem of low luminous efficiency.

Method used

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Examples

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Effect test

Embodiment

[0075] The present invention will be specifically described below with reference to examples. However, it should be noted that the technical scope of the present invention is not limited to this embodiment.

[0076] The evaluation results of actually produced light-emitting elements are described below. As a light-emitting element according to a comparative example, a light-emitting element in which an organic material film doped with an alkali metal was used as an electron transport layer was evaluated. As light-emitting elements according to Examples, those using a fullerene-containing film for the electron transport layer and those using an organic material film doped with fullerene-containing fullerene for the electron transport layer were evaluated. As light-emitting elements for evaluation, 10 elements were produced by each production method.

Embodiment 1

[0079] (Manufacture of light-emitting element related to Example 1)

[0080]First, a transparent glass substrate (Corning 1713, 30mm×30mm, thickness 0.8mm) was prepared, and a thin film made of ITO was deposited on the glass substrate with a thickness of 340 Å by sputtering to form an anode. Then, a thin film composed of copper phthalocyanine (trade name P1005) manufactured by Tokyo Kasei Co., Ltd. (trade name P1005) was deposited on the anode to a thickness of 10 Å to form a hole injection layer. Next, a thin film of NPD (trade name 55, 669-6) manufactured by Aldrich was deposited to a thickness of 1000 Å on the hole injection layer by vapor deposition to form a hole transport layer. Then Alq3 (trade name T203) manufactured by Tongren Chemical was purified by sublimation. On the hole injection layer, a thin film composed of purified Alq3 was deposited to a thickness of 500 Å by evaporation to form a light emitting layer. Next, add 50mg Na@C prepared by Ideal Star 60 After ...

Embodiment 2

[0081] (Manufacture of light-emitting element related to Example 2)

[0082] First, a transparent glass substrate (Corning 1713, 30 mm x 30 mm, thickness 0.8 mm) was prepared, and a thin film made of ITO was deposited on the glass substrate to a thickness of 340 Å by sputtering to form an anode. Then, a thin film composed of copper phthalocyanine (trade name P1005) manufactured by Tokyo Chemical Industry Co., Ltd. (trade name P1005) was deposited on the anode to a thickness of 10 Å to form a hole injection layer. Next, a thin film made of NPD (trade name 55, 669-6) manufactured by Aldrich was deposited to a thickness of 1000 Å by vapor deposition on the hole injection layer to form a hole transport layer. Then Alq3 (trade name T203) manufactured by Tongren Chemical was purified by sublimation. On the hole injection layer, a thin film composed of purified Alq3 was deposited to a thickness of 500 Å by evaporation to form a light emitting layer. Then, 20 mg of PBD (trade name 2...

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Abstract

Organic materials doped with an alkali metal have been conventionally used for electron-transporting layers or electron injection layers which constitute light-emitting films in organic EL light-emitting elements which are used in displays or illuminating devices. Such conventional organic materials involve problems such that a strict process control is required since the alkali metal is highly reactive and thus likely to be formed into a hydroxide, such that the resulting light-emitting element or light-emitting device needs complete sealing, and such that life of the light-emitting element cannot be sufficiently long. The present invention uses an alkali metal-containing fullerene or an organic material doped with an alkali metal-containing fullerene for electron-transporting layers or electron injection layers which constitute light-emitting films in organic EL light-emitting elements. The alkali metal-containing fullerene or the organic material doped with an alkali metal-containing fullerene is not very reactive with moisture in the atmosphere or other impurities and thus the process control thereof is easy. Furthermore, even with a simple sealing structure, the resulting light-emitting element can have sufficiently long life.

Description

technical field [0001] The present invention relates to a light-emitting element and a light-emitting device using organic EL as a light-emitting material used in devices such as display devices and lighting devices. Background technique [0002] Non-Patent Document 1: AMD Application Note Vol. 1 (2002, December) P1-P19, About Alkali Metal Diffusion of OLEDs (AMD Application Note Vol. 1 Dec., 2002, P1-19, AlkaliMetal Dispenser for OLED). [0003] Patent Document 1: Japanese Unexamined Patent Publication No. 2001-6878, thin-film EL element and its driving method. [0004] Currently, various display devices such as liquid crystal displays and plasma displays featuring thin and flat panels are widely used as display devices replacing picture tubes. In addition, in recent years, the research and development of display devices using organic EL has been rapidly progressing, and this research has attracted attention as a strong candidate for next-generation display devices. Organ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H05B33/22H01L27/32H01L51/00
CPCB82Y10/00H01L51/0046H01L51/002H01L51/0059H01L27/3244H01L51/0071H01L51/0081Y10S428/917H10K71/30H10K59/12H10K85/211H10K85/631H10K85/324H10K85/657H05B33/22
Inventor 笠间泰彦表研次
Owner IDEAL STAR INC
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