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Adjuvant composition for chemicals used in agriculture

a technology for adjuvants and chemicals, applied in the field of adjuvants for chemicals used in agriculture, can solve the problems of difficult preparation of stable homogeneous blends of lipophilic solvents and ammonium salts, and the inability to evaluate such products as adjuvants, and achieve the effect of minimizing the deleterious effects of hard water on herbicide performan

Inactive Publication Date: 2005-07-28
VICTORIAN CHEM INT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012] It was envisaged that incorporating ammonium salts into lipophilic solvent-based adjuvants would produce an adjuvant which provides active ingredient enhancement in several different ways. It was thought that the ammonium salts (a source of nitrogen) would enhance translocation through the fertilizer effects and could also increase leaf permeability, and the appropriate anion would reduce the effects of water hardness, whilst the lipophilic solvents would increase the availability of the active on the target and subsequently the absorption of the active into the target. However, preparing a stable homogeneous blend of lipophilic solvent with ammonium salts, particularly those which minimize the detrimental effects of hard water has not been easy to achieve because such salts are not soluble in lipophilic solvents. Hence, evaluating such a product as an adjuvant has not been possible.
[0029] The lipophobic plant nutrients include ammonium salts of inorganic anions (such as ammonium sulphate and phosphates) which are known to minimise the deleterious effects of hard water on herbicide performance. Preferably, the ammonium salt is ammonium sulphate. If an anhydrous ammonium salt is used then water may need to be added to the composition. However, if the ammonium salt is already in solution then additional water may not be necessary.
[0032] Preferably, the adjuvant composition comprises other components to improve the form of the composition. These other components may be added to form a micro-emulsion. The other components may be selected from the group consisting of nonionic emulsifiers, co-solvents and mixtures thereof.

Problems solved by technology

However, preparing a stable homogeneous blend of lipophilic solvent with ammonium salts, particularly those which minimize the detrimental effects of hard water has not been easy to achieve because such salts are not soluble in lipophilic solvents.
Hence, evaluating such a product as an adjuvant has not been possible.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0055] In this example, low levels of glyphosate were used to treat a broadleaf weed and a grass weed.

Adjuvant Compositions Tested

[0056] The following adjuvant formulations were prepared and are stable compositions. A formulation was classified as stable if it remained a clear liquid without detectable phase separation for at least 48 hours through the temperature range 0 to 40° C. Adjuvant D which is an oil-in-water emulsion was only tested at room temperature.

[0057] The proportions are shown as percentage by weight.

lipophilicplant nutrientcationicsolventPotassiumemulsifierother componentsEthylProrexAmmoniumAmmoniumammoniumAddedRadiaquatAlkadetSpanAdjuvantoleate36nitratesulfatephosphateUreaWater646515Ethanol80A—2816——1216123310B—22—17——39114—7C—26——50——107—7D25———47—696—6

Note that there was no water added to Adjuvant C but there was a water content of about 30%.

[0058] The above adjuvants were tested by combining the adjuvant with Glyphosate CT in a water-based tank mix. Comp...

example 2

[0073] In this example, the effect of external conditions and hard water are tested. Hard water has been shown to reduce the efficacy of glyphosate. Higher temperatures increase the evaporation rate of the spray water and thereby can leave the glyphosate dry on the foliage rendering it less available for absorption into the plant.

[0074] Water hardness is measured in World Health Organisation units of hardness (WHO). One WHO is equivalent to 343 ppm of CaCO3.

[0075] The test compositions were tested on ryegrass using water of three differing degrees of hardness: Melbourne tap water (typically 20 ppm), 1WHO and 3WHO water. The fresh weight (grams) of the weeds were measured 19 days after spray application. The results are an average of seven or eight replicates.

[0076] The test compositions were tested on ryegrass exposed to two differing environmental temperature conditions (Standard and Hot) for one hour before and two hours after spraying. Standard temperature was that of the cont...

example 3

[0085] This example investigated the formulation stability when another typical adjuvant component is added. The additional component tested was BIVERT concentrate which is the active ingredient of BIVERT, a spray drift retardant ex Wilbur-Ellis Company.

[0086] The following compositions were prepared as homogeneous blends. All proportions are by weight. All the ingredients except for the citric acid were stirred together. Then enough citric acid was then added with stirring to clear the mixture and give high temperature stability.

[0087] Each of the adjuvants G, H and I were found to be homogeneous blends which remained clear without phase separation for at least 48 hours through the temperature range 0 to 40° C.

[0088] Adjuvant Compositions with Spray Drift Retardant

AdjuvantComponentGHILipophilic solventEthyl oleate303030Plant nutrientAmmonium sulphate——10Potassium ammonium2020—phosphateWater101020Cationic EmulsifierDimethyl laurylamine101010Quatramine C16 / 29—66Radiaquat 64655——...

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Abstract

According to the invention an adjuvant for use with a chemical used in agriculture is provided comprising: (a) not in excess of about 75% by weight of one or more lipophilic solvents; (b) not in excess of about 50% by weight of one or more plant nutrients (e.g. ammonium salts of inorganic anions); and (c) not in excess of about 50% of a mixture of one or more cationic emulsifiers including surfactants which exhibit cationic characteristic in acidic conditions.

Description

FIELD OF THE INVENTION [0001] The invention relates to an adjuvant for use with chemicals used in agriculture. More particularly, the adjuvant of the invention is particularly adapted for use with herbicides. BACKGROUND OF THE INVENTION [0002] In this specification, where a document, act or item of knowledge is referred to or discussed, this reference or discussion is not to be taken as an admission that the document, act or item of knowledge or any combination thereof was at the priority date: [0003] (a) part of common general knowledge; or [0004] (b) known to be relevant to an attempt to solve any problem with which this specification is concerned. [0005] Whilst the following discussion highlights the invention with relation to herbicides, it is believed that the same principles apply to other chemicals used in agriculture, such as, plant hormones, insecticides, crop desiccants or crop defoliants. [0006] Farmers rotate the use of their fields to allow the fields to regain their fe...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): A01N25/02A01N25/30A01N57/20C05G3/00C05G3/70
CPCA01N25/02A01N25/30A01N57/20C05G3/0064C05G3/06A01N2300/00C05G3/50C05G5/27
Inventor KILLICK, ROBERT W.KILLICK, ANDREW R.JONES, PETER W.WRIGLEY, PETER R.MORRISON, JOHN D.
Owner VICTORIAN CHEM INT
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