Method for high energy density biomass-water slurry

Inactive Publication Date: 2008-01-24
RGT UNIV OF CALIFORNIA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Benefits of technology

[0018]The present invention provides an energy efficient process for converting biomass into a higher carbon content, high energy density slurry. In particular, water and biomass are mixed at a temperature and under a pressure that are much lower used in than prior processes, but under nitrogen, which enables a stable sl

Problems solved by technology

Since the resources for the production of petroleum-based fuels are being depleted, dependency on petroleum will become a major problem unless non-petroleum alternative fuels, in particular clean-burning synthetic diesel fuels, are developed.
Moreover, normal combustion of petroleum-based fuels in conventional engines can cause serious environmental pollution unless strict methods of exhaust emission control are used.
Such a process allows for the application of current state-of-art engine exhaust after-treatment methods for NOx reduction, removal of toxic particulates present in diesel engine exhaust, and the reduction of normal combustion product pollutants, currently accomplished by catalysts that are poisoned quickly by any sulfur present, as is the case in ordinary stocks of petroleum derived diesel fuel, reducing the catalyst effic

Method used

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  • Method for high energy density biomass-water slurry

Examples

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Example

EXAMPLE 1

[0025]Referring to FIG. 1, a mixture of 50% biomass, consisting of pine tree particles in water is shown before treatment. Dry pine sawdust was obtained from American Wood Fibers and the dry White Cedar from Utah. The sawdust was ground using a commercially available coffee grinder and sieved to <100 mesh (150 μm). For the wood pre-treatment, an autoclave system was set up. It consisted of an Autoclave Engineers EZE-Seal pressure vessel rated at 3,300 psi at 850° F. The wood sample and deionized water were weighed and then well mixed by hand to even water distribution in a large beaker before putting it in the vessel. The amount of wood added was adjusted for moisture content. The vessel was then weighed with contents, vacuumed and purged three times with argon, and finally pressurized to 100±1 psi. The temperature was ramped to operating temperature (210-230° C.) in about 30 minutes and then held for 30 minutes. Pressure and internal temperature were recorded using a data ...

Example

EXAMPLE 2

[0027]The procedure of Example 1 was followed but the vessel was preheated to >200° C. before being put in the heater. The autoclave was found to reach 230° C. in 15 minutes or less and then it was held for 30 minutes. The time needed to reach the target temperature did not have a noticeable physical impact on the resulting product

Example

EXAMPLE 3

[0028]The method of Example 1 can be carried out but in which the starting mixture is non-pumpable agricultural waste containing 60 weight percent solids. The result will be a pumpable slurry containing 60 wt. % solids in water.

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Abstract

An energy efficient process for converting biomass into a higher carbon content, high energy density slurry. Water and biomass are mixed at a temperature and under a pressure that are much lower used in than prior processes, but under a non-oxidative gas, which enables a stable slurry to be obtained containing up to 60% solids, about 38% carbon by weight. The temperature is nominally about 200° C. under non-oxidative gas pressure of about 150 psi, conditions that are substantially less stringent than those required by the prior art.

Description

FIELD OF THE INVENTION[0001]The field of the invention is the synthesis of transportation fuel from carbonaceous feed stocks.BACKGROUND OF THE INVENTION[0002]There is a need to identify new sources of chemical energy and methods for its conversion into alternative transportation fuels, driven by many concerns including environmental, health, safety issues, and the inevitable future scarcity of petroleum-based fuel supplies. The number of internal combustion engine fueled vehicles worldwide continues to grow, particularly in the midrange of developing countries. The worldwide vehicle population outside the U.S., which mainly uses diesel fuel, is growing faster than inside the U.S. This situation may change as more fuel-efficient vehicles, using hybrid and / or diesel engine technologies, are introduced to reduce both fuel consumption and overall emissions. Since the resources for the production of petroleum-based fuels are being depleted, dependency on petroleum will become a major pro...

Claims

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Application Information

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IPC IPC(8): C10J3/00
CPCC10B53/02C10J3/00C10L1/326C10L5/44C10J2300/09C10L9/086Y02E50/10Y02E50/14Y02E50/30C10L9/00Y02P20/145
Inventor NORBECK, JOSEPH M.PARK, CHAN SEUNGAGUIRRE, ANDRES
Owner RGT UNIV OF CALIFORNIA
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